Question: "What is special about the reactions of 1899?" Context: "There are many important organozinc compounds. Organozinc chemistry is the science of organozinc compounds describing their physical properties, synthesis and reactions. Among important applications is the Frankland-Duppa Reaction in which an oxalate ester(ROCOCOOR) reacts with an alkyl halide R'X, zinc and hydrochloric acid to the -hydroxycarboxylic esters RR'COHCOOR, the Reformatskii reaction which converts -halo-esters and aldehydes to -hydroxy-esters, the SimmonsSmith reaction in which the carbenoid (iodomethyl)zinc iodide reacts with alkene(or alkyne) and converts them to cyclopropane, the Addition reaction of organozinc compounds to carbonyl compounds. The Barbier reaction (1899) is the zinc equivalent of the magnesium Grignard reaction and is better of the two. In presence of just about any water the formation of the organomagnesium halide will fail, whereas the Barbier reaction can even take place in water. On the downside organozincs are much less nucleophilic than Grignards, are expensive and difficult to handle. Commercially available diorganozinc compounds are dimethylzinc, diethylzinc and diphenylzinc. In one study the active organozinc compound is obtained from much cheaper organobromine precursors:" Answer:
Ans: the Barbier reaction can even take place in water

Question: "When did textiles peak in Nanjing?" Context: "Since the Three Kingdoms period, Nanjing has been an industrial centre for textiles and minting owing to its strategic geographical location and convenient transportation. During the Ming dynasty, Nanjing's industry was further expanded, and the city became one of the most prosperous cities in China and the world. It led in textiles, minting, printing, shipbuilding and many other industries, and was the busiest business center in East Asia. Textiles boomed particularly in Qing dynasty, the industry created around 200 thousand jobs and there were about 50 thousand satin machines in the city in 18th and 19th century." Answer:
Ans: 18th and 19th century

Question: "what faith is mentioned first?" Context: "Orthodox Judaism considers views on the part of Jews who depart from traditional Jewish principles of faith heretical. In addition, the more right-wing groups within Orthodox Judaism hold that all Jews who reject the simple meaning of Maimonides's 13 principles of Jewish faith are heretics. As such, most of Orthodox Judaism considers Reform and Reconstructionist Judaism heretical movements, and regards most of Conservative Judaism as heretical. The liberal wing of Modern Orthodoxy is more tolerant of Conservative Judaism, particularly its right wing, as there is some theological and practical overlap between these groups." Answer:
Ans: Orthodox Judaism

Question: "When can we tie the origination of the word Iran?" Context: "The term Iran derives directly from Middle Persian Eran, first attested in a 3rd-century inscription at Rustam Relief, with the accompanying Parthian inscription using the term Aryan, in reference to Iranians. The Middle Iranian eran and aryan are oblique plural forms of gentilic er- (Middle Persian) and ary- (Parthian), both deriving from Proto-Iranian *arya- (meaning "Aryan," i.e., "of the Iranians"), argued to descend from Proto-Indo-European *ar-yo-, meaning "skillful assembler." In Iranian languages, the gentilic is attested as a self-identifier included in ancient inscriptions and the literature of Avesta,[a] and remains also in other Iranian ethnic names such as Alans (Ossetic: Ir) and Iron (Ossetic: Iron)." Answer:
Ans: 3rd-century