pinecone/core-2020-05-10-deduplication huggingface dataset:
Bias in bonding behavior among boron, carbon, and nitrogen atoms in ion implanted a-BN, a-BC, and diamond like carbon films

Cataloged from PDF version of article.In this study, we implanted N(+) and N(2)(+) ions into sputter deposited amorphous boron carbide (a-BC) and diamond like carbon (DLC) thin films in an effort to understand the chemical bonding involved and investigate possible phase separation routes in boron carbon nitride (BCN) films. In addition, we investigated the effect of implanted C(+) ions in sputter deposited amorphous boron nitride (a-BN) films. Implanted ion energies for all ion species were set at 40 KeV. Implanted films were then analyzed using x-ray photoelectron spectroscopy (XPS). The changes in the chemical composition and bonding chemistry due to ion-implantation were examined at different depths of the films using sequential ion-beam etching and high resolution XPS analysis cycles. A comparative analysis has been made with the results from sputter deposited BCN films suggesting that implanted nitrogen and carbon atoms behaved very similar to nitrogen and carbon atoms in sputter deposited BCN films. We found that implanted nitrogen atoms would prefer bonding to carbon atoms in the films only if there is no boron atom in the vicinity or after all available boron atoms have been saturated with nitrogen. Implanted carbon atoms also preferred to either bond with available boron atoms or, more likely bonded with other implanted carbon atoms. These results were also supported by ab-initio density functional theory calculations which indicated that carbon-carbon bonds were energetically preferable to carbon-boron and carbon-nitrogen bonds. (C) 2011 American Institute of Physics
Combining Spatiotemporal Corridor Design for Reindeer Migration with Harvest Scheduling in Northern Sweden

Reindeer husbandry and commercial forestry seek to co-exist in the forests of Northern Sweden. As interwoven as the two industries are, conflicts have arisen. Forest practices have reduced the distribution of lichen, the main winter diet for reindeer. Forest practices have also increased forest density, compromising the animals’ ability to pass through forested areas on their migration routes. In an attempt to reduce impacts on reindeer husbandry, we present a spatially explicit harvest scheduling model that includes reindeer corridors with user-defined spatial characteristics. We illustrate the model in a case study and explore the relationship between timber revenues and the selection and maintenance of reindeer corridors. The corridors are not only to include sufficient lichen habitat, but they are also supposed to ensure access for reindeer by connecting lichen areas with linkages that allow unobstructed travel. Since harvest scheduling occurs over a planning horizon, the spatial configuration of corridors can change from one time period to the next in order to accommodate harvesting activities. Our results suggest that maintaining reindeer corridors in harvest scheduling can be done at minimal cost. Also, we conclude that including corridor constraints in the harvest scheduling model is critical to guarantee connectivity of reindeer pastures
Extracting Models from Source Code in Software Modernization

International audienceModel-driven software modernization is a discipline in which model-driven development (MDD) techniques are used in the modernization of legacy systems. When existing software artifacts are evolved, they must be transformed into models to apply MDD techniques such as model transformations. Since most modernization scenarios (e.g., application migration) involve dealing with code in general-purpose programming languages (GPL), the extraction of models from GPL code is an essential task in a model-based modernization process. This activity could be performed by tools to bridge grammarware and MDD technical spaces, which is normally carried out by dedicated parsers. Grammar-to-Model Transformation Language (Gra2MoL) is a domain-specific language (DSL) tailored to the extraction of models from GPL code. This DSL is actually a text-to-model transformation language which can be applied to any code conforming to a grammar. Gra2MoL aims to reduce the effort needed to implement grammarware-MDD bridges, since building dedicated parsers is a complex and time-consuming task. Like ATL and RubyTL languages, Gra2MoL incorporates the binding concept needed to write mappings between grammar elements and metamodel elements in a simple declarative style. The language also provides a powerful query language which eases the retrieval of scattered information in syntax trees. Moreover, it incorporates extensibility and grammar reuse mechanisms. This paper describes Gra2MoL in detail and includes a case study based on the application of the language in the extraction of models from Delphi code
CHARACTERIZATION AND REACTIVITY OF SILICATIC CONSOLIDANS

In this study some results on the reactivity of silicatic consolidants employed for the conservation of valuable artistic and cultural\ud
porous materials are discussed. In particular, a colloidal suspension of silica made by particles with an average diameter of 10–\ud
15 nm, a sodium silicate and an ethyl silicate consolidant are studied. The chemical–physical characterization of xerogels achieved from\ud
the examined products were carried out determining the superficial area (BET method) and the average dimension of particles (SAXS)\ud
while the chemical structure of xerogels were investigated through NMR MAS spectroscopy of the 29Si nucleus. The investigation on\ud
reactivity between silica and stone support was executed by mixing consolidants with calcite and quartz powder to simplify as much\ud
as possible the system otherwise very complex. On silica produced by the three examined consolidants structural differences are revealed\ud
and these diversities can be responsible for the dissimilar reactivity of the silicatic systems towards the stone, in particular with regard to\ud
the carbonatic component
C-O-H fluid solubility in Haplo-basalt under reducing conditions: An experimental study

International audienceWe conducted an experimental study to constrain the C-H-O solubility and speciation in hydrous silicate melts equilibrated under reduced fO2 conditions. Haplo-basaltic glasses in the NCMAS-C-O-H system were synthesised using IHPV at 1250 °C, 200-300 MPa with variable applied fH2 so as to vary fO2. Recovered rapidly quenched glasses were characterized using various spectroscopic methods: Micro-FTIR, Raman and 13C-MAS NMR. Glass CO2 content changes from 680 to 1320 ppm between ΔFMQ-2.6 and ΔFMQ + 2.6 independently of H2O content changing from 1.3 to 4.0 wt.%. Recent thermodynamic modelling of isobaric CO2-H2O solubility fails to reproduce our CO2-H2O solubility trend under reducing conditions. The lower CO2 solubility in the melt as compared to more oxidized conditions is directly correlated to the decrease of fCO2 within the fluid phase under reducing conditions. Carbonate groups (CO32-), OH- and H2Omol are the volatile species in the glasses. No evidence for CH4, carbides or organic compounds was observed. 13C MAS NMR analysis suggests that several carbonate units are coexisting in the glasses. {1H} 13C-CPMAS NMR suggests that all CO32- units are surrounded by OH groups. Those environments appear to slightly change with changing fO2 conditions suggesting different degree of hydrogenation in the vicinity of the carbonate groups. Our data show that the presence of a significant amount of dissolved does not increase the solubility of species such as CO or CH4. In other words, such species remain insoluble in basaltic melts, as established under dry conditions. Altogether, our CO2 solubility results show that a wet but reduced basalt will degass more C-species than if oxidized, owing to the lower prevailing fCO2 and insoluble character of CO. The presence of an important fraction of CO in the fluid phase will have a large impact on the primitive atmospheric compositions of Mars and the Earth
Electrical conductivity of basaltic and carbonatite melt-bearing peridotites at high pressures: Implications for melt distribution and melt fraction in the upper mantle

International audienceElectrical impedance measurements were performed on two types of partial molten samples with basaltic and carbonatitic melts in a Kawai-type multi-anvil apparatus in order to investigate melt fraction-conductivity relationships and melt distribution of the partial molten mantle peridotite under high pressure. The silicate samples were composed of San Carlos olivine with various amounts of mid-ocean ridge basalt (MORB), and the carbonate samples were a mixture of San Carlos olivine with various amounts of carbonatite. High-pressure experiments on the silicate and carbonate systems were performed up to 1600 K at 1.5 GPa and up to at least 1650 K at 3 GPa, respectively. The sample conductivity increased with increasing melt fraction. Carbonatite-bearing samples show approximately one order of magnitude higher conductivity than basalt-bearing ones at the similar melt fraction. A linear relationship between log conductivity (σbulk) and log melt fraction (phi) can be expressed well by the Archie's law (Archie, 1942) (σbulk/σmelt = Cphin) with parameters C = 0.68 and 0.97, n = 0.87 and 1.13 for silicate and carbonate systems, respectively. Comparison of the electrical conductivity data with theoretical predictions for melt distribution indicates that the model assuming that the grain boundary is completely wetted by melt is the most preferable melt geometry. The gradual change of conductivity with melt fraction suggests no permeability jump due to melt percolation at a certain melt fraction. The melt fraction of the partial molten region in the upper mantle can be estimated to be 1-3% and not, vert, similar 0.3% for basaltic melt and carbonatite melt, respectively
Liquid phase immunoassay utilizing magnetic marker and high Tc superconducting quantum interference device

We have developed a liquid phase immunoassay system utilizing a magnetic marker and a superconducting quantum interference device (SQUID). In this system, the magnetic marker was used to detect the biological material called antigen. The magnetic marker was designed so as to generate a remanence, and the remanence field of the markers that bound to the antigens was measured with the SQUID. The measurement was performed in a solution that contained both the bound and free (or unbound) markers, i.e., without using the so-called bound/free (BF) separation process. The Brownian rotation of the free markers in the solution was used to distinguish the bound markers from the free ones. Using the system, we conducted the detection of biological material called IgE without BF separation. At present, we could detect the IgE down to 7  pg (or 39  amol
Topological formation of a multiply charged vortex in the Rb Bose-Einstein condensate: Effectiveness of the gravity compensation

In a Bose-Einstein condensate of^87Rb (F=2,mF=2) atoms we have topologically created a quantized vortex with a charge of 4 by reversing the magnetic field of the trap. Experimental conditions of reversal time and initial magnetic field strength for the successful vortex creation were restricted within narrower ranges, compared to those in the case of the ^23Na condensate. The experimental difficulty was explained in terms of a non-negligible gravitational sag arising from its large atomic mass. We have successfully stabilized the vortex formation by compensating gravity with a blue-detuned laser beam
Environmental effects on irradiation creep behavior of highly purified V-4Cr-4Ti alloys (NIFS-Heats) irradiated by neutrons

In order to investigate the effect of the environment on the irradiation creep properties of
	highly purified V-4Cr-4Ti alloys, neutron irradiation experiments with sodium-enclosed irradiation
	capsules in Joyo and lithium-enclosed irradiation capsules in HFIR-17J were carried out using
	pressurized creep tubes (PCTs).
	It was found that the creep strain rate exhibited a linear relationship with the effective stress
	up to 150 MPa at 458°C and 598°C in the Joyo irradiation experiments. For HFIR-17J irradiation
	at 425°C, the creep strain rate also exhibited a linear relationship with the effective stress up to
	150 MPa. The activation energy of the irradiation creep and irradiation creep stress factor were
	estimated to be 46 kJ/mol·K and 1 to 2, respectively. No significant difference in the irradiation
	creep behavior between liquid-sodium and liquid-lithium environments could be seen
Agency problems with non-smooth decision profiles: the case of monopoly under product quality

A method for dealing with monotonicity constraints in optimal control
problems is used to generalize some results in the context of monopoly theory, also extending the generalization to a large family of principal-agent programs. Our main conclusion is that many results on diverse economic topics, achieved under assumptions of continuity and piecewise differentiability in connection with the endogenous variables of the problem, still remain valid after replacing such assumptions by two minimal requirements
Reverse knowledge transfer in emerging market multinationals: The Indian context

© 2015 Elsevier Ltd This study examines knowledge acquisitions of Indian multinationals via overseas mergers and acquisitions. Specifically, the paper examines the effects of the perceived subsidiary capability, parent absorptive capacity, and the relevance of the target knowledge on reverse knowledge transfer. Using firm level data from a survey of Indian multinationals (with overseas acquisitions), we find that perceived subsidiary capability, knowledge relevance, and absorptive capacity positively influence reverse knowledge transfer. The results also highlight the moderating role of knowledge relevance and the mediating effects of absorptive capacity
Biomimetic Mineralization of Recombinamer-Based Hydrogels toward Controlled Morphologies and High Mineral Density

Producción CientíficaThe use of insoluble organic matrices as a structural template for the bottom-up fabrication of organic−inorganic nanocomposites is a powerful way to build a variety of advanced materials with deﬁned and controlled morphologies and superior mechanical properties. Calcium phosphate mineralization in polymeric hydrogels  is receiving signiﬁcant attention in terms  of obtaining biomimetic hierarchical structures with unique mechanical properties and understanding the mechanisms of the biomineralization process. However, integration of organic matrices with hydroxyapatite nanocrystals, diﬀerent in morphology and composition, has not been well-achieved yet at nanoscale. In this study, we synthesized thermoresponsive hydrogels, composed of elastin-like recombinamers (ELRs), to template mineralization of hydroxyapatite nanocrystals using a biomimetic polymer-induced liquid-precursor (PILP) mineralization process. Diﬀerent from conventional mineralization where minerals were deposited on the surface of organic matrices, they were inﬁltrated into the
frameworks of ELR matrices, preserving their microporous structure. After 14 days of mineralization, an average of 78 μm mineralization depth was achieved. Mineral density up to 1.9 g/cm3 was found after 28 days of mineralization, which is comparable to natural bone and dentin. In the dry state, the elastic modulus and hardness of the mineralized hydrogels were 20.3
± 1.7 and 0.93 ± 0.07 GPa, respectively. After hydration, they were reduced to 4.50 ± 0.55 and 0.10 ± 0.03 GPa, respectively.
These values were lower but still on the same order of magnitude as those of natural hard tissues. The results indicated that inorganic−organic hybrid biomaterials with controlled morphologies can be achieved using organic templates of ELRs. Notably, the chemical and physical properties of ELRs can be tuned, which might help elucidate the mechanisms by which living organisms regulate the mineralization process.Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA244U13
What explains corporate sukuk primary market spreads?

This study investigates the determining factors of international corporate sukuk pricing in the primary market for the period of 2004–2015. We present novel evidence for a unique data set covering all 63 international corporate sukuk issuances consisting of both a fixed margin rating as well a credit rating score. Our cross-sectional analysis indicates that both credit rating and maturity are significant factors which reduce issue spreads, whereas sukuk margin rating increases issue spreads. More prominently, Shari’ah scholar reputation and the type of sukuk are not statistically significant factors in the explanation of the issue spread. Our results are comparable with determinants of conventional bond pricing, and our findings further confirm existing sukuk market practices
Minimal basilar membrane motion in low-frequency hearing

Low-frequency hearing is critically important for speech and music perception, but no mechanical measurements have previously been available from inner ears with intact low-frequency parts. These regions of the cochlea may function in ways different from the extensively studied high-frequency regions, where the sensory outer hair cells produce force that greatly increases the sound-evoked vibrations of the basilar membrane. We used laser interferometry in vitro and optical coherence tomography in vivo to study the low-frequency part of the guinea pig cochlea, and found that sound stimulation caused motion of a minimal portion of the basilar membrane. Outside the region of peak movement, an exponential decline in motion amplitude occurred across the basilar membrane. The moving region had different dependence on stimulus frequency than the vibrations measured near the mechanosensitive stereocilia. This behavior differs substantially from the behavior found in the extensively studied high-frequency regions of the cochlea
Supporting primary teachers to teach children physical: continuing the journey

Little attention was paid to professional development of primary teachers in Ireland to support them in teaching physical education (PE) until 2004 when specific support was provided to help them implement the revised Primary Physical Education Curriculum. A significant National In-service Physical Education Programme was undertaken involving the preparation of a cohort of tutors who were to facilitate the programme to all primary teachers. This study focuses on the findings from a study of the effectiveness of the programme from the tutors’ and teachers’ perspectives beginning with the preparation of the tutors for facilitation of the programme. Elements of good practice emerged that can inform future policy with regard to support of primary teachers teaching PE within the constraints of funding. These include (1) the importance of quality preparation of tutors acknowledging the advantage of technology that may provide a new and cost effective way of supporting them, and (2) retaining the practical exploration of content by both tutors and teachers that prompts reflection on the nature and content of programmes of PE
Pairwise dichotomous cohesiveness measures

Producción CientíficaAbstract In a framework where experts or agents express their opinions in a dichotomous way, we analyze the cohesiveness of their opinions on axed set of issues in a population. A parametric family of related measures are introduced and axiomatically characterized. They are ordinally equivalent when the population isxed, and some further properties are proved. In order to argue that this restricted dichotomous situation is nevertheless versatile, the paper ends with several empirical illustrations based on real forecasts (for the 2012 American presidential election) and elections (with real data from referenda in two countries and from elections in several scientic societies).Ministerio de Economía, Industria y Competitividad (Project ECO2012-31933)Ministerio de Economía, Industria y Competitividad (Project ECO2012-32178)Ministerio de Economía, Industria y Competitividad (Proyect CGL2008-06003-C03-03/CLI)Ministerio de Economía, Industria y Competitividad (Project CGL2011-29396-C03-02)
p-exponent and p-leaders, Part II: Multifractal Analysis. Relations to Detrended Fluctuation Analysis

Multifractal analysis studies signals, functions, images or fields via the fluctuations of their local regularity along time or space, which capture crucial features of their temporal/spatial dynamics. It has become a standard signal and image processing tool and is commonly used in numerous applications of different natures. In its common formulation, it relies on the H\"older exponent as a measure of local regularity, which is by nature restricted to positive values and can hence be used for locally bounded functions only. In this contribution, it is proposed to replace the H\"older exponent with a collection of novel exponents for measuring local regularity, the p-exponents. One of the major virtues of p-exponents is that they can potentially take negative values. The corresponding wavelet-based multiscale quantities, the p-leaders, are constructed and shown to permit the definition of a new multifractal formalism, yielding an accurate practical estimation of the multifractal properties of real-world data. Moreover, theoretical and practical connections to and comparisons against another multifractal formalism, referred to as multifractal detrended fluctuation analysis, are achieved. The performance of the proposed p-leader multifractal formalism is studied and compared to previous formalisms using synthetic multifractal signals and images, illustrating its theoretical and practical benefits. The present contribution is complemented by a companion article studying in depth the theoretical properties of p-exponents and the rich classification of local singularities it permits
Antisymmetric multi-partite quantum states and their applications

Entanglement is a powerful resource for processing quantum information. In this context pure, maximally entangled states have received considerable attention. In the case of bipartite qubit-systems the four orthonormal Bell-states are of this type. One of these Bell states, the singlet Bell-state, has the additional property of being antisymmetric with respect to particle exchange. In this contribution we discuss possible generalizations of this antisymmetric Bell-state to cases with more than two particles and with single-particle Hilbert spaces involving more than two dimensions. We review basic properties of these totally antisymmetric states. Among possible applications of this class of states we analyze a new quantum key sharing protocol and methods for comparing quantum states
Identifying Jumps in Financial Assets: a Comparison between Nonparametric Jump Tests

We perform a comprehensive Monte Carlo comparison between nine alternative procedures available in the literature to detect jumps in financial assets using high-frequency data. We evaluate size and power properties of the procedures under alternative sampling frequencies, persistence in volatility, jump size and intensity, and degree of contamination with microstructure noise. The overall best performance is shown by the Andersen, Bollerslev, and Dobrev (2007 ) and Lee and Mykland (2008 ) intraday procedures (ABD-LM), provided the price process is not very volatile. We propose two extensions to the existing battery of tests. The first regards the finite sample improvements based on simulated critical values for the ABD-LM procedure. The second regards a procedure that combines frequencies and tests able to reduce the number of spurious jumps. Finally, we report an empirical analysis using real high frequency data on five stocks listed in the New York Stock Exchange