pinecone/core-2020-05-10-deduplication huggingface dataset:
A generalized Kiselev crossover approach applied to Soave–Redlich–Kwong equation of state

International audienceThree different variants of the crossover Soave–Redlich–Kwong equation of state are applied to describe the equilibrium behaviour of 72 common non-associating fluids – 27 hydrocarbons (including the first 10 n-alkanes), 36 halogenated refrigerants, 5 cryogenics (fluorine, oxygen, nitrogen, argon and carbon monoxide) and 4 other industrially important inorganic fluids (carbon dioxide, sulfur dioxide, nitrous oxide and sulfur hexafluoride). The model contains six compound dependent parameters.Two of them (a0 and b of the classical part) are adjusted on the critical experimental temperature and the critical pressure. In a first model denoted as model A, the four remaining parameters are fitted to describe the saturated liquid and vapour densities and vapor pressures as well as PVT data at pressures up to P = 3 × Pc. In the second model (model B), the dispersion softness m is expressed as a function of the acentric factor ω and a relation between two of the crossover parameters is employed; the number of fitted parameters is thus reduced to two. Based on model B, we suggested our final Model C, in which all the parameters can be determined from the critical point, acentric factor or rectlinear diameter. This model is superior to the classical Soave–Redlich–Kwong equation of state because it improves considerably the description of the liquid densities over the whole coexistence region. Contrary to equations of state optimized to reproduce the liquid densities at low temperatures, the crossover equation does not overpredict the critical temperature and pressure. Model C is applied to describe the equilibrium behaviour of two compounds not included in the parameterization, hexafluoropropene (HFO1216) and hexafluoropropene oxide (HFPO)
On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System

International audienceThe nature of liquid-solid phase equilibria in the Al-rich corner of the Al-Si-Ti system are determined by drawing three isothermal sections at 620, 680 and 727 C. The solubility of Ti in Al-Si liquids is determined for four different compositions (0, 9, 13 and 18 at.%Si) at temperature below 800 C. Combination of the two sets of experimental results leads to an attempt of liquidus projection. The primary crystallization surface of Al3Ti is found to extend up to 9.5 at.%Si in the liquid phase at 620 C and 11 at.%Si at 727 C. The solubility of Ti is found to be not significantly dependent on the Si content of the liquid. From DSC measurements and deduction on microstructure, the last invariant reaction of the solidification path is found to be quasi-peritectic: L + Tau1-Ti7Al5Si12 -> Al + Si
In vivo imaging of vessel diameter, size, and density: a comparative study between MRI and histology.
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Vessel diameter, size and density: MRI vs histology

International audienceThe aim of this study was to compare magnetic resonance imaging (MRI) and histological estimates of the mean vessel diameter (mVD), the vessel density (Density), and the vessel size index (VSI) obtained in the same tumor-bearing animals. Twenty-seven rats bearing intracranial glioma (C6 or RG2) were imaged by MRI. Changes in transverse relaxations (ΔR 2* and R(2)) were induced by the injection of an iron-based contrast agent and were mapped using a multi gradient-echo spin-echo sequence. Then, brain vascular network was studied ex vivo by histology. Three regions of interest were drawn in apparently normal tissue (neocortex and striatum) and in the tumor. In vivo mVD(MRI), Density(MRI), and VSI(MRI) were measured; ex vivo, mVD(histo), Density(histo), and VSI(histo) were quantified on the same animals. MRI and histology measurements differed by -15 to 26%. A positive correlation was found between MRI and histology for mVD, Density, and VSI counterparts (R(2) = 0.62, 0.50, 0.73, respectively; P < 0.001 in all cases). This study indicates that MRI and histology yields well correlated the estimates of mVD, Density, and VSI. VSI is the closest MRI estimate to histology. As Density and mVD or VSI provide complementary information, it is worth computing them to characterize angiogenesis beyond blood volume fraction
Altered synchrony and loss of consciousness during frontal lobe seizures

International audienceObjectiveLoss of consciousness (LOC) in frontal lobe epilepsy (FLE) has been rarely specifically studied until now. In this study we evaluated the LOC in a population of patients with FLE and studied the relationship between changes in synchrony and degree of LOC.Methods24 patients undergoing stereoelectroencephalography (SEEG) during pre-surgical evaluation of FLE were studied. The LOC intensity was scored using the Consciousness Seizure Scale (CSS). For each studied seizure (n = 52), interdependencies between signals recorded from 5 brain regions were estimated as a function of time by using non-linear regression analysis (h2 coefficient).ResultsSeizures were divided into 3 groups according to the CSS scale: group A (no LOC) with a score ⩽2, group B (intermediate or partial LOC) with a score ranging from 3 to 5, and group C (maximal LOC) with a score ⩾6. The majority of seizures in FLE patients disclosed significant LOC, particularly for patients with prefrontal lobe seizures. Mean correlation values were significantly different between groups A and C (p < 0.001), the maximal values of synchrony being observed in group C. Differences were significant for interaction affecting the external prefrontal cortex (p = 0.004) (p = 0.01) and the parietal cortex. In addition, a significant correlation was found between CSS scores and correlations values (h2) of the prefrontal and the parietal region but not with the premotor cortex.ConclusionsThis study indicates that in FLE, prefrontal seizures frequently alter consciousness. As in other focal seizures, LOC appears to be related to changes in synchrony in prefrontal and parietal associative cortices
Cold seeps along the main Marmara fault in the Sea of Marmara (Turkey)

International audienceThe main Marmara Fault exhibits numerous sites of fluid venting, observed during previous cruises and in particular with ROV VICTOR during the MARMARASCARPS cruise (2002). Long CALYPSO cores were recovered near active vents and at reference sites during the MARMARA-VT cruise (2004), together with echosounder sub-bottom profiles (frequency of 3.5 kHz). We compiled ROV video observations from MARMARASCARPS cruise and show that all known seeps occur in relationship with strike-slip faults, providing pathways for fluid migration. Among the main active sites, a distinction is made between gas seeps and water seeps. At gas seeps, bubble emissions at the seafloor or disturbed echofacies on sounder profiles demonstrate the presence of free methane gas at a shallow depth within the sediment. Most cores displayed gas related expansion, most intense for cores taken within the gas plumes. On the other hand, authigenic carbonate chimneys characterize the water seeps and visible water outflow was observed at two sites (in the Tekirdağ and Central basins). The pore fluid chemistry data show that the water expelled at these sites is brackish water trapped in the sediment during lacustrine times (before 14 cal Kyr BP), in relation with the paleoceanography in the Sea of Marmara. The chimney site in the Tekirdağ basin is located at the outlet of a canyon feeding a buried fan with coarse sandy turbidites. Pore fluid composition profiles indicate that the sand layers channel the brackish fluids laterally from the basin into the fault zone at less than 20 m depth. However, a deeper gas source cannot be excluded
Multi-scale strategy for high-k/metal-gate UTBB-FDSOI devices modeling with emphasis on back bias impact on mobility

International audienceMobility in high-k/metal-gate Ultra-Thin Body and Box Fully Depleted SOI devices has been extensively investigated by means of multi-scale simulations and experimental data. Split-CV mobility measurements have been performed for various Interfacial Layer Equivalent Oxide Thickness allowing an investigation of the physical mechanisms responsible for the mobility degradation at highk/ Interfacial layer interface. The impact of the back bias on transport properties is investigated and mobility enhancement in the reverse regime (back gate inversion) is studied. A multi-scale simulation strategy is ranging from quantum Non-equilibrium Green's Functions to semi-classical Kubo Greenwood approach. These advanced solvers made possible a throughout calibration of empirical TCAD mobility models
Observations of CO on Saturn and Uranus at millimeter wavelengths: New upper limit determinations

International audienceWe tried to detect CO lines at millimeter wavelength on Saturn and Uranus in order to better constrain the origin of this compound in the atmospheres of these planets. CO sources can be either of internal or of external origin. Methods. We recorded broad multi-band spectra of Saturn and Uranus at the frequencies of the J=1"0 and J=2"1 CO lines, at the IRAM 30m-telescope, Spain, using Lellouch et al. (2005) and Hesman et al. (2007) observing technique. Results. As we do not detect any CO line in the spectra, we derive new upper limits of the abundance of CO in the atmospheres of Saturn and Uranus. The value we obtain for Saturn (6.3×10−8, restricted to the stratosphere) is larger than the value of the CO mixing ratio in the external origin model of Noll & Larson (1991). New observations with better sensitivity and/or more observing time should enable us to state on the CO external source strength. The upper limit we derive on Uranus is slightly lower (2.7 × 10−8, restricted to the stratosphere) than the value derived from the first observation of CO on Uranus, at infrared wavelength, by Encrenaz et al. (2004). As their fluorescence model did not take scattering effects into account, we suggest that their value could be overestimated
Vacuum Casting to Manufacture a Plastic Biochip for Highly Parallel Cell Transfection

International audienceA novel polymer microarray fabrication technique is presented and applied to the realization of a biochip for highly parallelized cell transfection. The proposed microfabrication technique is derived from a macroscale rapid prototyping technique called vacuum casting. It was optimized to reduce production cost, in order to produce small series (100-10 000 chip series) of chips to meet demand in today's market of cellulomics. Microfabrication technologies and rapid prototyping technologies are combined to shape the master part, which can thus involve microsized features. The corresponding female structure is moulded in a flexible silicone material. The duplicated polymer chips are obtained by casting a thermosetting plastic under vacuum. The dimensional replication accuracy between the master part and the duplicated parts is uniform over the duplicated parts and better than 1%. Advantages of the proposed technique over existing plastic microfabrication techniques are discussed in the paper. Using this microfabrication technique, we produced a plastic biochip for highly parallelized transfection of arrays of living cells. The feasibility of parallel lipofection was demonstrated: two different plasmids encoding, respectively, eGFP and DsRED2 were inserted into HEK293T cells. The transfection was monitored through fluorescence observation after 72 h showing successful expression of both genes
A Raman Spectroscopic Study of Nitromethane up to 350 °C and 35 GPa

International audienceNitromethane has been studied as a model of the energetic nitro materials. The liquid - transition line has been established by Piermarini [1] and a first solid - solid transition corresponding to the methyl group rotation locking has been evidenced by Cromer [2]. In order to precise the phase diagram of nitromethane, a study has been performed by Raman scattering in the pressure and temperature range of 0 -35 GPa and 20 - 350°C respectively. From these experimental results three new solid phases of nitromethane called III, IV, V and their stability domain have been located. A first chemical transformation line has been detected by the disappearance of nitromethane Raman modes and by the irreversible formation of a transparent solid (CI). A second chemical transformation (CI - CII), at higher temperature, is observed by the sudden darkening of the sample
Geochemical investigation of a sediment core from the Trajan basin at Portus, the harbor of ancient Rome

International audiencea journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues. Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. In most cases authors are permitted to post their version of the article (e.g. in Word or Tex form) to their personal website or institutional repository. Authors requiring further information regarding Elsevier's archiving and manuscript policies are encouraged to visit: a b s t r a c t From the 1st century AD and for the duration of the Roman Empire, the Portus complex was the main harbor of Rome. Its location on the Tiber delta next to the Tyrrhenian Sea produced rapid environmental changes that, together with historical vicissitudes, largely determined the fate of the harbor. We have assembled data on the mineralogy, sedimentology, geochemistry, and ostracod populations of a sediment core drilled in the access channel of the hexagonal basin of Trajan, with the expectation that such a combined data set will shed new light on how the connections of the inland Trajan basin with the Tiber river, the earlier Claudius harbor on the nearby shoreline, and the sea evolved through the centuries. The data define four distinct periods which geochemistry characterizes by different conditions of salinity and oxygenation. These in turn can be related to historical periods and events by means of 1
A ~9 myr cycle in Cenozoicδ13C record and long-term orbital eccentricity modulation: Is there a link?

International audienceThe ~65-myr-long Cenozoic carbon isotope record (δ13C) of Zachos et al. (2001, 2008) documents a strong long-term cycle with a mean pseudoperiodicity close to ~ 9 myr. This cyclicity modulates the ~ 2.4 myr eccentricity cycle amplitude, hinting at a possible link between long-term astronomical and geological variations. Some phase shifts between ~9-myr δ13C and astronomical cycles suggest that additional processes (e.g., tectonics) contribute to these long-term carbon-cycle variations. The strong response of δ13C to long-term eccentricity periods (~9 myr, ~2.4 myr, ~400 kyr) supports the hypothesis that the long time-residence of carbon in the oceans amplifies lower frequency or dampens higher frequency orbital variations. Additionally, the strong expression of low-amplitude ~9 myr eccentricity cycle in theδ13C record could be explained by energy-transfer process from higher to lower frequency cycles, and all eccentricity components modulate the carrier climatic precession cycles. Finally, the Paleocene-Eocene Thermal Maximum (PETM, 55.9 Ma) event, which corresponds to a pronounced δ13C negative excursion, is situated within a strong decrease in the most prominent ~9 myr δ13C cycle, hinting at a link between accelerated rates in δ13C variations and the PETM. This specific ~9 myr δ13C cycle seems to be amplified by non-orbital mechanisms in atmosphere-continent-ocean system, such as previously suggested methane release from gas hydrate and volcanism
Simulation and analysis of solute transport in 2D fracture/pipe networks: The SOLFRAC program

International audienceThe Time Domain Random Walk (TDRW) method has been recently developed by Delay and Bodin (2001) and Bodin et al. (2003c) for simulating solute transport in discrete fracture networks. It is assumed that the fracture network can reasonably be represented by a network of interconnected one-dimensional pipes (i.e. flow channels). Processes accounted for are: (1) advection and hydrodynamic dispersion in the channels, (2) matrix diffusion, (3) diffusion into stagnant zones within the fracture planes, (4) sorption reactions onto the fracture walls and in the matrix, (5) linear decay, and (6) mass sharing at fracture intersections. The TDRW method is handy and very efficient in terms of computation costs since it allows for the one-step calculation of the particle residence time in each bond of the network. This method has been programmed in C++, and efforts have been made to develop an efficient and user-friendly software, called SOLFRAC. This program is freely downloadable at the URL http://labo.univ-poitiers.fr/hydrasa/intranet/telechargement.htm. It calculates solute transport into 2D pipe networks, while considering different types of injections and different concepts of local dispersion within each flow channel. Post-simulation analyses are also available, such as the mean velocity or the macroscopic dispersion at the scale of the entire network. The program may be used to evaluate how a given transport mechanism influences the macroscopic transport behaviour of fracture networks. It may also be used, as is the case, e.g., with analytical solutions, to interpret laboratory or field tracer test experiments performed in single fractures
Modelling of nonlinear circular plates using modal analysis: simulation and model validation

A method for simulating the large-displacement actuation of deformable micro-structures is proposed and illustrated in the case of a circular axisymmetric plate. First of all the problem is formulated and its boundary conditions are expressed as functions of the two unknowns, displacements and the Airy stress function. The problem is then split into two parts, each part corresponding to one equation of Von Karman, to which the techniques of modal analysis are applied in order to obtain a set of nonlinear ordinary differential equations. The implementation of the resulting high-level model is then discussed and some simulation results are given, as a basis for comparison
WISE-2005: effect of aerobic and resistive exercises on orthostatic tolerance during 60 days bed rest in women.
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Exercise Countermeasures and Orthostatic Intolerance

International audienceCardiovascular deconditioning after long duration spaceflight is especially challenging in women who have a lower orthostatic tolerance (OT) compared with men. We hypothesized that an exercise prescription, combining supine aerobic treadmill exercise in a lower body negative pressure (LBNP) chamber followed by 10 min of resting LBNP, three to four times a week, and flywheel resistive training every third day would maintain orthostatic tolerance (OT) in women during a 60-day head-down-tilt bed rest (HDBR). Sixteen women were assigned to two groups (exercise, control). Pre and post HDBR OT was assessed with a tilt/LBNP test until presyncope. OT time (mean +/- SE) decreased from 17.5 +/- 1.0 min to 9.1 +/- 1.5 min (-50 +/- 6%) in control group (P < 0.001) and from 19.3 +/- 1.3 min to 13.0 +/- 1.9 min (-35 +/- 7%) in exercise group (P < 0.001), with no significant difference in OT time between the two groups after HDBR (P = 0.13). Nevertheless, compared with controls post HDBR, exercisers had a lower heart rate during supine rest (mean +/- SE, 71 +/- 3 vs. 85 +/- 4, P < 0.01), a slower increase in heart rate and a slower decrease in stroke volume over the course of tilt/LBNP test (P < 0.05). Blood volume (mean +/- SE) decreased in controls (-9 +/- 2%, P < 0.01) but was maintained in exercisers (-4 +/- 3%, P = 0.17).Our results suggest that the combined exercise countermeasure did not significantly improve OT but protected blood volume and cardiovascular response to sub tolerance levels of orthostatic stress
Multisectoral climate impact hotspots in a warming world

The impacts of global climate change on different aspects of humanity's diverse life-support systems are complex and often difficult to predict. To facilitate policy decisions on mitigation and adaptation strategies, it is necessary to understand, quantify, and synthesize these climate-change impacts, taking into account their uncertainties. Crucial to these decisions is an understanding of how impacts in different sectors overlap, as overlapping impacts increase exposure, lead to interactions of impacts, and are likely to raise adaptation pressure. As a first step we develop herein a framework to study coinciding impacts and identify regional exposure hotspots. This framework can then be used as a starting point for regional case studies on vulnerability and multifaceted adaptation strategies. We consider impacts related to water, agriculture, ecosystems, and malaria at different levels of global warming. Multisectoral overlap starts to be seen robustly at a mean global warming of 3 degrees C above the 1980-2010 mean, with 11% of the world population subject to severe impacts in at least two of the four impact sectors at 4 degrees C. Despite these general conclusions, we find that uncertainty arising from the impact models is considerable, and larger than that from the climate models. In a low probability-high impact worst-case assessment, almost the whole inhabited world is at risk for multisectoral pressures. Hence, there is a pressing need for an increased research effort to develop a more comprehensive understanding of impacts, as well as for the development of policy measures under existing uncertainty
Alpha localized radiolysis and corrosion mechanisms at the iron/water interface: Role of molecular species

This paper is devoted to the iron corrosion phenomena induced by the α (4He2+) water radiolysis species studied in conjunction with the production/consumption of H2 at the solid/solution interface. On one hand, the solid surface is characterized during the 4He2+ ions irradiation by in situ Raman spectroscopy; on another hand, the H2 gas produced by the water radiolysis is monitored by ex situ gas measurements. The 4He2+ ions irradiation experiments are provided either by the CEMHTI (E = 5.0 MeV) either by the ARRONAX (E = 64.7 MeV) cyclotron facilities. The iron corrosion occurs only under irradiation and can be slowed down by H2 reductive atmosphere. Pure iron and carbon steel solids are studied in order to show two distinct behaviors of these surfaces vs. the 4He2+ ions water irradiation: the corrosion products identified are the magnetite phase (Fe(II)Fe(III)2O4) correlated to an H2 consumption for pure iron and the lepidocrocite phase (γ-Fe(III)OOH) correlated to an H2 production for carbon steel sample. This paper underlined the correlation between the iron corrosion products formation onto the solid surface and the H2 production/consumption mechanisms. H2O2 species is considered as the single water radiolytic species involved into the corrosion reaction at the solid surface with an essential role in the oxidation reaction of the iron surface. We propose to bring some light to these mechanisms, in particular the H2 and H2O2 roles, by the in situ Raman spectroscopy during and after the 4He2+ ions beam irradiation. This in situ experiment avoids the evolution of the solid surface, in particular phases which are reactive to the oxidation processing
The labor market participation of sandwich generation Italian women

We empirically analyzed the labor market participation of Italian women, with special emphasis on the role of intergenerational family links. Older relatives, on the one hand, discourage the work participation of women by requiring care; on the other hand they may provide household services favoring labor supply. We studied this dual impact estimating a trivariate probit model where the three choices to be in the labor force, to use informal help from older relatives and to care for them are jointly determined. Our estimates show that care duties towards members of the previous generation hinder the labor market participation of Italian women, and that informal help received from older relatives strongly increases their probability of being engaged in paid work