pinecone/core-2020-05-10-deduplication huggingface dataset:
High energy resolution five-crystal spectrometer for high quality fluorescence and absorption measurements on an X-ray Absorption Spectroscopy beamline

International audienceFluorescence detection is classically achieved with a solid state detector (SSD) on x-ray absorption spectroscopy (XAS) beamlines. This kind of detection however presents some limitations related to the limited energy resolution and saturation. Crystal analyzer spectrometers (CAS) based on a Johann-type geometry have been developed to overcome these limitations. We have tested and installed such a system on the BM30B/CRG-FAME XAS beamline at the ESRF dedicated to the structural investigation of very dilute systems in environmental, material and biological sciences. The spectrometer has been designed to be a mobile device for easy integration in multi-purpose hard x-ray synchrotron beamlines or even with a laboratory x-ray source. The CAS allows to collect x-ray photons from a large solid angle with five spherically bent crystals. It will cover a large energy range allowing to probe fluorescence lines characteristic of all the elements from Ca (Z = 20) to U (Z = 92). It provides an energy resolution of 1-2 eV. XAS spectroscopy is the main application of this device even if other spectroscopic techniques (RIXS, XES, XRS, etc.) can be also achieved with it. The performances of the CAS are illustrated by two experiments that are difficult or impossible to perform with SSD and the complementarity of the CAS vs SSD detectors is discussed
Nitrate and sulphate dynamics in peat subjected to different hydrological conditions: Batch experiments and field comparison

International audienceConservation of ecosystems that depend on water management and water quality has to be considered. We combined a field monitoring and batch experiments to better understand the impact of hydrological perturbations on peatland functioning. Factors influencing the dynamics of nitrate and sulphate concentration observed in two sites with different hydrological conditions in a south Normandy peatland were determined through the comparison of field and lab experiment. The effects of nitrate input, and oxic or anoxic conditions on nitrate and sulphate concentrations were investigated in bioreactors, using peat samples from field sites influenced by different hydrologic regimes. In this experiment, peat samples were subjected to similar conditions to address the effects of NO 3 and O2 concentrations (chemical effects), and the effect of hydrologic regimes and peat soil moisture (physical effects) on nitrate and sulphate dynamics. Cl , SO2 4 and NO 3 were monitored for 215 h. Nitrate was significantly reduced in most experiments. A complete nitrate reduction after 215 h in soil under anoxic conditions was observed. A denitrification process was also found under aerobic conditions depending on the peat site sampling, i.e. depending on the hydrological conditions. This process was interpreted as a heterotrophic denitrification. Sulphate monitoring revealed that 400 mg L 1 were produced in peat from the peat site with high hydrologic fluxes under aerobic conditions. Clear differences in chloride concentration (deviance analysis, P < 0.05), sulphate concentration and nitrate consumption dynamics (deviance analysis, P < 0.0001) were observed, for similar experimental chemical conditions, between the samples from the two peat sites. These differences were related to the field chemical variations observed and they indicate that part of the field nitrate and sulphate dynamics is linked to different bacterial activity and not only to nutrient fluxes variations
Linking canopy images to forest structural parameters : potential of a modeling framework

Remote sensing methods, and in particular very high (metric) resolution optical imagery, are essential assets to obtain forest structure data that cannot be measured from the ground, because they are too difficult to measure, or because the areas to sample are too large or inaccessible. To understand what kind of, and how precisely and accurately, information on forest structure can be inverted from RS data, we propose a modeling framework combining a simple 3D forest model, Allostand, based on empirical or theoretically-derived DBH distributions and allometry rules , with a well-established radiative transfer model, DART. This framework allows producing forest canopy images for any type of forest based on widely available information of inventory data. Image texture can then be quantified, for instance using the Fourier Transform Textural Ordination (FOTO) method, and the derived textural indices compared with stand parameters for inversion and sensitivity analyses, as well as to indices from real world remote sensing images. The potential of the approach for the development of quantitative methods to assess forest structure, dynamics, matter and energy budgets and degradation, including in tropical contexts, is illustrated emphasizing broadleaf natural forests and discussed
Early to mid-Holocene climate change at Lago dell'Accesa (central Italy): climate signal or anthropogenic bias?

International audienceDespite the high potential of pollen records for climate reconstruction, pollen-climate relationships may be biased due to past and present human activities on the landscape. We use (i) transfer functions based on modern pollen-climate relationships to infer seasonal temperature and summer precipitation for the period 11 500-4500 cal. a BP and (ii) lake-level change records based on different sedimentary proxies in multiple cores that are mainly indicative for summer hydrology at Lago dell'Accesa (central Italy). Quantitative reconstructions indicate lowest summer precipitation during two phases (8500-7700 cal. a BP and after 6000 cal. a BP) and a gradual winter temperature increase from 11 500 to ca. 8000 cal. a BP. Lowest summer precipitation was reconstructed during these phases characterised by vegetation shifts from open forests dominated by summergreen oaks (Quercus) to forests dominated by evergreen oaks (Quercus ilex), which are at present most abundant where summer drought is stronger. Similarly, the lake-level record indicates two long-lasting low summer precipitation phases (8800-7700 and 6400-4400 cal. a BP) that were interrupted by short-term high summer precipitation events. Based on the broad agreement between the pollen-inferred summer precipitation and the low-frequency lake-level changes, we suggest that the duration of the high summer precipitation events may have been too short to maintain drought-sensitive trees, which may have been affected by high mortality rates when summer dry conditions returned. Although past and modern pollen-climate relationships may very likely have been affected by human activities since the Neolithic (i.e. when exploitation of the landscape started), we reject the hypothesis of a significant anthropogenic bias in the pollen-based climate reconstruction. In addition, we suggest that pollen-based and lake-level reconstructions may have different inherent abilities of capturing high- and low-frequency precipitation signal
Detection of foreign phases in doped a-alumina powders by thermoluminescence

International audienceThe thermoluminescence (TL) after excitation by UV or X-rays radiation of doped a-alumina powders is investigated. In the case of zirconia, the alumina-zirconia composites present five of the characteristic peaks of zirconia at -170, -145, -90, 0 and 95°C. After a thermal treatment of mixed oxides, a new peak is observed at -35°C in TL. This peak reveals the presence of stabilized tetragonal zirconia in the material. In the case of calcium, the TL curves of a-alumina doped by calcium present a double peak around 110 and 130°C which can be attributed to the presence of the hibonite phase: CaAl12O19. Moreover, in the case of zirconia, by comparing this analysis with those realised by X-rays diffraction (XRD), it can be shown that the TL has one better limit of detection than the XRD
Seismo-ionosphere detection by underground SQUID in low-noise environment in LSBB-Rustrel, France

International audienceThe permanent operation of a 3 axes magnetometer in the LSBB below 550 m of calcite rock is a unique system of magnetic observation: a rejection rate better than 3 fT/Hz over 40 Hz. The observation of magneto-ionosphere responses to wave emissions both at the epicentre and at their arrival at LSBB for earthquakes of magnitude larger than 3 is reported. A simple model predicts the starting time of these events. These results are compared with those provided by Doppler sounders for ionosphere responses to Rayleigh waves
Logarithmic Sobolev Inequalities for Inhomogeneous Markov Semigroups

International audienceWe investigate the dissipativity properties of a class of scalar second order parabolic partial differential equations with time-dependent coefficients. We provide explicit condition on the drift term which ensure that the relative entropy of one particular orbit with respect to some other one decreases to zero. The decay rate is obtained explicitly by the use of a Sobolev logarithmic inequality for the associated semigroup, which is derived by an adaptation of Bakry's $\Gamma-$ calculus. As a byproduct, the systematic method for constructing entropies which we propose here also yields the well-known intermediate asymptotics for the heat equation in a very quick way, and without having to rescale the original equation
Ionogram height–time–intensity observations of descending sporadic E layers at mid-latitude

A new methodology of ionosonde height–time–intensity (HTI) analysis is introduced which allows the investigation of sporadic E layer (Es) vertical motion and variability. This technique, which is useful in measuring descent rates and tidal periodicities of Es, is applied on ionogram recordings made during a summer period from solstice to equinox on the island of Milos (36.71N; 24.51E). On the average, the ionogram HTI analysis revealed a pronounced semidiurnal periodicity in layer descent and occurrence. It is characterized by a daytime layer starting at 120km near 06 h local time (LT) and moving downward to altitudes below 100km by about 18 h LT when a nighttime layer appears above at_125 km. The latter moves also downward but at higher descent rates (1.6–2.2 km/h) than the daytime layer (0.8–1.5 km/h). The nighttime Es is weaker in terms of critical sporadic E frequencies (foEs), has a shorter duration, and tends to occur less during times close to solstice. Here, a diurnal periodicity in Es becomes dominant. The HTI plots often show the daytime and nighttime Es connecting with weak traces in the upper E region which occur with a semidiurnal, and at times terdiurnal, periodicity. These, which are identified as upper E region descending intermediate layers (DIL), play an important role in initiating and reinforcing the sporadic E layers below 120–125 km. The observations are interpreted by considering the downward propagation of wind shear convergent nodes that associate with the S2,3 semidiurnal tide in the upper E region and the S1,1 diurnal tide in the lower E region
Approche variationnelle de l'endommagement : II. Les modèles à gradient

International audienceThis second part of the variational approach to damage is devoted to the construction of non-local gradient-enhanced models. That consists in extending to these regularized models the concepts introduced in the ﬁrst part for local damage models. Speciﬁcally, once the gradient of damage has been inserted into the energy expression, the damage evolution problem is still based on the three physical principles of irreversibility, stability and energy balance. This new formulation is compared with that usually postulated and its merits are emphasized
From farm to fork - a life cycle assessment of fresh Austrian pork

With 7.5% total nutritional value, pork is a staple food for many members of the Austrian population. Among members of the general public, little is known about the environmental impacts "from farm to fork" in the production of pork. This paper identifies three main impact  categories for the environmental profile of Austrian pork using the Life Cycle Assessment (LCA) method. In a transparent and comprehensive manner, this LCA studied environmental impacts occurring throughout the production chain of pork, also including the transport and  consumption stages. The results are expressed in terms of the global warming potential (GWP), soil acidification and eutrophication, specifically in CO2-equivalents, SO2-equivalents and NO3-equivalents normalized to one kg of fresh Austrian pork (carcass  weight) as the functional unit. The main results of the study indicated that the environmental burden is primarily related to the farming stage: 92.3% of GWP, 98.4% of soil acidification and 95.4% of eutrophication. The processes taking place after the agriculture stage (i.e.,  during the slaughtering stage, retail market and consumption) play a minor role, except for the relative impact of eutrophication during the slaughtering stage. The transportation that took place between the different life cycle stages only marginally influenced the emissions  analysed, with private transport from the retail market to the household contributing most of the emissions considered in this part of the life cycle. These results point to the farming stage as the main focus for future improvements. Due to its high contribution to the GWP, soil  acidification and eutrophication potential, enhancing the efficiency and environmental protection measures implemented during the farming stage (or improving the choice of commodities used from feed production) could generate the highest reductions in impacts  on soil acidification, eutrophication and potentially on the global climate
A NMR and molecular dynamics study of CO2-bearing basaltic melts and glasses

International audienceThe presence of volatile, especially carbon dioxide (CO2), in silicate liquids is considered as a key parameter to magmatic degassing and eruptive processes. Unfortunately, due to experimental difficulties, our current knowledge on the CO2 effect on silicate melt structure is weak and relies on the observation of ex-situ recovered CO2-bearing glasses.In the present work, we confront the results obtained from NMR spectroscopic observations of glass synthesised at pressure between 0.5 and 3.0 GPa and theoretical investigations from first-principles molecular dynamics (FPMD) simulations conducted at 5.0 and 8.0 GPa on high temperature melt for a simplified basaltic composition.The results obtained on the aluminosilicate framework (molar fraction of silicon species and Al average coordination number) suggest that both ex-situ and in-situ results compare adequately. The results are in agreement with our current knowledge on the change in aluminosilicate melt/glass structure with changing intensive conditions. Increasing pressure from 0.5 to 8.0 GPa induces 1) an increase in the average Al coordination number from 4.1 to almost 5.0 and 2) an increase in the degree of polymerisation with NBO/Si changing from 1.30 to 0.80.The presence of CO2 does not seem to induce a dramatic change on both the average Al coordination number and the NBO/Si. FPMD simulations performed with 0 and 20 wt.% CO2 at 8.0 GPa result in a change from 4.84 to 4.96 for the average Al coordination number and in a change from 0.87 to 0.80 for the NBO/Si value, respectively.On the contrary, there is a lack of consistency in between the CO2 speciation obtained from NMR spectroscopy and from FPMD simulations. Whereas the analysis of glasses does not reveal the presence of CO2mol species, the FPMD simulation results suggests the existence of a small proportion of CO2mol. Further work with in-situ experimental approach is therefore required to explain the observed lack of consistency between the CO2 speciation in glass and in high temperature melt with basaltic composition
Market efficiency in the European carbon markets

International audienceIn this paper, we study the relationship between futures and spot prices in the European carbon markets from the cost-of-carry hypothesis. The aim is to investigate the extent of efficiency market. The three main European markets (BlueNext, EEX and ECX) are analyzed during Phase II, covering the period from March 13, 2009 to January, 17, 2012. Futures contracts are found to be cointegrated with spot prices and interest rates for several maturities in the three CO2 markets. Results are similar when structural breaks are taken into account. According to individual and joint tests, the cost-of-carry model is rejected for all maturities and CO2 markets, implying that neither contract is priced according to the cost-of-carry model. The absence of the cost-of-carry relationship can be interpreted as an indicator of market inefficiency and may bring arbitrage opportunities in the CO2 market
Analytic expressions for alpha-decay half-lives and potential barriers

From an adjustment on a recent selected data set of partial $\alpha$-decay half-lives of 344 ground state to ground state transitions, analytical formulas are proposed for $log_{10}T_{1/2}(s)$ depending or not on the angular momentum of the $\alpha$ particle. In particular, an expression allows to reproduce precisely the partial $\alpha$-decay half-lives of even-even heavy nuclei and, then, to predict accurately the partial $\alpha$-decay half-lives of other very heavy elements from the experimental or predicted $Q_\alpha$. Comparisons have been done with other empirical approaches. Moreover, the potential barrier against $\alpha$-decay or $\alpha$-capture has been determined within a liquid drop model including a proximity energy term. Simple expressions are provided to calculate the potential barrier radius and height
Reducing Equational Theories for the Decision of Static Equivalence

International audienceStatic equivalence is a well established notion of indistinguishability of sequences of terms which is useful in the symbolic analysis of cryptographic protocols. Static equivalence modulo equational theories allows for a more accurate representation of cryptographic primitives by modelling properties of operators by equational axioms. We develop a method that allows us in some cases to simplify the task of deciding static equivalence in a multi-sorted setting, by removing a symbol from the term signature and reducing the problem to several simpler equational theories. We illustrate our technique at hand of bilinear pairings
An improved elliptic guide concept for a homogeneous neutron beam without direct line of sight

Ballistic neutron guides are efficient for neutron transport over long distances, and in particular elliptically shaped guides have received much attention lately. However, elliptic neutron guides generally deliver an inhomogeneous divergence distribution when used with a small source, and do not allow kinks or curvature to avoid a direct view from source to sample. In this article, a kinked double elliptic solution is found for neutron transport to a small sample from a small  virtual  source, as given e.g. for instruments using a pinhole beam extraction with a focusing feeder. A guide consisting of two elliptical parts connected by a linear kinked section is shown by VITESS simulations to deliver a high brilliance transfer as well as a homogeneous divergence distribution while avoiding direct line of sight to the source. It performs better than a recently proposed ellipse parabola hybrid when used in a ballistic context with a kinked or curved central part. Another recently proposed solution, an analytically determined non linear focusing guide shape, is applied here for the first time in a kinked and curved ballistic context. The latter is shown to yield comparable results for long wavelength neutrons as the guide design found here, with a larger inhomogeneity in the divergence but higher transmission of thermal neutrons. It needs however a larger  virtual  source and might be more difficult to build in a real instrument
Temperature-sensitive defects of the GSP1gene, yeast Ran homologue, activate the Tel1-dependent pathway

RanGTPase is involved in many cellular processes. It functions in nuclear-cytosolic transport and centrosome formation. Ran also localizes to chromatin as RCC1 does, its guanine nucleotide exchange factor, but Ran's function on chromatin is not known. We found that gsp1, a temperature-sensitive mutant of GSP1, a Saccharomyces cerevisiae Ran homologue, suppressed the hydroxyurea (HU) and ultra violet (UV) sensitivities of the mec1 mutant. In UV-irradiated mec1 gsp1 cells, Rad53 was phosphorylated despite the lack of Mec1. This suppression depended on the TEL1 gene, given that the triple mutant, mec1 gsp1 tel1, was unable to grow. The gsp1 mutations also suppressed the HU sensitivity of the rad9 mutant in a Tel1-dependent manner, but not the HU sensitivity of the rad53 mutant. These results indicated that Rad53 was activated by the Tel1 pathway in mec1 gsp1 cells, suggesting that Gsp1 helps regulate the role switching the ATM family kinases Mec1 and Tel1
Electronic structure of LiSi

Silicon is of special interest in lithium-ion batteries (LIBs) since it has large theoretical specific
	capacity or volumetric capacity. The crystal structure, charge distribution and density of states of
	LiSi as the Li-poorest side compound at the start of Li intercalation mechanism for Si anode in LIBs
	has been studied by using Density Functional Theory calculations. The triangular pyramids are
	formed by four Li atoms. Compared with the charge density of crystalline Si, the Si-Si covalent
	bonds in LiSi become weak due to Li intercalation. On the other hand, the electrons around the Li
	atoms in LiSi increase compared with metallic Li. The Li atoms in LiSi have negative charge of
	0.830～0.843 compared with metallic Li. These electrons, which are transferred from p electrons in
	the Si atoms, are mainly made of p electrons of the Li atoms. When considering the lithium
	intercalation reaction from crystalline Si to LiSi, the average intercalation voltage is 0.4053 V
Gradient methods for variational optimization of projected entangled-pair states

We present a conjugate-gradient method for the ground-state optimization of projected entangled-pair states (PEPS) in the thermodynamic limit, as a direct implementation of the variational principle within the PEPS manifold. Our optimization is based on an efficient and accurate evaluation of the gradient of the global energy functional by using effective corner environments, and is robust with respect to the initial starting points. It has the additional advantage that physical and virtual symmetries can be straightforwardly implemented. We provide the tools to compute static structure factors directly in momentum space, as well as the variance of the Hamiltonian. We benchmark our method on Ising and Heisenberg models, and show a significant improvement on the energies and order parameters as compared to algorithms based on imaginary-time evolution