pinecone/core-2020-05-10-deduplication huggingface dataset:
Hypothermic liquid ventilation prevents early hemodynamic dysfunction and cardiovascular mortality after coronary artery occlusion complicated by cardiac arrest in rabbits.

International audienceOBJECTIVES: Ultrafast and whole-body cooling can be induced by total liquid ventilation with temperature-controlled perfluorocarbons. Our goal was to determine whether this can afford maximal cardio- and neuroprotections through cooling rapidity when coronary occlusion is complicated by cardiac arrest. DESIGN: Prospective, randomized animal study. SETTING: Academic research laboratory. SUBJECTS: Male New Zealand rabbits. INTERVENTIONS: Chronically instrumented rabbits were submitted to coronary artery occlusion and ventricular fibrillation. After 8 minutes of cardiac arrest, animals were resuscitated and submitted to a normothermic follow-up (control group) or to 3 hours of mild hypothermia induced by total liquid ventilation (total liquid ventilation group) or by combination of cold saline infusion and cold blankets application (saline group). Coronary reperfusion was permitted 40 minutes after the onset of occlusion. After awakening, rabbits were followed up during 7 days. MEASUREMENTS AND MAIN RESULTS: Ten animals were resuscitated in each group. In the control group, all animals secondarily died of cardiac/respiratory failure (8 of 10) or neurological dysfunction (2 of 10). In the saline group, the target temperature of 32°C was achieved within 30-45 minutes after cooling initiation. This slightly reduced infarct size versus control (41% ± 16% vs 54% ± 8% of risk zone, respectively; p < 0.05) but failed to significantly improve cardiac output, neurological recovery, and survival rate (three survivors, six death from cardiac/respiratory failure, and one from neurological dysfunction). Conversely, the 32°C temperature was achieved within 5-10 minutes in the total liquid ventilation group. This led to a dramatic reduction in infarct size (13% ± 4%; p < 0.05 vs other groups) and improvements in cardiac output, neurological recovery, and survival (eight survivors, two deaths from cardiac/respiratory failure). CONCLUSIONS: Achieving hypothermia rapidly is critical to improve the cardiovascular outcome after cardiac arrest with underlying myocardial infarction
Multi-criteria checkpointing strategies: response-time versus resource utilization

International audienceFailures are increasingly threatening the efficiency of HPC systems, and current projections of Exascale platforms indicate that rollback recovery, the most convenient method for providing fault tolerance to general-purpose applications, reaches its own limits at such scales. One of the reasons explaining this unnerving situation comes from the focus that has been given to per-application completion time, rather than to platform efficiency. In this paper, we discuss the case of uncoordinated rollback recovery where the idle time spent waiting recovering processors is used to progress a different, independent application from the system batch queue. We then propose an extended model of uncoordinated checkpointing that can discriminate between idle time and wasted computation. We instantiate this model in a simulator to demonstrate that, with this strategy, uncoordinated checkpointing per application completion time is unchanged, while it delivers near-perfect platform efficiency.Voir le résumé en anglais
Fixed Point and Aperiodic Tilings

v5: technical revision (positions of figures are shifted)International audienceAn aperiodic tile set was first constructed by R.Berger while proving the undecidability of the domino problem. It turned out that aperiodic tile sets appear in many topics ranging from logic (the Entscheidungsproblem) to physics (quasicrystals) We present a new construction of an aperiodic tile set that is based on Kleene's fixed-point construction instead of geometric arguments. This construction is similar to J. von Neumann self-reproducing automata; similar ideas were also used by P. Gacs in the context of error-correcting computations. The flexibility of this construction allows us to construct a ``robust'' aperiodic tile set that does not have periodic (or close to periodic) tilings even if we allow some (sparse enough) tiling errors. This property was not known for any of the existing aperiodic tile sets
Study of a low Mach nuclear core model for single-phase flows

This paper deals with the modelling of the coolant (water) in a nuclear reactor core. This study is based on a monophasic low Mach number model (LMNC model) coupled to the stiffened gas law for a single-phase flow. Some analytical steady and unsteady solutions are presented for the 1D case. We then introduce a numerical scheme to simulate the 1D model in order to assess its relevance. Finally, we carry out a normal mode perturbation analysis in order to approximate 2D solutions around the 1D steady solutions
Responsive Giant Vesicles filled with Poly(N-isopropylacrylamide) Sols or Gels

4 pagesInternational audienceWe prepared giant unilamellar vesicles (GUVs) enclosing solutions or covalent gels of Poly(Nisopropylacrylamide) (PolyNipam). Concentrated suspensions of GUVs were prepared by applying an alternative field on a lipid film hydrated by a monomer solution containing N-isopropylacrylamide, crosslinker (N,N-methylene-bis-acrylamide), initiator and sucrose. Vesicle inner medium was polymerised and crosslinked by UV irradiation of the suspension, yielding viscous vesicles enclosing a solution of linear PolyNipam chains (when no bisacrylamide was used) or elastic vesicles filled with a covalent PolyNipam gel. We show that gel-filled vesicles are responsive systems triggered by the temperature: they shrink, reducing by a factor eight their volume below the critical temperature (32 ◦C in water, lower in glucose solution) and re-swell in a reversible and reproducible way upon decreasing temperature. In both cases, we show that the vesicle lipid membrane interacts with the internal polymer, resulting in an strong resistance of the vesicles to external mechanical stresses (enhanced tension of lysis)
Pollen-rain-vegetation relationships along a forest-savanna transect in southeastern Cameroon

Modern soil and litter samples from southeastern Cameroon, collected along a continuous forest-savanna transect were analysed for pollen content to define modern pollen-vegetation relationships. The pollen results, completed and compared with botanical inventories, leaf area index and basal area measurements performed in the same area, clearly registered the physiognomy, the main floristic composition and floral richness of the two sampled ecosystems. Distortions were observed between sampled vegetations and their pollen rain, related to important differences in pollen production and dispersal of plant species: this is a general feature in many tropical regions. The pollen data in the area studied reflected well the recent transgression of forest versus savanna. This permitted us to define inside the forest ecosystem more successional vegetation communities than the botanical surveys allowed
Governing the transition to natural gas in Mediteranean Metropolis: The case of Cairo, Istanbul and Sfax (Tunisia)

International audienceConsiders the governance of natural gas networks in emerging cities. Adopts a geographical approach looking at interactions between natural gas infrastructure and urban space. Switch to natural gas linked to financial purpose (subsidy cuts) more than concern for climate change. Switch to natural gas shaped by policies governing other urban energy forms. Urban politics and issues of affordability impact the governance of natural gas transition. a b s t r a c t Recent scholarship on urban energy governance has focused on low carbon energy strategies seen as a response to climate change and energy pressure threats. But such approaches tend to overlook the situations of cities from the Global South and emerging countries concerned with strong energy demand growth. The development of urban natural gas networks is an understudied response to such a challenge. Focusing on three cities, Istanbul, Cairo and Sfax (Tunisia), the article analyses the factors and the governance of these energy transitions. It uses a geographical approach to such processes that highlight the mutual influence of the territory in its material and political dimensions and of the policy goals and tools in the implementation. The development of urban gas networks rests upon the proximity of gas deposits. It is determined by metropolitan strategies for economic development as well as by programs aiming to cut energy subsidies. Though urban gas networks have a strong potential for restructuring the physical and social landscapes in cities, the dominant commercial approach taken by energy utilities and morphological constraints in the urban fabric limit their universalization. Natural gas is part of a mix of energies at the urban level and often competes with other energy forms, specifically renewables (like solar water heaters). Lastly, the development of urban natural gas networks sparks heated politics in relation to unfulfilled energy demand and affordability
First estimate of volcanic SO2 budget for Vanuatu island arc

International audienceThe spatial and temporal coverage of measurements of previous termvolcanicnext term gas emissions remains patchy. However, over the last decade, emissions inventories have improved thanks to new measurements of some of the lesser-known previous termvolcanicnext term areas. We report on one such region - the Vanuatu island arc, in the Southwest Pacific - for which we now have sufficient systematic observations to offer a systematic emissions inventory. Our new estimate is based on SO2 flux measurements made in the period 2004-2009 with ultraviolet spectroscopy techniques for the following volcanoes: Yasur, Lopevi, Ambrym, Ambae, Gaua and Vanua Lava (from south to north). These are the first ever measurements for Lopevi, Gaua and Vanua Lava. The results reveal the Vanuatu arc as one of Earth's prominent sources of previous termvolcanicnext term degassing with a characteristic annual emission to the atmosphere of ~ 3 Tg of SO2 (representing about 20% of hitherto published global estimates). Our new dataset highlights the sustained prodigious degassing of Ambrym volcano, whose 5 Gg d-1 mean flux of SO2 represents nearly two-thirds of the total budget for the Vanuatu arc. This confirms Ambrym as one of the largest previous termvolcanic sources worldwide comparable to Etna, often considered as the most vigorous source of previous termvolcanic emission on Earth. We also report a high degassing for Ambae of ~ 2 Gg d-1 SO2, representing more than 28 % of the Vanuatu arc budget. Thus, 90 % of the SO2 output from Vanuatu is focused in the central part of the arc (from Ambrym and Ambae) where magmas originate from enriched Indian-type mantle and where peculiar tectonic conditions could favour high magma production rates
Reactive Functionalized Multilayer Polymers in a Coextrusion Process: Experimental and Theoretical Investigations of Interfacial Instabilities

International audienceCoextrusion technologies are commonly used to produce multilayered composite sheets or films for a large range of applications from food packaging to optics. The contrast of rheological properties between layers can lead to interfacial instabilities during flow. Important theoretical and experimental advances regarding the stability of compatible and incompatible polymers have, during the last decades, been made using a mechanical approach. However, few research efforts have been dedicated to the physicochemical affinity between the neighboring layers. The present study deals with the influence of this affinity on interfacial instabilities for functionalized incompatible polymers. Polyamide (PA6)/polyethylene grafted with glycidyl methacrylate (PE-GMA) was used as a reactive system and PE/PA6 as a non reactive one. Two grades of polyamide (PA6) were used in order to change the viscosity and elasticity ratios between PE (or PE-GMA) and PA6. It was experimentally confirmed, in this case, that weak disturbance can be predicted by considering an interphase of non-zero thickness (corresponding to an interdiffusion/reaction zone) instead of a purely geometrical interface between the two reactive layers. According to rheological investigations from previous work, an experimental strategy was here formulated to optimize the process by listing the parameters that controlled the stability of the reactive multilayer flows. Plastic films with two layers were coextruded in symmetrical and asymmetrical configurations in which PA6 was the middle layer. Indeed, for reactive multilayered systems, the interfacial flow instability could be reduced or eliminated, for instance, by (i) increasing the residence time or temperature in the coextrusion bloc (for T above the reaction temperature T = 240°C), and (ii) reducing the total extrusion flow rate. The reaction rate/compatibilization played a major role that must be taken into account. Furthermore, the role of the viscosity ratio, elasticity ratio, and layer ratio of the stability of the interface were also investigated coupling to the physicochemical affinity. The results show that it is necessary to obtain links between the classic factors that are introduced in the evaluation of the theoretical, given by linear stability analysis/longwave asymptotic investigations, and its corresponding experimental stability charts. Hence, based on this analysis, guide-lines for a stable coextrusion of reactive functionalized polymers can be provided
Ponderomotive effects in the femtosecond plasmon-assisted photoelectric effect in bulk metals: Evidence for coupling between surface and interface plasmons

International audienceThe existence of ponderomotive acceleration effects in the metal bulk has been experimentally demonstrated in the context of the femtosecond plasmon-assisted multiphoton photoelectric effect in metal systems. The resulting electron energy spectra show that these effects essentially depend on the coupling between the surface and interface plasmons. While the essential part played by the ponderomotive force of the surface plasmon is to accelerate the photoelectrons in the vacuum, the dramatic enhancement of the photoelectron production and the angular dependence in the photoemission process mainly result from ponderomotive effects in the metal bulk. In the photoelectric effect in metals, photoelectrons may be emitted from a region near the metal surface 1,2 or may originate from the bulk. 3 In the bulk, electron excitation occurs via photon absorption in the presence of a third body ͑ion or impurity͒ or through interband transitions. On the other hand, the surface effects play an essential role for the number of electrons emitted while the absorption of light energy in the surface layer ͑a few nanometers͒ is relatively small ͑about 0.1% of the total absorption rate͒. In recent years, much attention has been paid to the possibility of enhancing electron emission of metals through the surface pho-toelectric effect by means of light excitation of electron collective oscillation modes localized near the metal surface.
Stochastic semi-classical description of sub-barrier fusion reactions

International audienceA semi-classical method that incorporates the quantum e ects of the low-lying vibrational modes is applied to fusion reactions. The quantum e ect is simulated by stochastic sampling of initial zero-point fluc- tuations of the surface modes. In this model, dissipation of the relative energy into non-collective excitations of nuclei can be included straightforwardly. The inclusion of dissipation is shown to increase the agreement with the fusion cross section data of Ni isotopes
Effect of loading on the nature of the REE–humate complexes as determined by Yb3+ and Sm3+ LIII-edge EXAFS analysis

International audienceHumic substances are major natural complexing agents that strongly influence the cycling of metal cations in the environment. The metal to humic acid (HA) concentration ratio (metal loading) can significantly impact the overall HA complexation properties in natural soils and waters. At low metal loading, cations bind to strong multi-carboxylate or -phenolate sites of HA. In addition, these strong sites might contain soft Lewis bases such as N or S, the contribution of which is still a matter of debate. Based on the possible ability of Rare Earth Elements (REE) to trace HA binding properties, the present study aimed at evaluating the influence of REE-loading on the HA binding mechanisms of two hard Lewis acids, Sm3+ and Yb3+. Extended X-ray Absorption Fine Structure (EXAFS) at the Sm and Yb LIII edge was used to analyze the local coordination of these intermediate and heavy REE ions, respectively, in a low and a high REE-loading HA sample. Data were interpreted by comparison with EXAFS data for a series of aqueous REE complexes with iminodiacetic acid (IDA), nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and a carboxylic-grafted resin. In all these samples, both a Yb–O (~ 2.31 Å) and a Yb–N (~ 2.50 Å) backscattering path could be identified in the first coordination shell of Yb. At low REE loading, the first coordination shell around the Yb bond to HA is described by a single Yb–O backscattering path, i.e. the presence of N could not be evidenced. By contrast, the carboxylic-grafted resin exhibits both a short (2.31 Å) and a long Yb–O average distance (2.44 Å), suggesting the coordination of carboxylate is bidentate. The Fourier transform of the high loading HA samples exhibits a broad first shell peak possibly described by two Yb–O distances (2.29 and 2.43 Å) suggesting two coordination modes of the carboxylic groups. Different Yb–HA complex structures can therefore be observed at different metal loadings. Unfortunately, the Sm EXAFS spectra could only be recorded up to k = 10 Å−1. There was no evidence of either a clear difference between the metal loadings or with Yb–HA complex structures. A comparison between the EXAFS results, PHREEQC-Model VI simulations, and the pattern of the REE complexation constants with simple organic ligands (REE:ligand 1:1 and 1:2 complexes) provides evidence that, at high loading, REE are bound to HA through bi-ligand complexes without any chelation effect in which REE may potentially act as a cation bridge between two organic molecules. At low loading, the fact that N could not be detected in the Yb first shell suggests that, at low loading, Yb binds to O-containing groups of HA rather than N-containing groups. This may call into question the definition of HA strong sites for REE binding such as soft Lewis base-containing sites
Global S-wave tomography using receiver pairs: An alternative to get rid of earthquake mislocation

International audienceGlobal seismic tomography suffers from uncertainties in earthquake parameters routinely published in seismic catalogues. In particular, errors in earthquake location and origin-time may lead to strong biases in measured body wave delay-times and significantly pollute tomographic models. Common ways of dealing with this issue are to incorporate source parameters as additional unknowns into the linear tomographic equations, or to seek combinations of data to minimize the influence of source mislocations. We propose an alternative, physically-based method to desensitize direct S-wave delay-times to errors in earthquake location and origin-time. Our approach takes advantage of the fact that mislocation delay-time biases depend to first order on the earthquake-receiver azimuth, and to second order on the epicentral distance. Therefore, for every earthquake, we compute S-wave differential delay-times between optimized receiver pairs, such that a large part of their mislocation delay-time biases cancels out (for example origin-time fully subtracts out), while the difference of their sensitivity kernels remains sensitive to the model parameters of interest. Considering realistic, randomly distributed source mislocation vectors, as well as various levels of data noise and different synthetic Earths, we demonstrate that mislocation-related model errors are highly reduced when inverting for such differential delay-times, compared to absolute ones. The reduction is particularly rewarding for imaging the upper-mantle and transition zone. We conclude that using optimized receiver pairs is a suitable, low cost alternative to get rid of errors on earthquake location and origin-time for teleseismic direct S-wave traveltimes. Moreover, it can partly remove unilateral rupture propagation effects in cross-correlation delay-times, since they are similar to mislocation effects
Global S-wave tomography using receiver pairs: an alternative to get rid of earthquake mislocation

International audienceGlobal seismic tomography suffers from uncertainties in earthquake parameters routinely published in seismic catalogues. In particular, errors in earthquake location and origin-time may lead to strong biases in measured body wave delay-times and significantly pollute tomographic models. Common ways of dealing with this issue are to incorporate source parameters as additional unknowns into the linear tomographic equations, or to seek combinations of data to minimize the influence of source mislocations. We propose an alternative, physically-based method to desensitize direct S-wave delay-times to errors in earthquake location and origin-time. Our approach takes advantage of the fact that mislocation delay-time biases depend to first order on the earthquake-receiver azimuth, and to second order on the epicentral distance. Therefore, for every earthquake, we compute S-wave differential delay-times between optimized receiver pairs, such that a large part of their mislocation delay-time biases cancels out (for example origin-time fully subtracts out), while the difference of their sensitivity kernels remains sensitive to the model parameters of interest. Considering realistic, randomly distributed source mislocation vectors, as well as various levels of data noise and different synthetic Earths, we demonstrate that mislocation-related model errors are highly reduced when inverting for such differential delay-times, compared to absolute ones. The reduction is particularly rewarding for imaging the upper-mantle and transition zone. We conclude that using optimized receiver pairs is a suitable, low cost alternative to get rid of errors on earthquake location and origin-time for teleseismic direct S-wave traveltimes. Moreover, it can partly remove unilateral rupture propagation effects in cross-correlation delay-times, since they are similar to mislocation effects