Solar energy
Solar chemical processes use solar energy to drive chemical reactions. These processes offset energy that would otherwise come from a fossil fuel source and can also convert solar energy into storable and transportable fuels. Solar induced chemical reactions can be divided into thermochemical or photochemical. A variety of fuels can be produced by artificial photosynthesis. The multielectron catalytic chemistry involved in making carbon-based fuels (such as methanol) from reduction of carbon dioxide is challenging; a feasible alternative is hydrogen production from protons, though use of water as the source of electrons (as plants do) requires mastering the multielectron oxidation of two water molecules to molecular oxygen. Some have envisaged working solar fuel plants in coastal metropolitan areas by 2050 the splitting of sea water providing hydrogen to be run through adjacent fuel-cell electric power plants and the pure water by-product going directly into the municipal water system. Another vision involves all human structures covering the earth's surface (i.e., roads, vehicles and buildings) doing photosynthesis more efficiently than plants.

Q: What is a possible alternative to making carbon-based fuels from reduction of carbon dioxide?
hydrogen production from protons