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Copper occurs naturally as native copper and was known to some of the oldest civilizations on record. It has a history of use that is at least 10,000 years old, and estimates of its discovery place it at 9000 BC in the Middle East; a copper pendant was found in northern Iraq that dates to 8700 BC. There is evidence that gold and meteoric iron (but not iron smelting) were the only metals used by humans before copper. The history of copper metallurgy is thought to have followed the following sequence: 1) cold working of native copper, 2) annealing, 3) smelting, and 4) the lost wax method. In southeastern Anatolia, all four of these metallurgical techniques appears more or less simultaneously at the beginning of the Neolithic c. 7500 BC. However, just as agriculture was independently invented in several parts of the world, copper smelting was invented locally in several different places. It was probably discovered independently in China before 2800 BC, in Central America perhaps around 600 AD, and in West Africa about the 9th or 10th century AD. Investment casting was invented in 45004000 BC in Southeast Asia and carbon dating has established mining at Alderley Edge in Cheshire, UK at 2280 to 1890 BC. Otzi the Iceman, a male dated from 33003200 BC, was found with an axe with a copper head 99.7% pure; high levels of arsenic in his hair suggest his involvement in copper smelting. Experience with copper has assisted the development of other metals; in particular, copper smelting led to the discovery of iron smelting. Production in the Old Copper Complex in Michigan and Wisconsin is dated between 6000 and 3000 BC. Natural bronze, a type of copper made from ores rich in silicon, arsenic, and (rarely) tin, came into general use in the Balkans around 5500 BC.[citation needed]
When was copper first known to have been used?
A: 9000 BC

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11th Street is in two parts. It is interrupted by the block containing Grace Church between Broadway and Fourth Avenue. East 11th streets runs from Fourth Avenue to Avenue C and runs past Webster Hall. West 11th Street runs from Broadway to West Street. 11th Street and 6th Avenue was the location of the Old Grapevine tavern from the 1700s to its demolition in the early 20th century.
When was the Old Grapevine tavern demolished?
A: early 20th century

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New Haven is a notable center for higher education. Yale University, at the heart of downtown, is one of the city's best known features and its largest employer. New Haven is also home to Southern Connecticut State University, part of the Connecticut State University System, and Albertus Magnus College, a private institution. Gateway Community College has a campus in downtown New Haven, formerly located in the Long Wharf district; Gateway consolidated into one campus downtown into a new state-of-the-art campus (on the site of the old Macy's building) and was open for the Fall 2012 semester.
What school serves as the largest employer of New Haven?
A: Yale University

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Around the start of the 20th century, a growing population of Asian Americans lived in or near Santa Monica and Venice. A Japanese fishing village was located near the Long Wharf while small numbers of Chinese lived or worked in both Santa Monica and Venice. The two ethnic minorities were often viewed differently by White Americans who were often well-disposed towards the Japanese but condescending towards the Chinese. The Japanese village fishermen were an integral economic part of the Santa Monica Bay community.
What type of Village was located on the Long Wharf?
A:
Japanese fishing