Context and question: There are many important organozinc compounds. Organozinc chemistry is the science of organozinc compounds describing their physical properties, synthesis and reactions. Among important applications is the Frankland-Duppa Reaction in which an oxalate ester(ROCOCOOR) reacts with an alkyl halide R'X, zinc and hydrochloric acid to the -hydroxycarboxylic esters RR'COHCOOR, the Reformatskii reaction which converts -halo-esters and aldehydes to -hydroxy-esters, the SimmonsSmith reaction in which the carbenoid (iodomethyl)zinc iodide reacts with alkene(or alkyne) and converts them to cyclopropane, the Addition reaction of organozinc compounds to carbonyl compounds. The Barbier reaction (1899) is the zinc equivalent of the magnesium Grignard reaction and is better of the two. In presence of just about any water the formation of the organomagnesium halide will fail, whereas the Barbier reaction can even take place in water. On the downside organozincs are much less nucleophilic than Grignards, are expensive and difficult to handle. Commercially available diorganozinc compounds are dimethylzinc, diethylzinc and diphenylzinc. In one study the active organozinc compound is obtained from much cheaper organobromine precursors:
When will organomagnesium halide formation become permanent?
Answer: unanswerable
Context and question: On 30 September, Zhou Enlai warned the United States that China was prepared to intervene in Korea if the United States crossed the 38th parallel. Zhou attempted to advise North Korean commanders on how to conduct a general withdrawal by using the same tactics which had allowed Chinese communist forces to successfully escape Chiang Kai-shek's Encirclement Campaigns in the 1930s, but by some accounts North Korean commanders did not utilize these tactics effectively. Historian Bruce Cumings argues, however, the KPA's rapid withdrawal was strategic, with troops melting into the mountains from where they could launch guerrilla raids on the UN forces spread out on the coasts.
Who vowed to intervene if the US was to engage in conflict North of the 38th parallel?
Answer: China
Context and question: Yerevan Vernissage (arts and crafts market), close to Republic Square, bustles with hundreds of vendors selling a variety of crafts on weekends and Wednesdays (though the selection is much reduced mid-week). The market offers woodcarving, antiques, fine lace, and the hand-knotted wool carpets and kilims that are a Caucasus specialty. Obsidian, which is found locally, is crafted into assortment of jewellery and ornamental objects. Armenian gold smithery enjoys a long tradition, populating one corner of the market with a selection of gold items. Soviet relics and souvenirs of recent Russian manufacture nesting dolls, watches, enamel boxes and so on are also available at the Vernisage.
What is Obsidian used for?
Answer:
jewellery and ornamental objects