pinecone/core-2020-05-10-deduplication huggingface dataset:
Analytic Kramer kernels, Lagrange-type interpolation series and de Branges spaces

The classical Kramer sampling theorem provides a method for obtaining orthogonal sampling formulas. In particular, when the involved kernel is analytic in the sampling parameter it can be stated in an abstract setting of reproducing kernel Hilbert spaces of entire functions which includes as a particular case the classical Shannon sampling theory. This abstract setting allows us to obtain a sort of converse result and to characterize when the sampling formula associated with an analytic Kramer kernel can be expressed as a Lagrange-type interpolation series. On the other hand, the de Branges spaces of entire functions satisfy orthogonal sampling formulas which can be written as Lagrange-type interpolation series. In this work some links between all these ideas are established
Overview of the JET results in support to ITER

The 2014–2016 JET results are reviewed in the light of their significance for optimising the ITER research plan for the active and non-active operation. More than 60 h of plasma operation with ITER first wall materials successfully took place since its installation in 2011. New multi-machine scaling of the type I-ELM divertor energy flux density to ITER is supported by first principle modelling. ITER relevant disruption experiments and first principle modelling are reported with a set of three disruption mitigation valves mimicking the ITER setup. Insights of the L–H power threshold in Deuterium and Hydrogen are given, stressing the importance of the magnetic configurations and the recent measurements of fine-scale structures in the edge radial electric. Dimensionless scans of the core and pedestal confinement provide new information to elucidate the importance of the first wall material on the fusion performance. H-mode plasmas at ITER triangularity (H  =  1 at β N ~ 1.8 and n/n GW ~ 0.6) have been sustained at 2 MA during 5 s. The ITER neutronics codes have been validated on high performance experiments. Prospects for the coming D–T campaign and 14 MeV neutron calibration strategy are reviewed
Kinetics and dynamics of O + OClO reaction in a modified many-body expansion potential energy surface for ClO3

The ClO3 many-body expansion potential energy surface of Farantos and Murrell (Int J Quantum Chem 1978, 14, 659) has been modified along the minimum energy path for the reaction O + OClO rarr ClO + O2 such as to conform with the available kinetics data. The dynamics of the title reaction is also studied for temperatures of relevance in stratospheric chemistry. Two mechanisms for ClO + O2 formation are identified: (i) direct abstraction of a terminal oxygen atom from the OClO reactant and (ii) formation of an intermediate ClO3 complex followed by dissociation. The novel potential energy surface gives also a good description of the kinetics of the reaction Cl + O3 rarr ClO + O2. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 422-430, 2007http://dx.doi.org/10.1002/kin.2025
Influence of the isomeric structures of butyl acrylate on its single-electron transfer-degenerative chain transfer living radical polymerization in water Catalyzed by Na2S2O4

The aim of this work is to the study the influence of the isomer structures of butyl acrylate monomer on the single-electron transfer/degenerative chain transfer mediated living radical polymerization (SET-DTLRP). The kinetic of isobutyl acrylate is determined for the first time by SET-DTLRP in water catalyzed by sodium dithionite. The plots of number-average molecular weight versus conversion and ln([M]0/[M]) versus time are linear, demonstrating a controlled polymerization. The influence of the isomer t-butyl, i-butyl, and n-butyl on the kinetics, properties, and stereochemistry of the reactions was assessed. To the best of our knowledge, there is no previous report dealing with the synthesis of PiBA by any LRP approach in aqueous medium. The results presented in this work suggest that the stability provided by the acrylate side group has an important influence in the polymerization process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6542-6551, 2008http://dx.doi.org/10.1002/pola.2296
New insight into the discrimination between omeprazole enantiomers by cyclodextrins in aqueous solution

We report results regarding the use of 1H-NMR spectroscopy in the study of the conformational behaviour and optical activity of omeprazole. Changes in the chemical shifts of chosen atoms reveal that the conformational behaviour of omeprazole is temperature and pH sensitive. Separation and identification of omeprazole enantiomers in the presence of natural and derivative cyclodextrins, such as ß-cyclodextrin (ßCD) and methyl-ß-cyclodextrin (MßCD) are achieved using 1H-NMR spectroscopy, with information from molecular dynamics simulation. This work shows that ßCD includes preferentially R-(–)-omeprazole, acting as a chiral selector. This discrimination of omeprazole enantiomers by cyclodextrins allows development of pharmaceutical formulations with a better bioavailability profile.http://dx.doi.org/10.1007/s10847-008-9477-
Inkjet printed LED based pH chemical sensor for gas sensing

Predictable behaviour is a critical factor when developing a sensor for potential deployment within a wireless sensor network (WSN). The work presented here details the fabrication and performance of an optical chemical sensor for gaseous acetic acid analysis, which was constructed using inkjet printed deposition of a colorimetric chemical sensor. The chemical sensor comprised a pH indicator dye (bromophenol blue), phase transfer salt tetrahexylammonium bromide and polymer ethyl cellulose dissolved in 1-butanol. A paired emitter-detector diode (PEDD) optical detector was employed to monitor responses of the colorimetric chemical sensor as it exhibits good sensitivity, low power consumption, is low cost, accurate and has excellent signal to noise ratios. The chemical sensor formulation was printed directly onto the surface the emitter LED, and the resulting chemical sensors characterised with respect to their layer thickness, response time and recovery time. The fabrication reproducibility of inkjet printed chemical sensors in comparison to drop casted chemical sensors was investigated. Colorimetric chemical sensors produced by inkjet printing, exhibited an improved reproducibility for the detection of gaseous acetic acid with a relative standard deviation of 5.5 % in comparison to 68.0 % calculated for drop casted sensors (n = 10). The stability of the chemical sensor was also investigated through both intra and inter-day studies
Performance assessment of a kinetically-powered network for herd localization

Developing a herd localization system capable to operate unattended in communication-challenged areas arises from the necessity of improving current systems in terms of cost, autonomy or any other facilities that a certain target group (or overall users) may demand. A network architecture of herd localization is proposed with its corresponding hardware and a methodology to assess performance in different operating conditions. The system is designed taking into account an eventual environmental impact hence most nodes are simple, cheap and kinetically powered from animal movements-neither batteries nor sophisticated processor chips are needed. Other network elements integrating GPS and batteries operate with selectable duty cycles, thus reducing maintenance duties. Equipment has been tested on Scandinavian reindeer in Lapland and its element modeling is integrated into a simulator to analyze such localization network applicability for different use cases. Performance indicators (detection frequency, localization accuracy and delay) are fitted to assess the overall performance; system relative costs are enclosed also for a range of deployments
CCD image sensor induced error in PIV applications

The readout procedure of charge-coupled device (CCD) cameras is known to generate some image degradation in different scientific imaging fields, especially in astrophysics. In the particular field of particle image velocimetry (PIV), widely extended in the scientific community, the readout procedure of the interline CCD sensor induces a bias in the registered position of particle images. This work proposes simple procedures to predict the magnitude of the associated measurement error. Generally, there are differences in the position bias for the different images of a certain particle at each PIV frame. This leads to a substantial bias error in the PIV velocity measurement (~0.1 pixels). This is the order of magnitude that other typical PIV errors such as peak-locking may reach. Based on modern CCD technology and architecture, this work offers a description of the readout phenomenon and proposes a modeling for the CCD readout bias error magnitude. This bias, in turn, generates a velocity measurement bias error when there is an illumination difference between two successive PIV exposures. The model predictions match the experiments performed with two 12-bit-depth interline CCD cameras (MegaPlus ES 4.0/E incorporating the Kodak KAI-4000M CCD sensor with 4 megapixels). For different cameras, only two constant values are needed to fit the proposed calibration model and predict the error from the readout procedure. Tests by different researchers using different cameras would allow verification of the model, that can be used to optimize acquisition setups. Simple procedures to obtain these two calibration values are also described
Building an IT service catalog in a small company as the main input for the IT financial management

IT departments in non-IT small companies lack guidelines for defining the services they provide and for assigning costs to these services. This article compares international models and standards and describes an approach that can be used by these companies in order to define and implement their service catalog to be used as an input for their IT financial management. The proposed solution is based on the concept of a process asset library. The proposal has been tested in a non-IT small company. The results provide useful insights for companies interested in defining their own service catalog from a standard service catalog
Moral development in sports at school age: Towards a fair play behaviours typology expressed in the White Card (Tarjeta Blanca) programme

This paper aims to contribute to a better understanding of the moral development in sports at school age. A fair play behaviours typology has been developed, arranged into five stages of ethical progress and performed by young athletes within the White Card programme at the Fundación Real Madrid (FRM) basketball schools. In order to ascertain its validity, descriptions of the behaviours were submitted to the coaches at the FRM (n = 18), and a group of experts in sports and values from the actual FRM (n = 6) in order to rate them on a scale from 1 to 5 depending on the moral value they attribute. The result obtained confirm, with few exceptions, the five proposed stages of progression.
Production of neutron-rich fragments with neutron number N > Nprojectile in the reaction $^{48}$Ca (60 MeV/nucleon) + Ta

Expérience GANIL, Spectrometre LISEInternational audienceThe goal of the present paper is to attempt to clarify the nuclear reaction mechanism leading to the production of fragments at zero degree with neutron number larger than that in the 48Ca projectile, at about 60 MeV per nucleon. The production cross sections of the extremely neutron-rich Si and P isotopes were measured. Concerning the nuclear reaction mechanism leading to the production of these isotopes, one should probably refer to a particular type of transfer mechanism, which results in low excitation energy for the fragments, rather than to the ‘genuine' fragmentation mechanism. An upper limit of about 0.05 pb was estimated for the production cross section for the 47P isotope for which no count was observed
Giant monopole resonance in Pb isotopes

4 pagesInternational audienceThe extraction of the nuclear incompressibility from the isoscalar giant monopole resonance (GMR) measurements is analysed. Both pairing and mutually enhanced magicity (MEM) effects play a role in the shift of the GMR energy between the doubly closed shell $^{208}$Pb nucleus and other Pb isotopes. Pairing effects are microscopically predicted whereas the MEM effect is phenomenologically evaluated. Accurate measurements of the GMR in open-shell Pb isotopes are called for
Direct illumination LED calibration for telescope photometry

Accepted by Nuclear Inst. and Methods in Physics Research, A NIMAA calibration method for telescope photometry, based on the direct illumination of a telescope with a calibrated light source regrouping multiple LEDs, is proposed. Its purpose is to calibrate the instrument response. The main emphasis of the proposed method is the traceability of the calibration process and a continuous monitoring of the instrument in order to maintain a 0.2% accuracy over a period of years. Its specificity is to map finely the response of the telescope and its camera as a function of all light ray parameters. This feature is essential to implement a computer model of the instrument representing the variation of the overall light collection efficiency of each pixel for various filter configurations. We report on hardware developments done for SNDICE, the first application of this direct illumination calibration system which will be installed in Canada France Hawaii telescope (CFHT) for its leading supernova experiment (SNLS)
Global non-rigid alignment of surface sequences

This paper presents a general approach based on the shape similarity tree for non-sequential alignment across databases of multiple unstructured mesh sequences from non-rigid surface capture. The optimal shape similarity tree for non-rigid alignment is defined as the minimum spanning tree in shape similarity space. Non-sequential alignment based on the shape similarity tree minimises the total non-rigid deformation required to register all frames in a database into a consistent mesh structure with surfaces in correspondence. This allows alignment across multiple sequences of different motions, reduces drift in sequential alignment and is robust to rapid non-rigid motion. Evaluation is performed on three benchmark databases of 3D mesh sequences with a variety of complex human and cloth motion. Comparison with sequential alignment demonstrates reduced errors due to drift and improved robustness to large non-rigid deformation, together with global alignment across multiple sequences which is not possible with previous sequential approaches. © 2012 The Author(s)
Synthesis and characterization of new aromatic polyamides bearing crown ethers and acyclic ethylene oxide units in the pendant structure. III. Benzo-18-crown-6 systems and their open-chain counterparts

We report the synthesis and characterization of 10 novel polyamides containing the benzo-18-crown-6 subunit and its dipodal counterpart, along with their properties, and a comparison with homologous polyamides bearing benzo-12-crown-4, benzo-15-crown-5, and the corresponding dipodal systems. The anomalous polymerization of some of the diacid monomers, that leads to insoluble gels under standard Yamazaki polymerization conditions, is described. The gel formation has been attributed to the threading of cyclic oligoamides with a growing polyamide chain to yield rotaxanes, polyrotaxanes, catenanes, or polycatenanes. Polyamide macrocycles have been characterized with matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. A route to avoid gel formation, consisting of a lower initial monomer concentration, is also described, along with the polymer properties of the polyamides obtained, including the chemical characterization, mechanical behavior, water sorption, morphology, diffusion data, and permeability of membranes prepared with these polymers. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6252-6269, 2006http://dx.doi.org/10.1002/pola.2171
Population structure and species dynamics of Spisula solida, Diogenes pugilator and Branchiostoma lanceolatum along a temporal–spatial gradient in the south coast of Portugal

The population structure, dynamics and distribution of Spisula solida, Diogenes pugilator and Branchiostoma lanceolatum, common species in the south coast of Portugal, were studied in a spatial–temporal manner in order to understand the influence of cross-shore sediment transport and anthropogenic activities. Spisula solida is harvested commercially, whereas D. pugilator and B. lanceolatum are non-target species, with little information available on the population dynamics of these species. The study was performed in 2001–2002, and along a gradient of 100–5000 m from the coastline, corresponding to a depth gradient of between 1 and 32 m deep. Spisula solida was distributed preferentially at 3–12 m deep, and its distribution appeared to be influenced seasonally by the cross-shore sediment dynamics. Results suggested benthic recruitment in June. Some recruitments had no expression (year 2001) since adults were not present, which seems to be a direct impact of clams' fisheries. Diogenes pugilator showed preferential distribution at shallow depths, from 1.3 to 8 m. Results suggested recruitments every 4 months, in June, February and October. Branchiostoma lanceolatum showed the widest distribution, from 7 to 26 m deep. Recruitment seemed to start in June until October, when it attained an abundance peak of juveniles. For both non-target species no clear effects of the cross-shore dynamics or the clams' fisheries impact were visiblehttp://dx.doi.org/10.1016/j.ecss.2005.08.00
Nonlinear response to ultrasound of encapsulated microbubbles

The acoustic backscatter of encapsulated gas-filled microbubbles immersed in a weak compressible liquid and irradiated by ultrasound fields of moderate to high pressure amplitudes is investigated theoretically. The problem is formulated by considering, for the viscoelastic shell of finite thickness, an isotropic hyperelastic neo-Hookean model for the elastic contribution in addition to a Newtonian viscous component. First and second harmonic scattering cross-sections have been evaluated and the quantitative influence of the driving pressure amplitude on the harmonic resonance frequencies for different initial equilibrium bubble sizes and for different encapsulating physical properties has been determined. Conditions for optimal second harmonic imaging have been also investigated and some regions in the parameters space where the second harmonic intensity is dominant over the fundamental have been identified. Results have been obtained for albumin, lipid and polymer encapsulating shells, respectively
Universal conservation law and modified Noether symmetry in 2d models of gravity with matter

It is well-known that all 2d models of gravity---including theories with nonvanishing torsion and dilaton theories---can be solved exactly, if matter interactions are absent. An absolutely (in space and time) conserved quantity determines the global classification of all (classical) solutions. For the special case of spherically reduced Einstein gravity it coincides with the mass in the Schwarzschild solution. The corresponding Noether symmetry has been derived previously by P. Widerin and one of the authors (W.K.) for a specific 2d model with nonvanishing torsion. In the present paper this is generalized to all covariant 2d theories, including interactions with matter. The related Noether-like symmetry differs from the usual one. The parameters for the symmetry transformation of the geometric part and those of the matterfields are distinct. The total conservation law (a zero-form current) results from a two stage argument which also involves a consistency condition expressed by the conservation of a one-form matter ``current''. The black hole is treated as a special case
Noncyclic geometric phase for neutrino oscillation

We provide explicit formulae for the noncyclic geometric phases or Pancharatnam phases of neutrino oscillations. Since Pancharatnam phase is a generalization of the Berry phase, our results generalize the previous findings for Berry phase in a recent paper [Phys. Lett. B, 466 (1999) 262]. Unlike the Berry phase, the noncyclic geometric phase offers distinctive advantage in terms of measurement and prediction. In particular, for three-flavor mixing, our explicit formula offers an alternative means of determining the CP-violating phase. Our results can also be extended easily to explore geometric phase associated with neutron-antineutron oscillations
Finitely Many Dirac-Delta Interactions on Riemannian Manifolds

This work is intended as an attempt to study the non-perturbative
renormalization of bound state problem of finitely many Dirac-delta
interactions on Riemannian manifolds, S^2, H^2 and H^3. We formulate the
problem in terms of a finite dimensional matrix, called the characteristic
matrix. The bound state energies can be found from the characteristic equation.
The characteristic matrix can be found after a regularization and
renormalization by using a sharp cut-off in the eigenvalue spectrum of the
Laplacian, as it is done in the flat space, or using the heat kernel method.
These two approaches are equivalent in the case of compact manifolds. The heat
kernel method has a general advantage to find lower bounds on the spectrum even
for compact manifolds as shown in the case of S^2. The heat kernels for H^2 and
H^3 are known explicitly, thus we can calculate the characteristic matrix.
Using the result, we give lower bound estimates of the discrete spectrum.Comment: To be published in JM
Comparative RNAi Screening Identifies a Conserved Core Metazoan Actinome by Phenotype

Although a large number of actin-binding proteins and their regulators have been identified through classical approaches, gaps in our knowledge remain. Here, we used genome-wide RNA interference as a systematic method to define metazoan actin regulators based on visual phenotype. Using comparative screens in cultured Drosophila and human cells, we generated phenotypic profiles for annotated actin regulators together with proteins bearing predicted actin-binding domains. These phenotypic clusters for the known metazoan "actinome" were used to identify putative new core actin regulators, together with a number of genes with conserved but poorly studied roles in the regulation of the actin cytoskeleton, several of which we studied in detail. This work suggests that although our search for new components of the core actin machinery is nearing saturation, regulation at the level of nuclear actin export, RNA splicing, ubiquitination, and other upstream processes remains an important but unexplored frontier of actin biology
Comparison of stabilization by Vitamin E and 2,6-di-tert-butylphenols during polyethylene radio-thermal-oxidation

This paper reports a compilation of data for PE+Vitamin E and 2,6-di-tert-butylphenols oxidation in radio-thermal ageing. Data unambiguously show that Vitamin E reacts with P° and POO° whereas 2,6-di-tert-butyl phenols only react with POO°. Kinetic parameters of the stabilization reactions for both kinds of antioxidants were tentatively extracted from phenol depletion curves, and discussed regarding the structure of the stabilizer. They were also used for completing an existing kinetic model used for predicting the stabilization by antioxidants. This one permits to compare the efficiency of stabilizer with dose rate or sample thickness