pinecone/core-2020-05-10-deduplication huggingface dataset:
Electronic band alignment at CuGaS2 chalcopyrite interfaces

Cu-chalcopyrite semiconductors are commonly used as light absorbing materials on solar cell devices. The study of the heterointerfaces between the absorbent and the contact materials is crucial to understand their operation. In this study, band alignments of the heterojunctions between CuGaS2 chalcopyrite and different semiconductors have been theoretically obtained using density functional theory and more advanced techniques. Band alignments have been determined using the average electrostatic potential as reference level. We have found that the strain in the heterointerfaces plays an important role in the electronic properties of the semiconductors employed here. In this work CuAlSe2/CuGaS2 and CuGaS2/ZnSe heterointerfaces show band alignments where holes and electrons are selectively transferred through the respective heterojunctions to the external contacts. This condition is necessary for their application on photovoltaic devices
Vortices enable the complex aerobatics of peregrine falcons

The peregrine falcon (Falco peregrinus) is known for its extremely high speeds during hunting dives or stoop. Here we demonstrate that the superior manoeuvrability of peregrine falcons during stoop is attributed to vortex-dominated flow promoted by their morphology, in the M-shape configuration adopted towards the end of dive. Both experiments and simulations on life-size models, derived from field observations, revealed the presence of vortices emanating from the frontal and dorsal region due to a strong spanwise flow promoted by the forward sweep of the radiale. These vortices enhance mixing for flow reattachment towards the tail. The stronger wing and tail vortices provide extra aerodynamic forces through vortex-induced lift for pitch and roll control. A vortex pair with a sense of rotation opposite to that from conventional planar wings interacts with the main wings vortex to reduce induced drag, which would otherwise decelerate the bird significantly during pull-out. These findings could help in improving aircraft performance and wing suits for human flights
Defining benzodiazepine dependence: The confusion persists

Contains fulltext :
                  27682.pdf (publisher's version ) (Open Access)Little consensus exists on the risk of benzodiazepine (BZD) dependence. We investigated how often BZD dependence and related concepts have been defined in the literature on BZD effects in humans. In addition, the definitions of BZD dependence were compared in order to assess the similarity of contents. From a total of 250 papers (published between 1988 and 1991) 51 provided 126 dependence-related definitions. Six studies referred to the DSM definitions and one to the WHO definition. The obsolete concept of addiction was frequently defined (n=13), with little consensus about its meaning. Psychological and physical dependence were defined fairly often (n=29), also with low levels of consensus. We conclude that the discussion on the risk of BZD dependence would be well-served by attempting to improve consensus first. This may lead to more meaningful data on the incidence, prevalence and relevant co-factors of BZD dependence. An outline for criteria for benzodiazepine dependence is presented
Measuring the Value of Strategic Alliances in the Wake of a Financial Implosion: Evidence from Japan's Financial Services Sector

This paper examines the wealth effects of financial-institution strategic alliances on the shareholders of the newly allied firms.  Our paper is different from previous studies of non-financial joint ventures, financial and non-financial mergers and acquisitions, and non-financial strategic alliances in three important aspects/ways:  First, we focus on financial institutions that form strategic alliances.  Second, while most related studies use U.S. data, this paper employs Japanese data for the late 1990s, directly testing financial theory in a different setting.  Finally, we study whether different types of alliances result in differing magnitudes of stock market responses.

Our primary results are as follows: First, we find that a strategic alliance, on average, increases the value of the partner firms.  This is consistent with the “synergy” hypothesis.  Second, the gains from the alliance are spread more widely among the partners than would be suggested by a random alternative, supporting a “win-win” hypothesis.  Third, smaller partners tend to experience larger percentage gains, which is consistent with a “relative size” hypothesis.  Fourth, the market values inter-group alliance announcements more than intra-group alliance announcements; the latter may well be seen as redundant.  This is consistent with an “inter-group synergies” hypothesis.  Fifth, we do not find a significant difference in the abnormal returns showed by domestic-foreign alliances and domestic-domestic alliances, although both sets of alliances show significantly positive returns.  We thus do not find support for a “foreign firm superior” hypothesis.  Finally, we find that an investment-banking alliance has a strong positive effect on abnormal returns, indicating that investment banking, which has been underdeveloped in Japan relative to the U.S., may be a promising business for financial institutions.

Overall, this paper complements the existing literature in that we analyze the value of financial institution alliances.  Our analysis reconfirms that strategic alliances are value-enhancing.  This is consistent with previous studies that find increased value in the announcement of a strategic alliance or a merger.  Our results are consistent with the notion that financial deregulation tends to increase competition, which, in turn, encourages firms to adopt aggressive corporate strategies.  This is viewed as a positive move by investors, as evidenced by the average gains of the shareholders of these alliance-forging firms
γ-Glutamyltransferase, but not markers of hepatic fibrosis, is associated with cardiovascular disease in older people with type 2 diabetes mellitus: the Edinburgh Type 2 Diabetes Study

AIMS/HYPOTHESIS: We examined the association of prevalent and incident cardiovascular disease (CVD) with chronic liver disease in a cohort of community-based people with type 2 diabetes, in order to clarify the relationship between these two important conditions. METHODS: 1,066 participants with type 2 diabetes aged 60–75 years underwent assessment of a range of liver injury markers (non-specific injury, steatosis, steatohepatitis, fibrosis, portal hypertension). Individuals were followed up for incident cardiovascular events. RESULTS: At baseline there were 370/1,033 patients with prevalent CVD, including 317/1,033 with coronary artery disease (CAD). After a mean follow-up of 4.4 years there were 44/663 incident CVD events, including 27/663 CAD events. There were 30/82 CVD-related deaths. Risk of dying from or developing CVD was no higher in participants with steatosis than in those without (HR 0.90; 95% CI 0.40, 2.00; p > 0.05). The only notable relationship was with γ-glutamyltransferase (GGT) (incident CVD: adjusted HR for doubling GGT 1.24 [95% CI 0.97, 1.59] p = 0.086; incident CAD: adjusted HR 1.33 [95% CI 1.00, 1.78] p = 0.053), suggesting that in our study population, chronic liver disease may have little effect on the development of, or mortality from, CVD. CONCLUSIONS/INTERPRETATION: An independent association between GGT and CVD warrants further exploration as a potentially useful addition to current cardiovascular risk prediction models in diabetes. However, overall findings failed to suggest that there is a clinical or pathophysiological association between chronic liver disease and CVD in elderly people with type 2 diabetes. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1007/s00125-015-3575-y) contains peer-reviewed but unedited supplementary material, which is available to authorised users
History and Sociology of Science

The relationship between archaeology and other sciences has only recently become a research topic for sociologists and historians of science. From the 1950s to the present day, different approaches have been taken and the aims of research studies have changed considerably. Besides methodological textbooks, which aim at advancing archaeological knowledge, historians of archaeology have tackled this question by exploring the development of archaeology as a scientific discipline. More recently, collaborations between archaeologists and other scientists have been examined as a general phenomenon regarding transfers of knowledge and power relationships between specialists, organizations, and scientific tools, where archaeology is considered as a scientific practice. Adopting a sociohistorical perspective, this entry examines the specificity of aims, facts, and procedures shared by archaeologists and other scientists regarding the crucial question of measuring time and computations
Energy Efficiency Improvements in Dry Drilling with Optimised Diamond-Like Carbon Coating

We demonstrate enhancements of performance and energy efficiency of cutting tools by deposition of diamond-like carbon (DLC) coatings on machine parts. DLC was deposited on steel drill bits, using plasma enhanced chemical vapour deposition (PECVD) with the acetylene precursor diluted with argon, to produce a surface with low friction and low wear rate. Drill bit performance in dry drilling of aluminium was quantified by analysis of power consumption and swarf flow. Optimised deposition conditions produced drill bits with greatly enhanced performance over uncoated drill bits, showing a 25% reduction in swarf clogging, a 36% reduction in power consumption and a greater than five-fold increase in lifetime. Surface analysis with scanning electron microscopy shows that DLC coated drills exhibit much lower aluminium build up on the trailing shank of the drill, enhancing the anti-adhering properties of the drill and reducing heat generation during operation, resulting in the observed improvements in efficiency. Variation of drilling efficiency with argon dilution of precursor is related to changes in the microstructure of the DLC coating
The principle of non-gravitating vacuum energy and some of its consequences

For Einstein's General Relativity (GR) or the alternatives suggested up to date the vacuum energy gravitates. We present a model where a new measure is introduced for integration of the total action in the D-dimensional space-time. This measure is built from D scalar fields \varphi_{a}. As a consequence of such a choice of the measure, the matter lagrangian L_{m} can be changed by adding a constant while no gravitational effects, like a cosmological term, are induced. Such Non-Gravitating Vacuum Energy (NGVE) theory has an infinite dimensional symmetry group which contains volume-preserving diffeomorphisms in the internal space of scalar fields \varphi_{a}. Other symmetries contained in this symmetry group, suggest a deep connection of this theory with theories of extended objects. In general {\em the theory is different from GR} although for certain choices of L_{m}, which are related to the existence of an additional symmetry, solutions of GR are solutions of the model. This is achieved in four dimensions if L_{m} is due to fundamental bosonic and fermionic strings. Other types of matter where this feature of the theory is realized, are for example: scalars without potential or subjected to nonlinear constraints, massless fermions and point particles. The point particle plays a special role, since it is a good phenomenological description of matter at large distances. de Sitter space is realized in an unconventional way, where the de Sitter metric holds, but such de Sitter space is supported by the existence of a variable scalar field which in practice destroys the maximal symmetry. The only space - time where maximal symmetry is not broken, in a dynamical sense, is Minkowski space. The theory has non trivial dynamics in 1+1 dimensions, unlike GR
Echo spectroscopy and Atom Optics Billiards

We discuss a recently demonstrated type of microwave spectroscopy of trapped ultra-cold atoms known as "echo spectroscopy" [M.F. Andersen et. al., Phys. Rev. Lett., in press (2002)]. Echo spectroscopy can serve as an extremely sensitive experimental tool for investigating quantum dynamics of trapped atoms even when a large number of states are thermally populated. We show numerical results for the stability of eigenstates of an atom-optics billiard of the Bunimovich type, and discuss its behavior under different types of perturbations. Finally, we propose to use special geometrical constructions to make a dephasing free dipole trap
Assessment of interatomic potentials for atomistic analysis of static and dynamic properties of screw dislocations in W

Screw dislocations in bcc metals display non-planar cores at zero temperature which result in high lattice friction and thermally-activated strain rate behavior. In bcc W, electronic structure molecular statics calculations reveal a compact, non-degenerate core with an associated Peierls stress between 1.7 and 2.8 GPa. However, a full picture of the dynamic behavior of dislocations can only be gained by using more efficient atomistic simulations based on semiempirical interatomic potentials. In this paper we assess the suitability of five different potentials in terms of static properties relevant to screw dislocations in pure W. Moreover, we perform molecular dynamics simulations of stress-assisted glide using all five potentials to study the dynamic behavior of screw dislocations under shear stress. Dislocations are seen to display thermally-activated motion in most of the applied stress range, with a gradual transition to a viscous damping regime at high stresses. We find that one potential predicts a core transformation from compact to dissociated at finite temperature that affects the energetics of kink-pair production and impacts the mechanism of motion. We conclude that a modified embedded-atom potential achieves the best compromise in terms of static and dynamic screw dislocation properties, although at an expense of about ten-fold compared to central potentials
Mechanical Characterization of Lead-Free Sn-Ag-Cu Solder Joints by High-Temperature Nanoindentation

The reliability of Pb-free solder joints is controlled by their microstructural constituents. Therefore, knowledge of the solder microconstituents’ mechanical properties as a function of temperature is required. Sn-Ag-Cu lead-free solder alloy contains three phases: a Sn-rich phase, and the intermetallic compounds (IMCs) Cu6Sn5 and Ag3Sn. Typically, the Sn-rich phase is surrounded by a eutectic mixture of β-Sn, Cu6Sn5, and Ag3Sn. In this paper, we report on the Young’s modulus and hardness of the Cu6Sn5 and Cu3Sn IMCs, the β-Sn phase, and the eutectic compound, as measured by nanoindentation at elevated temperatures. For both the β-Sn phase and the eutectic compound, the hardness and Young’s modulus exhibited strong temperature dependence. In the case of the intermetallics, this temperature dependence is observed for Cu6Sn5, but the mechanical properties of Cu3Sn are more stable up to 200°C
Quantitative analysis of morphological changes in yeast colonies growing on solid medium: the eccentricity and Fourier indices

The colony shape of four yeast species growing on agar medium wasmeasured for 116 days by image analysis. Initially, all the colonies are circular, with regular edges. The loss of circularity can be quantitatively estimated by the eccentricity index, Ei, calculated as the\ud
ratio between their orthogonal vertical and horizontal diameters. Ei can increase from 1 (complete circularity) to a maximum of 1.17–1.30, depending on the species. One colony\ud
inhibits its neighbour only when it has reached a threshold area. Then, Ei of the inhibited colony increases proportionally to the area of the inhibitory colony. The initial distance between colonies affects those threshold values but not the proportionality, Ei/area; this\ud
inhibition affects the shape but not the total surface of the colony. The appearance of irregularities in the edges is associated, in all the species, not with age but with nutrient exhaustion. The edge irregularity can be quantified by the Fourier index, Fi, calculated by\ud
the minimum number of Fourier coefficients that are needed to describe the colony contour with 99% fitness. An ad hoc function has been developed in Matlab v. 7.0 to automate the\ud
computation of the Fourier coefficients. In young colonies, Fi has a value between 2 (circumference) and 3 (ellipse). These values are maintained in mature colonies of Debaryomyces, but can reach values up to 14 in Saccharomyces.All the species studied showed the inhibition\ud
of growth in facing colony edges, but only three species showed edge irregularities associated with substrate exhaustion. Copyright © 2014 John Wiley & Sons, Ltd
Geometry and the quantum: basics

Motivated by the construction of spectral manifolds in noncommutative geometry, we introduce a higher degree Heisenberg commutation relation involving the Dirac operator and the Feynman slash of scalar fields. This commutation relation appears in two versions, one sided and two sided. It implies the quantization of the volume. In the one-sided case it implies that the manifold decomposes into a disconnected sum of spheres which will represent quanta of geometry. The two sided version in dimension 4 predicts the two algebras M 2 (ℍ) and M 4 (ℂ) which are the algebraic constituents of the Standard Model of particle physics. This taken together with the non-commutative algebra of functions allows one to reconstruct, using the spectral action, the Lagrangian of gravity coupled with the Standard Model. We show that any connected Riemannian Spin 4-manifold with quantized volume > 4 (in suitable units) appears as an irreducible representation of the two-sided commutation relations in dimension 4 and that these representations give a seductive model of the “particle picture” for a theory of quantum gravity in which both the Einstein geometric standpoint and the Standard Model emerge from Quantum Mechanics. Physical applications of this quantization scheme will follow in a separate publication
Lattice worldline representation of correlators in a background field

We use a discrete worldline representation in order to study the continuum limit of the one-loop expectation value of dimension two and four local operators in a background field. We illustrate this technique in the case of a scalar field coupled to a non-Abelian background gauge field. The first two coefficients of the expansion in powers of the lattice spacing can be expressed as sums over random walks on a d -dimensional cubic lattice. Using combinatorial identities for the distribution of the areas of closed random walks on a lattice, these coefficients can be turned into simple integrals. Our results are valid for an anisotropic lattice, with arbitrary lattice spacings in each direction
The role of power in financial statement fraud schemes

In this paper, we investigate a large-scale financial statement fraud to better understand the process by which individuals are recruited to participate in financial statement fraud schemes. The case reveals that perpetrators often use power to recruit others to participate in fraudulent acts. To illustrate how power is used, we propose a model, based upon the classical French and Raven taxonomy of power, that explains how one individual influences another individual to participate in financial statement fraud. We also provide propositions for future research
Moment tensor inversion of Explosive Long Period events recorded on Arenal Volcano, Costa Rica, constrained by synthetic tests

International audienceIn order to constrain the moment tensor solution of an explosive seismic event recorded on Arenal volcano, Costa Rica, we perform tests using synthetic data. These data are generated using a 3D model including the topography of the volcano and the best estimation of the velocity model available for Arenal. Solutions for (i) the moment tensor components, and (ii) the moment tensor plus single forces, are analyzed. When noisy data and mislocated sources are used in the inversion, spurious single forces are easily generated in the solution for the moment tensor components plus single forces. Forces also appear when the inversion is performed using an explosive event recorded on Arenal in 2005. Synthetic tests indicate that these forces might be spurious. However the mechanism is correctly retrieved by the inversion in both solutions. The ability to recover the explosive mechanism for the 2005 event combined with the interpretative aids from the synthetics tests will enable us to invert for the large variation in events observed on Arenal
Geochronology and geochemistry of Eocene-aged volcanic rocks around the Bafra (Samsun, N Turkey) area: Constraints for the interaction of lithospheric mantle and crustal melts

International audience40Ar-39Ar age, whole-rock chemical and Sr-Nd isotope data are presented for the post-collisional, Eocene (51.3-44.1 Ma)-aged volcanic rocks from the Bafra (Samsun) area in the western part of the Eastern Pontides (N Turkey) aiming to unravel their sources and evolutionary history. The studied Eocene volcanic rocks can be divided into two groups: analcime-bearing (tephritic lava flows and dykes) and analcime-free (basaltic to trachytic lava flows and basaltic dykes). The analcime-bearing volcanic rocks have a fine-grained porphyritic texture with clinopyroxene phenocrysts, whereas analcime-free volcanic rocks show a variety of textures including hyalo-microlitic microgranular porphyritic, intersertal, trachytic, fluidal and glomeroporphyritic. The volcanic rocks also show evidence of mineral-melt disequilibrium textures such as sieved, rounded and corroded plagioclases, partially melted and dissolved clinopyroxenes and poikilitic texture. Petrochemically, the parental magmas of the volcanic rocks evolved from alkaline to calc-alkaline lava suites and include high-K and shoshonitic compositions. They display enrichments in light rare earth and large ion lithophile elements such as Sr, K and Rb, as well as depletions in high field strength elements such as Nb, Ta, Zr and Ti, resembling subduction-related magmas. The analcime-bearing and -free volcanic rocks share similar incompatible element ratios and chondrite-normalised rare rearth element patterns, indicating that they originated from similar sources. They also have relatively low to moderate initial 87Sr/86Sr (0.7042 to 0.7051), high positive εNd(t) values (+ 0.20 to + 3.32), and depleted mantle Nd model ages (TDM1 = 0.63-0.93 Ga, TDM2 = 0.58–0.84 Ga). The bulk-rock chemical and Sr-Nd isotope features as well as the high Rb/Y and Th/Zr, but low Nb/Zr and Nb/Y ratios, indicate that the volcanic rocks were derived from a lithospheric mantle source that had been metasomatised by slab-derived fluids. Trace element modelling suggests that the parental magma(s) of the volcanic rocks represent mixtures of melts derived by low-degree (~ 5–10 %) partial melting of spinel-lherzolite (40–85%) and garnet-lherzolite (15–60 %) mantle sources. Sr-Nd isotopic modelling also suggests that a 25–35% lower crustal component was added in the parental magmas; AFC modelling additionally indicates minor upper crustal contamination during the evolution of the volcanic rocks. In conclusion, integration of the geochemical, petrologic and isotopic data with regional geology suggests that the analcime-bearing and -free volcanic rocks evolved from parental magma(s) derived from melts of a subcontinental lithospheric mantle and lower crustal sources