pinecone/core-2020-05-10-deduplication huggingface dataset:
Manganese Catalysts to Obtain Olefins from C1-C4 Alkanes

AbstractOxidative transformations of C1-C4 alkanes into olefins on oxide manganese catalysts were under study. We also studied oxidative coupling of methane (OCM) into ethylene on deposited and applied on the silicon dioxide catalysts. We studied the influence of chemical composition of catalyst and promotors on the OCM. Adding a little amount of ethane and propane hydrocarbons to methane allows increasing the concentration of ethylene in gases and significantly increasing productivity in ethylene. The study also shows the impact of the amount of manganese and promotors applied on SiO2 on the yield of olefins during the conversion of C3-C4 alkanes
Maintenance Cognitive Stimulation Therapy: An Economic Evaluation Within a Randomized Controlled Trial

AbstractBackgroundCognitive Stimulation Therapy (CST) is effective and cost-effective for people with mild-to-moderate dementia when delivered biweekly over 7 weeks.AimsTo examine whether longer-term (maintenance) CST is cost-effective when added to usual care.MethodsCost-effectiveness analysis within multicenter, single-blind, pragmatic randomized controlled trial; subgroup analysis for people taking acetylcholinesterase inhibitors (ACHEIs). A total of 236 participants with mild-to-moderate dementia received CST for 7 weeks. They were randomized to either weekly maintenance CST added to usual care or usual care alone for 24 weeks.ResultsAlthough outcome gains were modest over 6 months, maintenance CST appeared cost-effective when looking at self-rated quality of life as primary outcome, and cognition (MMSE) and proxy-rated quality-adjusted life years as secondary outcomes. CST in combination with ACHEIs offered cost-effectiveness gains when outcome was measured as cognition.ConclusionsContinuation of CST is likely to be cost-effective for people with mild-to-moderate dementia
Competing in a Globalising World: International Ranking of South African Universities

AbstractRankings of higher education institutions are important for students, research administrations, industry and academics. A number of rankings are published internationally, most of which aim to identify the top universities in the world.Developing countries are also interested for relevant rankings that could assist them to develop appropriate higher education policies.In this article we develop a ranking approach based on citations received for articles produced by universities in a variety of scientific disciplines. The approach is relatively simple and has the potential to guide policy.In this context this article identifies the international standing of the South African universities in the various scientific disciplines, compares them with their standing over time and elaborates on the consequences relevant to higher education and science and technology policy
New Challenge of the Public Buildings: nZEB Findings from IEE RePublic_ZEB Project

AbstractNearly Zero-Energy Buildings (nZEBs) have received increased attention in recent years as a result of constant concerns for energy supply constraints, decreasing energy resources, increasing energy costs and rising impact of greenhouse gases on world climate. The EPBD recast directive [1] requests all new buildings to meet higher levels of performance than before, by exploring more the alternative energy supply systems available locally on a cost-efficiency basis and without prejudicing the occupants’ comfort. To this end, after 2020, all new buildings should become “nearly zero-energy” and after 31 December 2018, the same requirement is applied for new buildings occupied and owned by public authorities. Furthermore, the EPBD recast states that MS must ensure that minimum energy performance requirements for buildings are set with a view to achieving cost-optimal levels according to the Commission Delegated Regulation (EU) No 244/2012 of 16 January 2012. In this context, the authors of this paper, who are participants in the recent started European project RePublic_ZEB, are willing to share the initial findings from on- going research work. Public buildings constitute a specific class of buildings that require a complex analysis from the statistic point of view taking into consideration the definition and typologies and other specific parameters related with. Thus, this paper will focus on the analysis of public building stocks in the countries covered by the project consortium with the view to define relevant parameters characterizing the reference public buildings that will be considered in the further analysis regarding the assessment of cost-effective packages of solutions towards nZEB levels of performance. A review of nZEB holistic approach, definitions and existing implemented policies in the participant countries, will be presented as well
Understanding the nature of Ds(2317) and Ds(2460) through nonleptonic B decays

AbstractWe consider the nonleptonic B decays B→D(∗)Ds(2317) and B→D(∗)Ds(2460), involving the newly discovered Ds(2317) and the Ds(2460) states. We find that experiments indicate disagreement with model calculations of their properties and/or breakdown of the factorization assumption for these decays. We point out that decays involving Bs mesons where the Ds resonances can be produced via the weak decay of the b quark can provide further information about the nature of these newly discovered states. We also propose a model to calculate the two body nonleptonic decays B→D(∗)Ds(2317)(Ds(2460)), if the Ds(2317) and Ds(2460) are interpreted as DK and D∗K molecules
Sharp bounds on 2m/r of general spherically symmetric static objects

AbstractIn 1959 Buchdahl [H.A. Buchdahl, General relativistic fluid spheres, Phys. Rev. 116 (1959) 1027–1034] obtained the inequality 2M/R⩽8/9 under the assumptions that the energy density is non-increasing outwards and that the pressure is isotropic. Here M is the ADM mass and R the area radius of the boundary of the static body. The assumptions used to derive the Buchdahl inequality are very restrictive and for instance neither of them hold in a simple soap bubble. In this work we remove both of these assumptions and consider any static solution of the spherically symmetric Einstein equations for which the energy density ρ⩾0, and the radial and tangential pressures p⩾0 and pT satisfy p+2pT⩽Ωρ, Ω>0, and we show thatsupr>02m(r)r⩽(1+2Ω)2−1(1+2Ω)2, where m is the quasi-local mass, so that in particular M=m(R). We also show that the inequality is sharp under these assumptions. Note that when Ω=1 the original bound by Buchdahl is recovered. The assumptions on the matter model are very general and in particular any model with p⩾0 which satisfies the dominant energy condition satisfies the hypotheses with Ω=3
Re-evaluation and extension of the Marine Isotope Stage 5 tephrostratigraphy of the Faroe Islands region: The cryptotephra record

AbstractPrevious studies of marine sequences from the Faroe Islands region have identified a series of coarse-grained tephra horizons deposited during Marine Isotope Stage (MIS) 5. Here we reassess the MIS 5 tephrostratigraphy of the Faroe Islands region and focus on the cryptotephra deposits preserved within the fine-grained fraction of marine core LINK 16. We also extend the record to encompass the late MIS 6 and early MIS 4 periods. A density separation technique, commonly used for tephra investigations in lacustrine settings but rarely applied to marine sediments, is utilised to explore the fine-grained material and EPMA and LA-ICP-MS are employed to determine the major and trace element composition of individual tephra shards. In total, 3 basaltic and 3 rhyolitic Icelandic cryptotephra deposits with homogeneous geochemical compositions are identified — all of which have the potential to act as isochronous tie-lines. Geochemical results highlight that the Grímsvötn volcanic system of Iceland is the predominant source of the basaltic horizons and the Öraefajökull or Torfajökull systems are the likely sources of the rhyolitic deposits. Three of the horizons have been previously recognised in Faroe Islands region marine sequences, with two of these deposits traceable into a Norwegian Sea sequence. An early MIS 4 rhyolitic horizon is the most widespread deposit as it can be traced into the Norwegian Sea and to the south into a record from the Rockall Trough. Basaltic and rhyolitic horizons deposited during late MIS 6 have not been recognised in other sequences and represent new additions to the regional tephrostratigraphy
Thermal Analysis of Heat Transfer Enhancement and Fluid Flow for Low Concentration of Al2O3 Water - Ethylene Glycol Mixture Nanofluid in a Single PEMFC Cooling Plate

AbstractNumerical analysis of thermal enhancement for a single Proton Exchange Membrane Fuel Cell (PEMFC) cooling plate is presented in this paper. A low concentration of Al2O3 in Water - Ethylene Glycol mixtures was used as coolant in 220mm x 300mm cooling plate with 22 parallel mini channels of 1 x 5 x 100mm. This cooling plate mimicked conventional PEMFC cooling plate as it was made of carbon graphite. Large header was added to have an even velocity distribution across all Re number studied. The cooling plate was subjected to a constant heat flux of 100W that represented the artificial heat load of a single cell. Al2O3 nano particle volume % concentration of 0.1 and 0.5 vol was dispersed in 50:50 (water: Ethylene Glycol) mixtures. The effect of different flow rates to heat transfer enhancement and fluid flow in Re range of 30 to 150 were observed. The result showed that thermal performance has improved by 7.3 and 4.6% for 0.5 and 0.1 vol % Al2O3 consecutively in 50:50 (water:EG) as compared to base fluid of 50:50 (water:EG). It is shown that the higher vol % concentration of Al2O3 the better the heat transfer enhancement but at the expense of higher pumping power required as much as 0.04W due to increase in pressure drop. The positive thermal results implied that Al2O3 nanofluid is a potential candidate for future applications in PEM fuel cell thermal managemen
Last glacial dynamics of the Vale of York and North Sea lobes of the British and Irish Ice Sheet

AbstractDuring the Last Glacial Maximum, the Vale of York and North Sea lobes of the British and Irish Ice Sheet extended to within 10km of each other, impounding a series of pro-glacial lakes. Such an interplay of ice lobes provides a useful analogue for elsewhere in the North Sea basin. This paper focusses on reconstructing the Vale of York and North Sea Ice lobes using a regional suite of 25 luminescence ages in combination with stratigraphical and geomorphic evidence. Results extend and revise the chronology of the Dimlington LGM typesite, showing that the North Sea Ice lobe advanced between 20.9–17.1ka and 17.1–15.1ka before present. Initially this lobe impounded a proto Lake Humber which likely covered parts of Holderness as well as the southern part of the Vale of York. Later stages of Lake Humber within the Vale of York show continued blockage of the Humber Gap by the North Sea Ice lobe. The Vale of York Ice extended briefly at ∼18.7±0.63ka across Lake Humber into South Yorkshire and North Lincolnshire before retreating to and forming the Escrick and York moraines. Both glacier lobes appear to have been short-lived, comprising relatively dynamic ice, especially when moving into areas of deformable lacustrine sediments, which allowed them to rapidly advance and over-extend their margins due to low basal shear stress. Topographic control of the extent and spatial positioning of both Ice lobes also appears to have been significant
Search for the production of an excited bottom quark decaying to tW in proton-proton collisions at sqrt(s) = 8 TeV

A search is presented for a singly produced excited bottom quark (b*) decaying to a top quark and a W boson in the all- hadronic, lepton + jets, and dilepton final states in proton- proton collisions at sqrt(s) = 8 TeV recorded by the CMS experiment at the CERN LHC. Data corresponding to an integrated luminosity of 19.7 inverse femtobarns are used. No significant excess of events is observed with respect to standard model expectations. We set limits at 95% confidence on the product of the b* quark production cross section and its branching fraction to tW. The cross section limits are interpreted for scenarios including left-handed, right-handed, and vector-like couplings of the b* quark and are presented in the two-dimensional coupling plane based on the production and decay coupling constants. The masses of the left-handed, right-handed, and vector-like b* quark states are excluded at 95% confidence below 1390, 1430, and 1530 GeV, respectively, for benchmark couplings. This analysis gives the most stringent limits on the mass of the b* quark to date
An XMM-Newton and INTEGRAL view on the hard state of EXO 1745-248 during
  its 2015 outburst

CONTEXT - Transient low-mass X-ray binaries (LMXBs) often show outbursts
lasting typically a few-weeks and characterized by a high X-ray luminosity
($L_{x} \approx 10^{36}-10^{38}$ erg/sec), while for most of the time they are
found in X-ray quiescence ($L_X\approx10^{31} -10^{33}$ erg/sec). EXO 1745-248
is one of them. AIMS - The broad-band coverage, and the sensitivity of
instrument on board of {\xmm} and {\igr}, offers the opportunity to
characterize the hard X-ray spectrum during {\exo} outburst. METHODS - In this
paper we report on quasi-simultaneous {\xmm} and {\igr} observations of the
X-ray transient {\exo} located in the globular cluster Terzan 5, performed ten
days after the beginning of the outburst (on 2015 March 16th) shown by the
source between March and June 2015. The source was caught in a hard state,
emitting a 0.8-100 keV luminosity of $\simeq10^{37}$~{\lumcgs}. RESULTS - The
spectral continuum was dominated by thermal Comptonization of seed photons with
temperature $kT_{in}\simeq1.3$ keV, by a cloud with moderate optical depth
$\tau\simeq2$ and electron temperature $kT_e\simeq 40$ keV. A weaker soft
thermal component at temperature $kT_{th}\simeq0.6$--0.7 keV and compatible
with a fraction of the neutron star radius was also detected. A rich emission
line spectrum was observed by the EPIC-pn on-board {\xmm}; features at energies
compatible with K-$\alpha$ transitions of ionized sulfur, argon, calcium and
iron were detected, with a broadness compatible with either thermal Compton
broadening or Doppler broadening in the inner parts of an accretion disk
truncated at $20\pm6$ gravitational radii from the neutron star. Strikingly, at
least one narrow emission line ascribed to neutral or mildly ionized iron is
needed to model the prominent emission complex detected between 5.5 and 7.5
keV. (Abridged)Comment: 14 pages, 6 figure, 2 tables. Accepted for publication on A&A
  (21/03/2017
Does continued participation in STEM enrichment and enhancement activities affect school maths attainment?

This is the final version of the article. Available from Taylor & Francis via the DOI in this record.Science, technology, engineering, and mathematics (STEM) skills are very valuable for economic growth. However, the number of young people pursuing STEM learning trajectories in the United Kingdom was lower than the predicted demand during the last decade. Several STEM enrichment and enhancement activities were thus funded by the government, private, and charitable organisations to improve understanding of and raise pupil interest in these subjects. One possible way of measuring the impact of these activities in supporting pupil understanding of maths was to track the proportion of young people obtaining a ‘good’ grade in standardised national tests such as the GCSEs. Attainment is of course only one possible outcome of education but certainly a very important one because students are more likely to continue studying subjects in which they score higher. This makes maths attainment even more important as it is a pre-requisite for admission to STEM degree courses. This longitudinal study makes use of the National Pupil Database to assess the impact of these schemes on maths attainment of participating schools. Following up 300 intervention schools for five years the study shows the intervention group did not do any better than the comparator. The paper suggests further directions for research and offers recommendations for practice.This study has been supported by the ESRC impact acceleration award
The Gamma-Ray Emitting Radio-Loud Narrow-Line Seyfert 1 Galaxy PKS 2004-447. I. The X-ray View

As part of the TANAMI multiwavelength progam, we discuss new X-ray observations of the γ-ray and radio-loud narrow line Seyfert 1 galaxy (γ-NLS1) PKS 2004−447. The active galaxy is a member of a small sample of radio-loud NLS1s detected in γ-rays by the Fermi Large Area Telescope. It stands out for being the radio-loudest and the only southern-hemisphere source in this sample. We present results from our X-ray monitoring program comprised of Swift snapshot observations from 2012 through 2014 and two new X-ray observations with XMM-Newton in 2012. Supplemented by archival data from 2004 and 2011, our data set allows for a careful analysis of the X-ray spectrum and variability of this peculiar source. The (0.5-10) keV spectrum is described well by a power law (Γ ~ 1.6), which can be interpreted as non-thermal emission from a relativistic jet. The source exhibits moderate flux variability on timescales of both months and years. Correlated brightness variations in the (0.5-2) keV and (2-10) keV bands are explained by a single variable spectral component, such as the one from the jet. A possible soft excess seen in the data from 2004 cannot be confirmed by the new XMM-Newton observations taken during low-flux states. Any contribution to the total flux in 2004 is less than 20% of the power-law component. The (0.5-10) keV luminosities of PKS 2004−447 are in the range of (0.5−2.7) × 1044 erg s-1. A comparison of the X-ray properties among the known γ-NLS1 galaxies shows that in four out of five cases the X-ray spectrum is dominated by a flat power law without intrinsic absorption. These objects are moderately variable in their brightness, while spectral variability is observed in at least two sources. The major difference across the X-ray spectra of γ-NLS1s is the luminosity, which spans a range of almost two orders of magnitude from 1044 erg s-1 to 1046 erg s-1 in the (0.5-10) keV band
A search for top squarks with R-parity-violating decays to all-hadronic final states with the ATLAS detector in √s = 8 TeV proton-proton collisions

Journal of High Energy Physics 2016.6 (2016): 067 reproduced by permission of Scuola Internazionale Superiore di Studi Avanzati (SISSA)Artículo escrito por muchos autores, sólo se referencian el que aparece en primer lugar, el nombre del grupo de colaboración y los autores que firman como pertenecientes a la UAMA search for the pair production of top squarks, each with R-parity-violating decays into two Standard Model quarks, is performed using 17.4 fb−1 of √ s = 8 TeV proton-proton collision data recorded by the ATLAS experiment at the LHC. Each top squark is assumed to decay to a b- and an s-quark, leading to four quarks in the final state. Background discrimination is achieved with the use of b-tagging and selections on the mass and substructure of large-radius jets, providing sensitivity to top squark masses as low as 100 GeV. No evidence of an excess beyond the Standard Model background prediction is observed and top squarks decaying to ¯bs¯ are excluded for top squark masses in the range 100 ≤ mt˜ ≤ 315 GeV at 95% confidence levelWe acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWFW and FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq and FAPESP, Brazil; NSERC, NRC and CFI, Canada; CERN; CONICYT, Chile; CAS, MOST and NSFC, China; COLCIENCIAS, Colombia; MSMT CR, MPO CR and VSC CR, Czech Republic; DNRF and DNSRC, Denmark; IN2P3-CNRS, CEA-DSM/IRFU, France; GNSF, Georgia; BMBF, HGF, and MPG, Germany; GSRT, Greece; RGC, Hong Kong SAR, China; ISF, I-CORE and Benoziyo Center, Israel; INFN, Italy; MEXT and JSPS, Japan; CNRST, Morocco; FOM and NWO, Netherlands; RCN, Norway; MNiSW and NCN, Poland; FCT, Portugal; MNE/IFA, Romania; MES of Russia and NRC KI, Russian Federation; JINR; MESTD, Serbia; MSSR, Slovakia; ARRS and MIZS, Slovenia; DST/NRF, South Africa; MINECO, Spain; SRC and Wallenberg Foundation, Sweden; SERI, SNSF and Cantons of Bern and Geneva, Switzerland; MOST, Taiwan; TAEK, Turkey; STFC, United Kingdom; DOE and NSF, United States of America. In addition, individual groups and members have received support from BCKDF, the Canada Council, CANARIE, CRC, Compute Canada, FQRNT, and the Ontario Innovation Trust, Canada; EPLANET, ERC, FP7, Horizon 2020 and Marie Sklodowska-Curie Actions, European Union; Investissements d’Avenir Labex and Idex, ANR, Région Auvergne and Fondation Partager le Savoir, France; DFG and AvH Foundation, Germany; Herakleitos, Thales and Aristeia programmes co- financed by EU-ESF and the Greek NSRF; BSF, GIF and Minerva, Israel; BRF, Norway; Generalitat de Catalunya, Generalitat Valenciana, Spain; the Royal Society and Leverhulme Trust, United Kingdo
Measurement of the t t ¯ production cross section in the eμ channel in proton-proton collisions at √s = 7 and 8 TeV

The inclusive cross section for top quark pair production is measured in proton-proton collisions at s=7 and 8 TeV, corresponding to 5.0 and 19.7 fb−1, respectively, with the CMS experiment at the LHC. The cross sections are measured in the electron-muon channel using a binned likelihood fit to multi-differential final state distributions related to identified b quark jets and other jets in the event. The measured cross section values are 173.6 ± 2.1(stat)− 4.0 + 4.5(syst) ± 3.8(lumi)pb at s=7 TeV, and 244.9 ± 1.4(stat)− 5.5 + 6.3(syst) ± 6.4(lumi)pb at s=8 TeV, in good agreement with QCD calculations at next-to-next-to-leading-order accuracy. The ratio of the cross sections measured at 7 and 8 TeV is determined, as well as cross sections in the fiducial regions defined by the acceptance requirements on the two charged leptons in the final state. The cross section results are used to determine the top quark pole mass via the dependence of the theoretically predicted cross section on the mass, giving a best result of 173. 8− 1.8 + 1.7 GeV. The data at s=8 TeV are also used to set limits, for two neutralino mass values, on the pair production of supersymmetric partners of the top quark with masses close to the top quark mass.The Scientific and Technical Research Council of Turkey, and Turkish Atomic Energy Authorit
Search for new physics with the M T2 variable in all-jets final states produced in pp collisions at √s=13 TeV

A search for new physics is performed using events that contain one or more jets, no isolated leptons, and a large transverse momentum imbalance, as measured through the MT2 variable, which is an extension of the transverse mass in events with two invisible particles. The results are based on a sample of proton-proton collisions collected at a center-of-mass energy of 13 TeV with the CMS detector at the LHC, and that corresponds to an integrated luminosity of 2.3 fb−1. The observed event yields in the data are consistent with predictions for the standard model backgrounds. The results are interpreted using simplified models of supersymmetry and are expressed in terms of limits on the masses of potential new colored particles. Assuming that the lightest neutralino is stable and has a mass less than about 500 GeV, gluino masses up to 1550-1750 GeV are excluded at 95% confidence level, depending on the gluino decay mechanism. For the scenario of direct production of squark-antisquark pairs, top squarks with masses up to 800 GeV are excluded, assuming a 100% branching fraction for the decay to a top quark and neutralino. Similarly, bottom squark masses are excluded up to 880 GeV, and masses of light-flavor squarks are excluded up to 600-1260 GeV, depending on the degree of degeneracy of the squark masses.The Scientific and Technical Research Council of Turkey, and Turkish Atomic Energy Authorit