Question: There are many important organozinc compounds. Organozinc chemistry is the science of organozinc compounds describing their physical properties, synthesis and reactions. Among important applications is the Frankland-Duppa Reaction in which an oxalate ester(ROCOCOOR) reacts with an alkyl halide R'X, zinc and hydrochloric acid to the -hydroxycarboxylic esters RR'COHCOOR, the Reformatskii reaction which converts -halo-esters and aldehydes to -hydroxy-esters, the SimmonsSmith reaction in which the carbenoid (iodomethyl)zinc iodide reacts with alkene(or alkyne) and converts them to cyclopropane, the Addition reaction of organozinc compounds to carbonyl compounds. The Barbier reaction (1899) is the zinc equivalent of the magnesium Grignard reaction and is better of the two. In presence of just about any water the formation of the organomagnesium halide will fail, whereas the Barbier reaction can even take place in water. On the downside organozincs are much less nucleophilic than Grignards, are expensive and difficult to handle. Commercially available diorganozinc compounds are dimethylzinc, diethylzinc and diphenylzinc. In one study the active organozinc compound is obtained from much cheaper organobromine precursors:
Try to answer this question if possible: What does organozinc chemistry conceal?
Answer: unanswerable
Question: A "lock-in" is when a pub owner lets drinkers stay in the pub after the legal closing time, on the theory that once the doors are locked, it becomes a private party rather than a pub. Patrons may put money behind the bar before official closing time, and redeem their drinks during the lock-in so no drinks are technically sold after closing time. The origin of the British lock-in was a reaction to 1915 changes in the licensing laws in England and Wales, which curtailed opening hours to stop factory workers from turning up drunk and harming the war effort. Since 1915, the UK licensing laws had changed very little, with comparatively early closing times. The tradition of the lock-in therefore remained. Since the implementation of Licensing Act 2003, premises in England and Wales may apply to extend their opening hours beyond 11 pm, allowing round-the-clock drinking and removing much of the need for lock-ins. Since the smoking ban, some establishments operated a lock-in during which the remaining patrons could smoke without repercussions but, unlike drinking lock-ins, allowing smoking in a pub was still a prosecutable offence.
Try to answer this question if possible: What is it called when the owner of a pub allows patrons to remain when the pub should have closed?
Answer: "lock-in"
Question: The national postal infrastructure was completely destroyed during the civil war. In order to fill the vacuum, Somali Post signed an agreement in 2003 with the United Arab Emirates' Emirates Post to process mail to and from Somalia. Emirates Post's mail transit hub at the Dubai International Airport was then used to forward mail from Somalia to the UAE and various Western destinations, including Italy, the Netherlands, the United Kingdom, Sweden, Switzerland and Canada.
Try to answer this question if possible: Where is the Somalia Post mail transit Hub?
Answer: unanswerable
Question: In four months, Aonuma's team managed to present realistic horseback riding,[l] which Nintendo later revealed to the public with a trailer at Electronic Entertainment Expo 2004. The game was scheduled to be released the next year, and was no longer a follow-up to The Wind Waker; a true sequel to it was released for the Nintendo DS in 2007, in the form of Phantom Hourglass. Miyamoto explained in interviews that the graphical style was chosen to satisfy demand, and that it better fit the theme of an older incarnation of Link. The game runs on a modified The Wind Waker engine.
Try to answer this question if possible: How long did it take to implement riding Phantoms in a believable manner?
Answer:
unanswerable