pinecone/core-2020-05-10-deduplication huggingface dataset:
Simple scalings for various regimes of electron acceleration in surface plasma waves

International audienceDifferent electron acceleration regimes in the evanescent field of a surface plasma wave are studied by considering the interaction of a test electron with the high-frequency electromagnetic field of a surface wave. The non-relativistic and relativistic limits are investigated. Simple scalings are founddemonstrating the possibility to achieve an efficient conversion of the surface wave field energy into electron kinetic energy. This mechanism of electron acceleration can provide a high-frequency pulsed source of relativistic electrons with a well defined energy. In the relativistic limit, the most energetic electrons are obtained in the so-called electromagnetic regime for surface waves. In this regime, the particles are accelerated to velocities larger than the wave phase velocity, mainly in the direction parallel to the plasma-vacuum interface
O-Glycosylation of the N-terminal region of the serine-rich adhesin Srr1 of Streptococcus agalactiae explored by mass spectrometry.

International audienceSerine-rich (Srr) proteins exposed at the surface of Gram-positive bacteria are a family of adhesins that contribute to the virulence of pathogenic staphylococci and streptococci. Lectin-binding experiments have previously shown that Srr proteins are heavily glycosylated. We report here the first mass-spectrometry analysis of the glycosylation of Streptococcus agalactiae Srr1. After Srr1 enrichment and trypsin digestion, potential glycopeptides were identified in collision induced dissociation spectra using X! Tandem. The approach was then refined using higher energy collisional dissociation fragmentation which led to the simultaneous loss of sugar residues, production of diagnostic oxonium ions and backbone fragmentation for glycopeptides. This feature was exploited in a new open source software tool (SpectrumFinder) developed for this work. By combining these approaches, 27 glycopeptides corresponding to six different segments of the N-terminal region of Srr1 [93-639] were identified. Our data unambiguously indicate that the same protein residue can be modified with different glycan combinations including N-acetylhexosamine, hexose, and a novel modification that was identified as O-acetylated-N-acetylhexosamine. Lectin binding and monosaccharide composition analysis strongly suggested that HexNAc and Hex correspond to N-acetylglucosamine and glucose, respectively. The same protein segment can be modified with a variety of glycans generating a wide structural diversity of Srr1. Electron transfer dissociation was used to assign glycosylation sites leading to the unambiguous identification of six serines and one threonine residues. Analysis of purified Srr1 produced in mutant strains lacking accessory glycosyltransferase encoding genes demonstrates that O-GlcNAcylation is an initial step in Srr1 glycosylation that is likely required for subsequent decoration with Hex. In summary, our data obtained by a combination of fragmentation mass spectrometry techniques associated to a new software tool, demonstrate glycosylation heterogeneity of Srr1, characterize a new protein modification, and identify six glycosylation sites located in the N-terminal region of the protein
Building the electrical model of the Photoelectric Laser Stimulation of a PMOS transistor in 90nm technology

International audienceThis paper presents the electrical model of a PMOS transistor in 90nm technology under 1064nm Photoelectric Laser Stimulation. The model was built and tuned from measurements made on test structures. It permits to simulate theeffectofacontinuous wave laser on a PMOS transistor by taking into account the laser's parameters (i.e. spot size and location, orpower)andthePMOS'geometryandbias. It offers a significant gain of time by comparison with experiments and makes possible to build 3D photocurrent cartographies generated by the laser on the PMOS
Genome structure and metabolic features in the red seaweed Chondrus crispus shed light on evolution of the Archaeplastida.

International audienceRed seaweeds are key components of coastal ecosystems and are economically important as food and as a source of gelling agents, but their genes and genomes have received little attention. Here we report the sequencing of the 105-Mbp genome of the florideophyte Chondrus crispus (Irish moss) and the annotation of the 9,606 genes. The genome features an unusual structure characterized by gene-dense regions surrounded by repeat-rich regions dominated by transposable elements. Despite its fairly large size, this genome shows features typical of compact genomes, e.g., on average only 0.3 introns per gene, short introns, low median distance between genes, small gene families, and no indication of large-scale genome duplication. The genome also gives insights into the metabolism of marine red algae and adaptations to the marine environment, including genes related to halogen metabolism, oxylipins, and multicellularity (microRNA processing and transcription factors). Particularly interesting are features related to carbohydrate metabolism, which include a minimalistic gene set for starch biosynthesis, the presence of cellulose synthases acquired before the primary endosymbiosis showing the polyphyly of cellulose synthesis in Archaeplastida, and cellulases absent in terrestrial plants as well as the occurrence of a mannosylglycerate synthase potentially originating from a marine bacterium. To explain the observations on genome structure and gene content, we propose an evolutionary scenario involving an ancestral red alga that was driven by early ecological forces to lose genes, introns, and intergenetic DNA; this loss was followed by an expansion of genome size as a consequence of activity of transposable elements
High performance of symmetric micro supercapacitors based on silicon nanowires using N-methyl-N-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide as electrolyte

This work describes the development and performance of a symmetric microsupercapacitor made of nanostructured electrodes based on silicon nanowires (SiNWs) deposited using chemical vapor deposition (CVD) on silicon substrates. The performance of the SiNWs micro-supercapacitor employing an aprotic ionic liquid (N-methyl-N-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide) (PYR13TFSI) as an electrolyte was able to deliver a maximal power density of 182 mW cm-2 and a specific energy of 190 µJ cm-2 operating at a wide cell voltage of 4V with a quasi-ideal capacitive behaviour. The lifetime of the device exhibited a remarkable electrochemical stability retaining 75 % of the initial capacitance after several million galvanostatic charge-discharge cycles at a high current density of 1 mA cm-2. Furthermore, a coulombic efficiency of approximately 99 % was obtained after galvanostatic cycling test without structural degradation on the morphology of SiNWs
Reliability of OTFTs on flexible substrate: Mechanical stress effect

Flexibility will significantly expand the application scope of electronics, particularly large-area electronics. Over the last 10 years, printed organic electronic is believed to be one of the next major technological breakthroughs in the field of microelectronic and the use of printing technology to process organic field-effect transistors (OFETs) opens promising perspectives for low-cost, large-area circuits integrated on flexible, plastic substrates. With amorphous polymer-based thin film transistors acceptable electrical performances are now achieved with relatively good stability at ambient air. In the literature a lot of work has been devoted to study degradation of device characteristics under bias stress conditions but only few papers deal with the mechanical behavior. In this paper, we review our first reliability results obtained on flexible organic thin film transistors under mechanical stresses. The variations of electrical characteristics under bending tests, both in compression and tension, have been studied. Using specific equipment, we have also evaluated the reliability of transistors under cyclic bending tests. The stress dependency of the transfer characteristic deviates from the one observed for inorganic material like silicon
Spectral estimation on the sphere with needlets: high frequency asymptotics

International audienceThe angular power spectrum of a stationary random field on the sphere is estimated from the needlet coefficients of a single realization, observed with increasingly fine resolution. The estimator we consider is similar to the one recently used in practice by (Faÿ et al. 2008) to estimate the power spectrum of the Cosmic Microwave Background. The consistency of the estimator, in the asymptotics of high frequencies, is proved for a model with a stationary Gaussian field corrupted by heteroscedastic noise and missing data
Mid- to late-Holocene environmental evolution of the Loire estuary as observed from sedimentary characteristics and benthic foraminiferal assemblages

International audienceWe used sedimentological and foraminiferal characteristics of four sedimentary cores, supported by paleogeographical and historical data, to reconstruct the depositional history of the inner Loire estuary (Near Saint-Nazaire, France) and the response of benthic foraminifera to the mid- to late-Holocene marine flooding of the incised valley. These were further used to evaluate the consequent changes in estuarine morphological and hydro-sedimentary patterns during this time period. Our results described significant changes in hydro-sedimentary dynamics over the past ~ 6 kyrs BP. At our location, these changes expressed the combined influence of marine (e.g., tide, storm waves) and fluvial dynamics (e.g., floods), which are linked, on a broader scale, to sea-level variations and the regional climate regime. Three main periods stand out: (1) from ~ 6.0 to ~ 2.5 kyrs BP, when the sea-level rise slowed down, a large brackish bay extended over and around the study area. The fine-grained tidal rythmites recorded north of the Bilho bank (the main tidal bar located in our study area) indicated a calm depositional environment, protected from the main riverine influence. The presence of thick flood deposits from ~ 5.4 to ~ 4.0 kyrs BP near the Bilho bank indicates further the dominance of humid conditions. (2) From ~ 2.5 kyrs BP to ~ 1850 CE (pre-industrial state), sea-level stabilized at its present value, and the pre-existing bay was progressively infilled. North of the Bilho bank, near a major mudflat (Méan), the generally homogenous sedimentation composed of silty muds rich in organic matter indicated a sheltered environment; the main water flow channel being located south of the Bilho bank. Within this overall homogenous sedimentation, foraminiferal assemblages described rather accurately the progressive infilling of the valley (indicated by a decrease in the proportions of outer estuarine species), accompanied with the channelization of the main entering marine currents (tide, storm waves) (indicated by an increase in the proportions of transported species from the adjacent upper continental shelf), and finally the buildup of the Méan mudflat and the stabilization of the environment to its present day configuration (indicated by the dominance of autochthonous inner estuarine species). (3) Since 1850 CE, the human impact progressively modified the general landscape of our study area with the construction of the Saint-Nazaire shipyard, the digging of the northern navigation channel and the polderization of the northern Bay. The southern channel was progressively abandoned by the main water flow in favor of the newly dug northern channel, causing the southern migration of the Bilho sandbank and the progressive filling of the southern channel
Land use development and environmental responses since the Neolithic around Lake Paladru in the French Pre-alps

International audienceThe Lake Paladru sedimentary archive documents the past 10,000 years of the environmental history of the French Pre-alps. The archive's information on vegetation dynamics, fire activity and soil erosion serves to reconstruct a continuous dynamic record of land use over the last 6000 years. This multi-proxy approach serves to document the effects of successive human settlements on the environment at the watershed scale. First, discrete human impacts were identified during the Middle Neolithic that have not yet been confirmed by archaeological discoveries in the watershed. Developments of agropastoral activity have been recorded during the Late Neolithic (the period of the pile-dwelling archaeological site " Les Baigneurs ") and the Bronze Age, and the practice of slash-and-burn is documented by the records of fires. During the Iron Age and the Roman period, agropastoral activities (livestock farming and cereal cultivation) became continuous. They involved an intensification of human effects with a rapid and high-amplitude increase in soil erosion and a shift in the use of fire from an instrument for clearing land to an agropastoral landscape management tool. The Medieval period was characterized by the spatial expansion and diversification of crops. Results of this study have located the " thousand-year " pile dwelling sites such as " Colletière " in a longer phase of human occupation that deeply and sustainably modified the surrounding landscape of the lake. Beginning in the Modern period, the proxies used in this study served to record a new shift in land use marked by extensive clearing and the abandonment of most crop areas. This shift was linked to the expansion of industrial activities and subsequently to their abandonment during the 20th century
Amazonian Northern Mid-Latitude Glaciation on Mars: A Proposed Climate Scenario

International audienceRecent geological observations in the northern mid-latitudes of Mars show evidence for past glacial activity during the late Amazonian, similar to the integrated glacial landsystems in the Dry Valleys of Antarctica. The large accumulation of ice (many hundreds of meters) required to create the observed glacial deposits points to significant atmospheric precipitation, snow and ice accumulation, and glacial flow. In order to understand the climate scenario required for these conditions, we used the LMD (Laboratoire de Météorologie Dynamique) Mars GCM (General Circulation Model), which is able to reproduce the present-day water cycle, and to predict past deposition of ice consistent with geological observations in many cases. Prior to this analysis, however, significant mid-latitude glaciation had not been simulated by the model, run under a range of parameters.In this analysis, we studied the response of the GCM to a wider range of orbital configurations and water ice reservoirs, and show that during periods of moderate obliquity (ϵ = 25–35°) and high dust opacity (τdust = 1.5–2.5), broad-scale glaciation in the northern mid-latitudes occurs if water ice deposited on the flanks of the Tharsis volcanoes at higher obliquity is available for sublimation. We find that high dust contents of the atmosphere increase its water vapor holding capacity, thereby moving the saturation region to the northern mid-latitudes. Precipitation events are then controlled by topographic forcing of stationary planetary waves and transient weather systems, producing surface ice distribution and amounts that are consistent with the geological record. Ice accumulation rates of ∼10 mm yr−1 lead to the formation of a 500–1000 m thick regional ice sheet that will produce glacial flow patterns consistent with the geological observations
Empirical model for rapid macroseismic intensities prediction in Guadeloupe and Martinique Modèle empirique pour la prédiction rapide des intensités macrosismiques en Guadeloupe et Martinique

International audienceWe describe a simple model for prediction of macroseismic intensities adapted to Guadeloupe and Martinique (Lesser Antilles), based on a combination of peak ground acceleration (PGA) predictive equation and a forward relation between acceleration and intensity. The PGA predictive equation is built from a 3-parameter functional form constrained by measurements from permanent accelerometer stations, mostly associated with Les Saintes crustal earthquake (21/11/2004, Mw = 6:3) and its many aftershocks. The forward intensity model is checked on a database of recent instrumental events of various origins with magnitudes 1.6 to 7.4, distances from 4 to 300 km, and observed intensities from I to VIII. Global sigma residual equals 0.8 in the MSK scale, suggesting a larger applicability range than the intermediate PGA predictive equation. The model is presently used by the French Lesser Antilles observatories to produce automatic reports for earthquakes potentially felt
Monitoring and flux determination of trace metals in rivers of the Seversky Donets basin (Ukraine) using DGT passive samplers

International audienceThis paper reports the results of the in situ application of diffusive gradients in thin-films (DGT) passive samplers for trace metals (Cd, Co, Cr, Cu, Ni, Pb and Zn) monitoring in transboundary Udy and Lopan rivers of the Seversky Donets watershed in the Kharkiv region (Ukraine), which has a long history of industrial development. The research discusses potential sources of DGT-measured labile metals in water and seasonal variations. Our results demonstrate the application of DGT for identifying and measuring labile metal concentrations in contrasted climate conditions (cold snowy winter and hot summer) and appropriateness of such a tool for continuous water monitoring with the presence of an ice cover. Results show that DGT-measured concentrations of most of trace metals were much higher downstream of the wastewater treatment plants discharges than upstream; thus wastewater treatment plants seemed not able to reduce or to remove trace metals' contaminations and become major sources of pollutants in the studied rivers. The calculation of the average metal fluxes based on the DGT-measured concentrations confirmed that the urban wastewater discharges significantly contribute to the metal fluxes into the Udy and the Lopan rivers during both low-flow and high-flow periods. Compared to the wastewaters inputs to the rivers, the transboundary effect is limited, but should be taken into account as the origin of some metals is from sources located on the adjacent Russian territory
On bromine, nitrogen oxides and ozone depletion in the tropospheric plume of Erebus volcano (Antarctica)

International audienceSince the discovery of bromine oxide (BrO) in volcanic emissions, there has been speculation concerning its role in chemical evolution and notably ozone depletion in volcanic plumes. We report the first measurements using Differential Optical Absorption Spectroscopy (DOAS) of BrO in the tropospheric plume of the persistently degassing Erebus volcano (Antarctica). These are the first observations pertaining to emissions from an alkaline phonolitic magma. The observed BrO/SO2 ratio of 2.5 x 10-4 is similar to that measured at andesitic arc volcanoes. The high abundance of BrO is consistent with high abundances of F and Cl relative to sulfur in the Erebus plume. Our estimations of HBr flux and BrO production rate suggest that reactive bromine chemistry can explain a 35% loss of tropospheric O3 observed in the Erebus plume at approximately 30 km from source (Oppenheimer et al., 2010). Erebus also has a permanent lava lake, which could result in generation of NOx by thermal fixation of atmospheric N2 at the hot lava surface. Any NOx emission could play a potent role in reactive bromine chemistry. However, the presence of NO2 could not be detected in the plume, about 400 m above the lake, in our DOAS observations of 2005. Nor could we reproduce spectroscopic retrievals that reportedly identified NO2 in DOAS observations from 2003 made of the Erebus plume (Oppenheimer et al., 2005). Based on the NO2 detection limit of our analysis, we can state an upper limit of the NO2/SO2 ratio of ≤ 0.012, an order of magnitude lower than previously reported. Our new result supports a rapid oxidation of NOx in the young plume and is more consistent with measurements of NOy species measured using an instrumented aircraft flying in the plume. Model simulations, tuned for Erebus, were performed to reproduce the BrO/SO2 observed in the young plume and to investigate the impact of NOx emissions at source on the subsequent formation of BrO in the plume. They support our hypothesis of rapid conversion of NOx to NOy in the vicinity of the lava lake. This study thus places new constraints on the interaction between reactive nitrogen and bromine species in volcanic plumes, and its effects on ozone
Volcanic Markers of the Post-Subduction Evolution of Baja California and Sonora, Mexico: Slab Tearing Versus Lithospheric Rupture of the Gulf of California

International audienceThe study of the geochemical compositions and K-Ar or Ar-Ar ages of ca. 350 Neogene and Quaternary lavas from Baja California, the Gulf of California and Sonora allows us to discuss the nature of their mantle or crustal sources, the conditions of their melting and the tectonic regime prevailing during their genesis and emplacement. Nine petrographic/geochemical groups are distinguished: ''regular'' calc-alkaline lavas; adakites; magnesian andesites and related basalts and basaltic andesites; niobium-enriched basalts; alkali basalts and trachybasalts; oceanic (MORB-type) basalts; tholeiitic/transitional basalts and basaltic andesites; peralkaline rhyolites (comendites); and icelandites. We show that the spatial and temporal distribution of these lava types provides constraints on their sources and the geodynamic setting controlling their partial melting. Three successive stages are distinguished. Between 23 and 13 Ma, calc-alkaline lavas linked to the subduction of the Pacific-Farallon plate formed the Comondu' and central coast of the Sonora volcanic arc. In the extensional domain of western Sonora, lithospheric mantle-derived tholeiitic to transitional basalts and basaltic andesites were emplaced within the southern extension of the Basin and Range province. The end of the Farallon subduction was marked by the emplacement of much more complex Middle to Late Miocene volcanic associations, between 13 and 7 Ma. Calc-alkaline activity became sporadic and was replaced by unusual post-subduction magma types including adakites, niobium-enriched basalts, magnesian andesites, comendites and icelandites. The spatial and temporal distribution of these lavas is consistent with the development of a slab tear, evolving into a 200-km-wide slab window sub-parallel to the trench, and extending from the Pacific coast of Baja California to coastal Sonora. Tholeiitic, transitional and alkali basalts of subslab origin ascended through this window, and adakites derived from the partial melting of its upper lip, relatively close to the trench. Calcalkaline lavas, magnesian andesites and niobium-enriched basalts formed from hydrous melting of the supraslab mantle triggered by the uprise of hot Pacific asthenosphere through the window. During the Plio-Quaternary, the ''no-slab'' regime following the sinking of the old part of the Farallon plate within the deep mantle allowed the emplacement of alkali and tholeiitic/transitional basalts of deep asthenospheric origin in Baja California and Sonora. The lithospheric rupture connected with the opening of the Gulf of California generated a high thermal regime associated to asthenospheric uprise and emplaced Quaternary depleted MORB-type tholeiites. This thermal regime also induced partial melting of the thinned lithospheric mantle of the Gulf area, generating calcalkaline lavas as well as adakites derived from slivers of oceanic crust incorporated within this mantle