pinecone/core-2020-05-10-deduplication huggingface dataset:
Transmutation Analysis of Realistic Low-Activation Steels for Magnetic Fusion Reactors and IFMIF

A comprehensive transmutation study has been performed for steels considered in the selection of structural materials\ud
for magnetic and inertial fusion reactors for the international fusion materials irradiation facility (IFMIF) neutron irradiation environment, as well as in the international thermonuclear experimental reactor (ITER) and a fusion demonstration reactor (DEMO) for comparison purposes. An element by element transmutation approach is used in the study, addressing the generation of: (1) H and He and (2) solid transmutants. The IEAF 2001 activation library and the activation code ACAB were applied in the IFMIF transmutation analysis, after proving the applicability of ACAB for transmutation calculations in intermediate energy systems
Short-term effects of impurities in the CO2 stream injected into fractured carbonates.

After the Paris Agreement in which 195 countries are involved, the Carbon Capture and Storage (CCS) is now an accepted technology in the United Nations Framework Convention on Climate Change (UNFCCC). In Spain, Fundación Ciudad de la Energía (CIUDEN) has successfully completed the full CCS chain, being CO2 captured in the Technology Development Centre in Cubillos del Sil (León, Spain) whereas that it is geologically stored in a deep saline aquifer, formed by fractured carbonates with poor matrix porosity, located in the Technology Development Plant (TDP) at Hontomín (Burgos, Spain).  The results of the field tests, in which up to 150 tons of CO2 and synthetic air (5 %v of N2 and O2) were co-injected on site, are analyzed in this paper comparing the operational parameters gained during the injection of impure CO2 (pressures, temperatures and flow ranges) with its corresponding baseline previously determined (i.e. 1,500 tons of pure CO2 were injected during the reservoir hydraulic characterization). Besides that, the geochemical reactivity analysis of impure CO2 injected in this saline aquifer and its correlation with the results from laboratory tests were assessed. As main conclusions from laboratory scale results, a porosity diminution was measured after the injection of CO2 with 5 %v of SO2; apart from that, without SO2, the effluent pH was in the range of 7-8 whereas in case of CO2 and SO2, a pH of 1-2 was obtained. Otherwise and focused on field scale tests, a density decrease was detected comparing the base case (pure CO2) with the CO2 injection containing 5.1 %v of synthetic air. On the other hand, Ca2+, SO42-, Mg2+ and K+ migration effects in the rock were also detected and analyzed
Barbed suture vs conventional tenorrhaphy: biomechanical analysis in an animal model

Background: The advantages of barbed suture for tendon repair could be to eliminate the need for a knot and to better distribute the load throughout the tendon so as to reduce the deformation at the repair site. The purpose of this study was to evaluate the breaking force and the repair site deformation of a new barbed tenorrhaphy technique in an animal model.Materials and methods: Sixty porcine flexor tendons were divided randomly into three groups and repaired with one of the following techniques: a new 4-strand barbed technique using 2/0 polypropylene Quill™ SRS or 2/0 polydioxanone Quill™ SRS and a modified Kessler technique using 3/0 prolene. All tendons underwent mechanical testing to assess the 2-mm gap formation force, the breaking force and the mode of failure. The percentage change in tendon cross-sectional area before and after repair was calculated.\ud
Results: The two-sample Student t-test demonstrated a significant increase in 2-mm gap formation force and in breaking force with barbed sutures, independently from suture material, when compared to traditional Kessler suture. Concerning the tendon profile, we registered less bunching at the repair site in the two barbed groups compared with the Kessler group.Conclusions: This study confirms the promising results achieved in previous ex vivo studies about the use of barbed suture in flexor tendon repair. In our animal model, tenorrhaphy with Quill™ SRS suture guarantees a breaking force of repair that exceeds the 40–50 N suggested as sufficient to initiate early active motion, and a smoother profile at the repair site
Diastereoselective synthesis of optically active (2R,5R)-hexanediol

Erworben im Rahmen der Schweizer Nationallizenzen (http://www.nationallizenzen.ch)Diastereoselective reduction of diketones with Lactobacillus kefir DSM 20587 was examined. The reduction of both oxo-functions proceeded highly diastereoselectively. (2R,5R)-Hexanediol 3 was produced starting from (2,5)-hexanedione 1 in quantitative yields with enantiomeric excess >99% and diastereomeric excess >99%. The reaction conditions were optimized: maximum yield of (2R,5R)-hexanediol was reached at pH 6, 30°C and with equal amounts of substrate and cosubstrate. The applicability of the system in fed-batch experiments was demonstrated. The feed specific biomass concentration required to reach maximal yield and selectivity in fed-batch mode was determined
Perceived interparental conflict and early adolescents' friendships : the role of attachment security and emotion regulation

Erworben im Rahmen der Schweizer Nationallizenzen (http://www.nationallizenzen.ch)Although there is strong evidence for the effect of interparental conflict on adolescents’ internalizing and externalizing problems, little is known about the effect on the quality of adolescents’ relationships. The current study investigates the link between adolescents’ friendships and interparental conflict as reported by both parents and adolescents. It considers early adolescents’ emotion regulation ability and attachment security as mediators. The analysis is based on a longitudinal study with two waves separated by 12 months. The participants were 180 two-parent families and their adolescent children (50.5 % girls), the average age of the latter being 10.61 years (SD = 0.41) at the outset (Time 1). Binomial logistic regression analysis revealed that perceived interparental conflict increased the risk of instability in friendship relationships across the 1-year period. Structural equation modeling analysis indicated that the association between perceived interparental conflict and friendship quality was mediated by emotion regulation and attachment security. The discussion focuses on mechanisms whereby interparental conflict influences early adolescents’ friendship relationships
High efficient luminescence in type-II GaAsSb-capped InAs quantum dots upon annealing

The photoluminescence efficiency of GaAsSb-capped InAs/GaAs type II quantum dots (QDs) can be greatly enhanced by rapid thermal annealing while preserving long radiative lifetimes which are ∼20 times larger than in standard GaAs-capped InAs/GaAs QDs. Despite the reduced electron-hole wavefunction overlap, the type-II samples are more efficient than the type-I counterparts in terms of luminescence, showing a great potential for device applications. Strain-driven In-Ga intermixing during annealing is found to modify the QD shape and composition, while As-Sb exchange is inhibited, allowing to keep the type-II structure. Sb is only redistributed within the capping layer giving rise to a more homogeneous composition
Subnanometer-resolved measurement of the tunneling effective mass using bulk plasmons

Superlattices are periodic structures where the constituents alternate between low- and high-bandgap materials; the resulting quantum confinement tailors the resulting device properties and increases their operating speed. Amorphous carbon is an excellent candidate for both the well and barrier layers of the superlattices, leading to a fast and reliable device manufacturing process. We show theoretically and experimentally that, using low energy-loss spatially resolved spectroscopy, we can characterize the component layers of a superlattice. We measure quantum confinement of the electron wave function in the superlattice's wells and calculate the effective tunneling mass for amorphous carbon superlattices as m* =0.067 me. This effective mass makes diamondlike carbon films as feasible candidate for electronic devices. © 2006 American Institute of Physics
Reproduction, fat metabolism, and life span: what is the connection?

Reduced reproduction is associated with increased fat storage and prolonged life span in multiple organisms, but the underlying regulatory mechanisms remain poorly understood. Recent studies in several species provide evidence that reproduction, fat metabolism, and longevity are directly coupled. For instance, germline removal in the nematode Caenorhabditis elegans promotes longevity in part by modulating lipid metabolism through effects on fatty acid desaturation, lipolysis, and autophagy. Here, we review these recent studies and discuss the mechanisms by which reproduction modulates fat metabolism and life span. Elucidating the relationship between these processes could contribute to our understanding of age-related diseases including metabolic disorders
How do patients, politicians, physiotherapists and other health professionals view physiotherapy research in Switzerland? : a qualitative study

Since 2002, the professional education for Swiss physiotherapists has been upgraded to a tertiary educational level. With this change, the need for research related to professional practice has become more salient. The elaboration of research priorities is seen as a possible way to determine the profession's needs, to help coordinate research collaborations and to address expectations regarding physiotherapy. There is still limited evidence about stakeholders' views with regard to physiotherapy research. The objective of this study was to investigate key stakeholders' opinions about research in physiotherapy in Switzerland
Theoretical study of the HS (v',,j' = 1) + O2;(v''=0,j''=1) reaction

We report a theoretical study of the title four-atom reaction for a wide range of translational energies, considering the reactants in the ground vibrational state and also in some vibrationally excited levels of the HS radical. All calculations have employed the quasi-classical trajectory (QCT) method and a reported double many-body expansion potential energy surface for ground electronic state of HSO2. Cross sections as well as specific rate constants for HS elimination are reported and compared with literature data for such processes. To account the zero-point energy problem in QCT calculations, an internal energy quantum mechanics threshold (IEQMT) criteria is used. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008http://dx.doi.org/10.1002/qua.2159
The Muonic Hydrogen Lamb Shift Experiment at PSI

Abstract  A measurement of the 2S Lamb shift in muonic hydrogen (µ-p) is being prepared at the Paul Scherrer Institute (PSI). The goal of the experiment is to measure the energy difference ?E(25 P 3/2-23 S 1/2) by laser spectroscopy (?˜6µm) to a precision of 30 ppm and to deduce the root mean square (rms) proton charge radius with 10-3 relative accuracy, 20 times more precise than presently known.  An important prerequisite to this experiment is the availability of long-lived µp2S -atoms. A 2S-lifetime of ~1 µs – sufficiently long to perform the laser experiment – at H2 gas pressures of 1–2 hPa was deduced from recent measurements of the collisional 2S-quenching rate. A new low-energy negative muon beam yields an order of magnitude more muon stops in a small low-density gas volume than a conventional cloud muon beam. A stack of ultra-thin carbon foils is the key element of a fast detector for keV-muons. The development of a 2 keV X-ray detector and a 3-stage laser system providing 0.5 mJ laser pulses at 6 µm is on the way.http://dx.doi.org/10.1023/A:102088631423
Evaluation of the permeability of modified cellulose acetate propionate membranes for use in biosensors based on hydrogen peroxide detection

Phase inversion cellulose acetate propionate membranes showed lowpermeability to hydrogen peroxide aqueous solutions. Their permeability wasincreased by alkaline hydrolysis of the ester linking units. However, thepermeability remained lower than that of an unsubstituted cellulose membrane.The inclusion of hydroxypropyl cellulose in the membrane formulation, followedby an alkaline hydrolysis step, increased permeability to hydrogen peroxideaqueous solutions to 29% of that of an unsubstituted cellulose membrane.http://dx.doi.org/10.1023/A:101513780950
Mutations in FBXL4, encoding a mitochondrial protein, cause early-onset mitochondrial encephalomyopathy

Whole-exome sequencing and autozygosity mapping studies, independently performed in subjects with defective combined mitochondrial OXPHOS-enzyme deficiencies, identified a total of nine disease-segregating FBXL4 mutations in seven unrelated mitochondrial disease families, composed of six singletons and three siblings. All subjects manifested early-onset lactic acidemia, hypotonia, and developmental delay caused by severe encephalomyopathy consistently associated with progressive cerebral atrophy and variable involvement of the white matter, deep gray nuclei, and brainstem structures. A wide range of other multisystem features were variably seen, including dysmorphism, skeletal abnormalities, poor growth, gastrointestinal dysmotility, renal tubular acidosis, seizures, and episodic metabolic failure. Mitochondrial respiratory chain deficiency was present in muscle or fibroblasts of all tested individuals, together with markedly reduced oxygen consumption rate and hyperfragmentation of the mitochondrial network in cultured cells. In muscle and fibroblasts from several subjects, substantially decreased mtDNA content was observed. FBXL4 is a member of the F-box family of proteins, some of which are involved in phosphorylation-dependent ubiquitination and/or G protein receptor coupling. We also demonstrate that FBXL4 is targeted to mitochondria and localizes in the intermembrane space, where it participates in an approximately 400 kDa protein complex. These data strongly support a role for FBXL4 in controlling bioenergetic homeostasis and mtDNA maintenance. FBXL4 mutations are a recurrent cause of mitochondrial encephalomyopathy onset in early infancy
Dielectric properties of interacting storage ring plasmas

A dielectric function including collisional correlations is derived by linearizing the self consistent Vlasov equation with a Fokker-Planck collision integral. The calculation yields the same type of dielectric function as in the standard-theory of Schottky-noise in storage rings. This dielectric function is compared with the Mermin-dielectric function derived from a kinetic equation with relaxation time approximation. We observe that these functions are identical, however the Mermin-DF is computationally advantageous. The limits of both dielectric functions are given and the sum rules are proven. We apply these dielectric functions for typical storage ring plasmas and calculate the stopping power and the plasmon excitation spectrum
Solid-state diffusion in amorphous zirconolite

We discuss how structural disorder and amorphization affects solid-state diffusion, and consider zirconolite as a currently important case study. By performing extensive molecular dynamics simulations, we disentangle the effects of amorphization and density, and show that a profound increase of solid-state diffusion takes place as a result of amorphization. Importantly, this can take place at the same density as in the crystal, representing an interesting general insight regarding solid-state diffusion. We find that decreasing the density in the amorphous system increases pre-factors of diffusion constants, but not decreasing the activation energy. We also find that atomic species in zirconolite are affected differently by amorphization and density change. Our microscopic insights are relevant for understanding how solid-state diffusion changes due to disorder and for building predictive models of operation of materials to be used to encapsulate nuclear waste
Stress corrosion cracking of ring type joint of reactor pipeline of a hydrocracker unit

Failure of a ring type joint (RTJ) of reactor pipeline of a hydrocracker unit has been reported. Cracks were noticed on the flange as well as the ring gasket of the RTJ during inspection following a periodic shutdown of the unit. These components of the RTJ were manufactured from stabilized grades of austenitic stainless steel, namely, type 321 and 347, respectively. Study showed that the failure of the RTJ components occurred by transgranular stress corrosion cracking. It was further established that formation of polythionic acid due to presence of H2S in the process gas and H2O in the system was responsible for initiation of SCC in RTJ components. Detailed metallurgical investigation was carried out to identify the probable causes that could have been responsible for formation of polythionic acid in the process gas
The feasibility of high-efficiency InAs/GaAs quantum dot intermediate band solar cells

In recent years, all the operating principles of intermediate band behaviour have been demonstrated in InAs/GaAs quantum dot (QD) solar cells. Having passed this hurdle, a new stage of research is underway, whose goal is to deliver QD solar cells with efficiencies above those of state-of-the-art single-gap devices. In this work, we demonstrate that this is possible, using the present InAs/GaAs QD system, if the QDs are made to be radiatively dominated, and if absorption enhancements are achieved by a combination of increasing the number of QDs and light trapping. A quantitative prediction is also made of the absorption enhancements required, suggesting that a 30 fold increase in the number of QDs and a light trapping enhancement of 10 are sufficient. Finally, insight is given into the relative merits of absorption enhancement via increasing QD numbers and via light trapping
Mutual information and the F -theorem

Mutual information is used as a purely geometrical regularization of entanglement entropy applicable to any QFT. A coefficient in the mutual information between concentric circular entangling surfaces gives a precise universal prescription for the monotonous quantity in the c -theorem for d = 3. This is in principle computable using any regularization for the entropy, and in particular is a definition suitable for lattice models. We rederive the proof of the c -theorem for d = 3 in terms of mutual information, and check our arguments with holographic entanglement entropy, a free scalar field, and an extensive mutual information model
Lorentz contracted proton

The proton charge and magnetization density distributions can be related to the well known Sachs electromagnetic form factors G E , M ( q 2 ) through Fourier transforms, only in the Breit frame. The Breit frame however moves with relativistic velocities in the Lab and a Lorentz boost must be applied before extracting the static properties of the proton from the corresponding densities. Apart from this, the Fourier transform relating the densities and form factors is inherently a non-relativistic expression. We show that the relativistic corrections to it can be obtained by extending the standard Breit equation to higher orders in its 1 /c 2 expansion. We find that the inclusion of the above corrections reduces the size of the proton as determined from electron proton scattering data by about 4%
Consistently faster and smaller compressed bitmaps with Roaring

Compressed bitmap indexes are used in databases and search engines.  Many bitmap compression techniques have  been proposed, almost all relying primarily on run-length encoding (RLE). However, on unsorted data, we can get superior performance with a hybrid compression technique that uses both uncompressed bitmaps and packed arrays inside a two-level tree. An instance of this technique, Roaring, has recently been proposed. Due to its good performance, it has been adopted by several production platforms (e.g., Apache Lucene, Apache Spark, Apache Kylin and Druid).\ud
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Yet there are cases where run-length encoded bitmaps are smaller than the original Roaring bitmaps---typically when the data is sorted so that the bitmaps contain long compressible runs. To better handle these cases, we build a new Roaring hybrid that combines uncompressed bitmaps, packed arrays and RLE compressed segments. The result is a new Roaring format that compresses better.\ud
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Overall, our new implementation of Roaring can be several times faster (up to two orders of magnitude) than the implementations of traditional RLE-based alternatives (WAH, Concise, EWAH) while compressing better. We review the design choices and optimizations that make these good results possible
Dechlorination of Lindane in the Multiphase Catalytic Reduction System with Pd/C, Pt/C and Raney-Ni

Dechlorination of -hexachlorocyclohexane (lindane) is carried out in the multiphase catalytic system, composed by isooctane and aqueous KOH phases, a phase transfer agent (Aliquat 336) and a metal catalyst, e.g. 5% Pd/C, 5% Pt/C, or Raney-Ni. At 50 ◦C and atmospheric pressure the full conversion of lindane to 1,2,4-tricholorobenzene (1,2,4-TCB) is achieved in 5–10 min via the base assisted dehydrochlorination, followed by the metal catalyzed hydrodechlorination with hydrogen to benzene. Aqueous KOH and Aliquat 336 strongly affect the reaction:\ud
if present together they co-promote both dehydrochlorination and hydrodechlorination steps; if KOH is absent, the reaction is forced to follow a different catalytic pathway, which involves a removal of a pair of chlorines at every reaction step by zerovalent metal followed by reduction of metal with hydrogen. This is proven by the formation of 3,4,5,6-tetrachlorocyclohex-1-ene and 5,6-dichlorocyclohexa-1,3-diene as intermediates in the reaction over Raney-Ni, and by the absence of TCBs in the reactions on all the catalysts studied. The final yield of benzene via this pathway can be achieved in shorter times than in a system with KOH. The presence of Aliquat 336 in the isooctane-water system produces a 10-fold rate increase, the presence of alkaline water is also important since it avoids catalyst poisoning by neutralizing the hydrochloric acid formed
PCBs and PAHs in sea-surface microlayer and sub-surfacewater samples of the Venice Lagoon (Italy)

Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) are two classes of micropollutants intensively monitored\ud
and regulated due to their toxicity, persistency and wide diffusion. Their concentrations have been investigated in sea-microlayer\ud
(SML) and sub-surface water (SSW) samples collected at two sites of the Venice Lagoon, a fragile ecosystem highly influenced by industrial\ud
and anthropogenic emissions. The total PPCB concentration varies from 0.45 ng/l to 2.1 ng/l in SSW while a clear enrichment is\ud
observed in the SML, where it ranges from 1.2 ng/l to 10.5 ng/l. The total PPAH concentration shows marked differences between the\ud
two stations and varies from 12.4 ng/l to 266.8 ng/l in SSW; in SML it is more uniform and ranges from 19.6 ng/l to 178.9 ng/l. The\ud
enrichment factors are not larger than 1 for both pollutants in the dissolved phase, while they are most significant for the particulate\ud
phase (PPCB: 5–9; PPAH: 4–14).\ud
 2005 Elsevier Ltd. All rights reserved