pinecone/core-2020-05-10-deduplication huggingface dataset:
Methylene blue adsorption from aqueous solutions to flexible poly(vinyl chloride) silica composites

Methylene blue (MB) adsorption studies were performed with poly(vinyl chloride)-(dioctyl phthalate)-silica composites, which were obtained by using plastisol-plastigel technology. The films were flexible, having elastic modulus of 1.0-1.5 GPa. Diminishing MB concentration in the aqueous phase was followed as the adsorption process advanced by using visible spectroscopy. Contributions of the individual components of the composites to adsorption were also investigated. Although the MB adsorption capacity was extensively high for silica, it was moderate for the composite, most likely owing to the occlusion of pores of silica by plasticizer to some extent. The improvement of MB adsorption capacity of the composites as the silica ratio increased was explicitly deduced from the optical microscopy photographs. The diffusion coefficients of MB through the composites were 5 × 10-13, 6 × 10-13, and 3 × 10-13 m2 s-1 with regression coefficients of 0.73, 0.89, and 0.88 for 0, 2, and 16% silica-containing composites, respectively. Because of the slow diffusion of MB in poly(vinyl chloride)-silica composites, using them as dynamic column adsorbent was not practical. However, these versatile plastics can be used as plastic labels, colored clothing, leather substitutes, antimicrobial medical devices, and laser printable surfaces
Preparation and characterization of magnesium stearate, cobalt stearate, and copper stearate and their effects on poly(vinyl chloride) dehydrochlorination

Preparation and characterization of pure metal soaps and investigation of their effects on poly(vinyl chloride) (PVC) dehydrochlorination were the objectives of the present study. Magnesium stearate (MgSt2), cobalt stearate (CoSt2), and copper stearate (CuSt2) were prepared by a precipitation method. An aqueous sodium stearate (NaSt) solution was mixed at 500 rpm with respective metal salt solutions at 75oC. The precipitates that formed were collected by filtration, washed with water, and ultimately dried at 105oC under reduced pressure. Lamellar crystals that melted on heating were obtained. Solid-liquid phase transitions were observed by optical microscopy at 160oC, 159oC, and 117oC for MgSt2, CoSt2, and CuSt2, respectively. However, the melting points of MgSt2, CoSt2, and CuSt2 were determined as 115oC, 159oC, and 111oC, respectively, by analysis by differential scanning calorimetry. The onset temperature of the mass loss was the lowest at 255oC for CuSt2 and the lowest activation energy for thermal decomposition was 18 kJ/mol for CuSt2. CoSt2 was effective in extending the induction time of PVC dehydrochlorination at both 140oC and 160oC. The activation energy calculated from stability time decreased from 175 kJ/mol for a blank PVC sample to 114, 105, and 107 kJ/mol for MgSt2, CoSt2, and CuSt2-containing PVC samples, respectively. All three metal soaps accelerated the dehydrochlorination of PVC. J. VINYL ADDIT. TECHNOL., 21:235-244, 2015.TUBITAK (MISAG 185
Crystallization kinetics and affecting parameters on polycaprolactone composites with inorganic and organic additives

The isothermal crystallization and mechanical behavior of biodegradable polycaprolactone (PCL) composites with organic (oleic acid and glycerol monooleate) and inorganic (zinc oxide, organoclay, and hydroxy apatite) additives used alone or simultaneously were investigated. The effect of all additives on the degree of crystallinity percentage (DOC%), isothermal crystallization kinetics parameters, and mechanical test results of PCL composites was studied. The PCL composite films were prepared by solvent casting by using dichloromethane as the solvent. The films were characterized by X-ray diffraction, differential scanning calorimetry (DSC), and tensile tests. DSC of the first melting and X-ray diffraction DOC% results (for composites by solvent casting) are compatible. The values by DSC of the second melting (for composites by extrusion method) are lower. Organoclay gives the highest crystallinity among the other inorganic additives used. Small amounts of inorganic additives act as a nucleating agent and increase the crystallinity; the higher amounts decrease. The organic additives act as the plasticizer. When used alone, it lowers the crystallinity, but when used with inorganic additives, it improves the dispersion of inorganic particles in the polymer matrix. The isothermal crystallization kinetics parameters by Avrami analysis showed that crystallization was controlled by nucleation and the crystals had spherical structure. The nucleation type changed between thermal and athermal nucleation. The Pukanzky model interaction parameter B indicated that the organic additives improved the dispersion of inorganic particles in the polymer matrix. Statistically significant, eight correlations (F>6) were obtained for the crystallinity, crystallization parameters, Young's modulus, and tensile strength as a function of concentration of additives.Scientific and Technological Research Council of Turkey (110M157
On the importance of very long-term water quality records.

This overview is concerned with the value of long-term records of water quality in river basin management. In a world where change rather than stasis is increasingly the norm, monitoring is an essential way to discover whether there are significant undesirable changes taking place in the natural environment. The regular collection and processing of information involves systematic and purposeful observation, a deliberate plan of action in which the data have considerable value given the knowledge of their context in time and space. Long-term data reveal important patterns, which allow trends, cycles, and rare events to be identified. This is particularly important for complex systems where signals may be subtle and slow to emerge. Moreover, very long data sets are essential to test hypotheses undreamt of at the time the measurements were started. This overview includes long time series from UK rivers showing how water quality has changed over time—and continues to change. An important conclusion is the long time frame of system recovery, well beyond the normal lifetime of individual governments. At a time of increasing hydroclimatic variability, long time series of water quality observations remain critically important; continuity of observations is critical at key benchmark sites
The Taniwha and the Crown : defending water rights in Aotearoa/New Zealand.

Through the sale of hydroelectric and water company shares, the building of dams to impound and control freshwater supplies, and via water trading schemes, there is continual acceleration in the privatization of water resources around the world. Key opponents to the enclosure of this ‘common good’ are indigenous communities who, having had their land and water appropriated by colonial societies, are now seeing these subjected to further economic colonization, exploitation, and ecological degradation, often by transnational corporations with little or no local social or environmental accountability. Their protests regarding commercial appropriation are not merely attempts to assert prior rights of ownership and managerial responsibility. They are also a critique of ideologies oriented toward unlimited growth and development which, they argue, conflict with their more sustainable and reciprocal relations with place, and with the nonhuman environment. This article considers some of the efforts of indigenous people to uphold their traditional rights to own and manage water. It focuses particularly on a recent case brought by the Māori Council against the Crown in New Zealand/ Aotearoa. Taking this to the Waitangi Tribunal, to the High Court and finally to the Supreme Court, Māori tried to prevent the Government from privatizing a major hydroelectric company and thus its water allocations. As well as initiating a lively national discussion on water ownership and governance, the case articulated a bicultural dialogue which resonates with wider national and international debates about human–environmental relationships and what constitutes ‘the common good’
How to make sense of our rivers : using assemblage to understand angling.

Our freshwater habitats are under threat and governance of these systems is rapidly evolving. It is thus important to examine how we make sense of our rivers and how this understanding can underpin catchment management. Assemblage is one approach that can be used to understand our freshwater environments. In this article we reflect on an interdisciplinary project on angling to evaluate whether using assemblage may help us comprehend our rivers in new ways. We work through themes of: different perspectives of river processes, what constitutes evidence used in decision making, how the nexus between wildlife and the physical environment plays out, and the importance of rivers to our well-being. We demonstrate how assemblage can facilitate a deeper and more comprehensive understanding of relational processes and how these evolve over time. Assemblage can thus be used as a way of exploring rivers to support integrated management within complex systems of governance
Water ethics on a human-dominated planet : rationality, context and values in global governance.

A discourse on water ethics has emerged as a field linking practical water demands, social practices, and hydrological constraints to philosophic norms. The field arose parallel to growing, global understandings of the interconnected nature of water management and governance challenges. As such, it has been inflected with issues and contests across a range of policy concerns—from holistic and integrated water management to economics, justice, and human rights. The emerging water ethics discourse challenges both traditional environmental ethics and conventional approaches to resource management on issues of gender, power relations, and ecological concerns. It suggests an alternate, place-specific approach for linking shared water concerns to normative contests
The hydraulic description of vegetated river channels : the weaknesses of existing formulations and emerging alternatives.

Currently, many of the methods used to predict the effect of vegetation on river flow suffer from one or both of the following problems: (1) a strong dependence on parameters that have a poor physical basis and which are only readily determined using empirical means; and (2) a poor conceptual basis, in terms of the way they represent the effects of vegetation on the flow, especially in higher dimensionality numerical models. This limits their contribution to problems that extend beyond basic hydraulic prediction (e.g., of water levels) to ecosystem understanding. In this study, we show how use of coupled biomechanical–hydraulic models may lead to a much-improved representation of a range of open-channel flow processes. Preliminary experiments over hypothetical vegetation canopies are producing very encouraging results and may provide the means for an improved representation of vegetation in higher dimensionality numerical models that may result in a better justification and more reliable identification of the conveyance parameters needed for both flood identification and the characterization of habitat
What else do managers need to know about warming rivers? A United Kingdom perspective

This is the peer reviewed version of the following article: ORR, H.G. et al., 2015. What else do managers need to know about warming rivers? A United Kingdom perspective. Wiley Interdisciplinary Reviews: Water\ud
2 (2), pp. 55–64., which has been published in final form at http://dx.doi.org/10.1002/wat2.1062. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.River flow and water temperature are fundamental controls of freshwater ecosystems. Hence, future warming could impact valued habitats and species, particularly those with cold water preferences (such as salmonids). Warming could also exacerbate existing environmental pressures or diminish the effectiveness of management interventions. Climate model projections provide compelling evidence of the need for adaptation despite uncertainty about the timing, nature, and distribution of impacts on water quality, vulnerable species, and habitats. Low-regret adaptation options to manage temperature impacts include increasing riparian shade, enhancing thermal refugia, and removing thermal barriers or hotspots. Indirect controls include managing river flows through abstraction and discharge regulation, moderating flow control structures, and manipulating channel hydromorphology. However, fundamental gaps in understanding may limit the effectiveness of some of these measures, leading to undesired side effects, wasted resources, ineffectual outcomes, or limited uptake. These knowledge gaps include where to target measures, how to implement in different situations, how to maximize co-benefits and integrate with other policy objectives, and how to support implementation across rural and agricultural landscapes. Despite many uncertainties, restoration of riparian shade and river flows has the potential to deliver multiple benefits even if this does not include retarding rates of warming
A Review of Plant-Flow Interactions on Salt Marshes: The Importance of Vegetation Structure and Plant Mechanical Characteristics

Observations of plant-flow interactions on salt marshes have revealed a highly complex process dominated by the tightly coupled effects of plant characteristics and hydrodynamic conditions. This paper highlights the importance of vegetation structures such as plant density and height, as well as their spatial variability and mechanical properties including flexibility, upon energy dissipation and flow modification. Many field, laboratory and modelling studies which attempt to predict flow dissipation or improve our understanding of plant-flow interactions use simplified structural measures of salt marsh vegetation or artificial representations. These simplifications neglect important plant and canopy elements and are unlikely to be truly representative of their natural counterparts. Such approaches limit our understanding of plant-flow interactions and potentially compromise the predictive accuracy and application of numerical flow models. It is important therefore that improved techniques to measure vegetation structure are adopted in order to better define the key relationships between measurable plant characteristics and drag-relevant plant properties.This is the author accepted manuscript. The final version is available from Wiley via http://dx.doi.org/10.1002/wat2.110
Ecosystem impacts of Alpine water intakes for hydropower: the challenge of sediment management

The natural flow hydrological characteristics (such as the magnitude, frequency, duration, timing, and rate of change of discharge) of Alpine streams, dominated by snowmelt and glacier melt, have been established for many years. More recently, the ecosystems that they sustain have been described and explained. However, natural Alpine flow regimes may be strongly modified by hydroelectric power production, which impacts upon both river discharge and sediment transfer, and hence on downstream flora and fauna. The impacts of barrages or dams have been well studied. However, there is a second type of flow regulation, associated with flow abstraction at intakes where the water is transferred laterally, either to another valley for storage, or at altitude within the same valley for eventual release downstream. Like barrages, such intakes also trap sediment, but because they are much smaller, they fill more frequently and so need to be flushed regularly. Downstream, while the flow regime is substantially modified, the delivery of sediment (notably coarser fractions) remains. The ecosystem impacts of such systems have been rarely considered. Through reviewing the state of our knowledge of Alpine ecosystems, we outline the key research questions that will need to be addressed in order to modify intake management so as to reduce downstream ecological impacts. Simply redesigning river flows to address sediment management will be ineffective because such redesign cannot restore a natural sediment regime and other approaches are likely to be required if stream ecology in such systems is to be improved
Long-term perspectives on terrestrial and aquatic carbon cycling from palaeolimnology

Lakes are active processors and collectors of carbon (C) and thus recognized as quantitatively important within the terrestrial C cycle. Better integration of palaeolimnology (lake sediment core analyses) with limnological C budgeting approaches has the potential to enhance understanding of lacustrine C processing and sequestration. Palaeolimnology simultaneously assimilates materials from across lake habitats, terrestrial watersheds, and airsheds to provide a uniquely broad overview of the terrestrial-atmospheric-aquatic linkages across different spatial scales. The examination of past changes over decadal–millennial timescales via palaeolimnology can inform understanding and prediction of future changes in C cycling. With a particular, but not exclusive, focus on northern latitudes we examine the methodological approaches of palaeolimnology, focusing on how relatively standard and well-tested techniques might be applied to address questions of relevance to the C cycle. We consider how palaeolimnology, limnology, and sedimentation studies might be linked to provide more quantitative and holistic estimates of lake C cycling and budgets. Finally, we use palaeolimnological examples to consider how changes such as terrestrial vegetation shifts, permafrost thaw, the formation of new lakes and reservoirs, hydrological modification of inorganic C processing, land use change, soil erosion and disruption to global nitrogen and phosphorus cycles might influence lake C cycling
A transdisciplinary account of water research

TK acknowledges funding by the German Excellence Initiative through IRI THESys. GC acknowledges funding from the Austrian Science Funds (FWF) as part of the Vienna Doctoral Programme on Water Resource Systems (DK-plus W1219-N22).Water research is introduced from the combined perspectives of natural and social science and cases of citizen and stakeholder coproduction of knowledge. Using the overarching notion of transdisciplinarity, we examine how interdisciplinary and participatory water research has taken place and could be developed further. It becomes apparent that water knowledge is produced widely within society, across certified disciplinary experts and noncertified expert stakeholders and citizens. However, understanding and management interventions may remain partial, or even conflicting, as much research across and between traditional disciplines has failed to integrate disciplinary paradigms due to philosophical, methodological, and communication barriers. We argue for more agonistic relationships that challenge both certified and noncertified knowledge productively. These should include examination of how water research itself embeds and is embedded in social context and performs political work. While case studies of the cultural and political economy of water knowledge exist, we need more empirical evidence on how exactly culture, politics, and economics have shaped this knowledge and how and at what junctures this could have turned out differently. We may thus channel the coproductionist critique productively to bring perspectives, alternative knowledges, and implications into water politics where they were not previously considered; in an attempt to counter potential lock‐in to particular water policies and technologies that may be inequitable, unsustainable, or unacceptable. While engaging explicitly with politics, transdisciplinary water research should remain attentive to closing down moments in the research process, such as framings, path‐dependencies, vested interests, researchers’ positionalities, power, and scale.Publisher PDFPeer reviewe
Recent progresses in incorporating human land-water management into global land surface models toward their integration into Earth system models

The global water cycle has been profoundly affected by human land–water management. As the changes in the water cycle on land can affect the functioning of a wide range of biophysical and biogeochemical processes of the Earth system, it is essential to represent human land–water management in Earth system models (ESMs). During the recent past, noteworthy progress has been made in large-scale modeling of human impacts on the water cycle but sufficient advancements have not yet been made in integrating the newly developed schemes into ESMs. This study reviews the progresses made in incorporating human factors in large-scale hydrological models and their integration into ESMs. The study focuses primarily on the recent advancements and existing challenges in incorporating human impacts in global land surface models (LSMs) as a way forward to the development of ESMs with humans as integral components, but a brief review of global hydrological models (GHMs) is also provided. The study begins with the general overview of human impacts on the water cycle. Then, the algorithms currently employed to represent irrigation, reservoir operation, and groundwater pumping are discussed. Next, methodological deficiencies in current modeling approaches and existing challenges are identified. Furthermore, light is shed on the sources of uncertainties associated with model parameterizations, grid resolution, and datasets used for forcing and validation. Finally, representing human land–water management in LSMs is highlighted as an important research direction toward developing integrated models using ESM frameworks for the holistic study of human–water interactions within the Earths system
Environmental flows - basics for novices

The term environmental flows has become widely used to define the hydrological regime required to sustain freshwater and estuarine ecosystems and the human livelihoods and well-being that depend on them. A large range of frameworks and methods has been developed to assess environmental flow needs and many authors have identified subtleties in the approaches needed for different situations and required outcomes. This article summaries some basic concepts that can assist those new to environmental flows to navigate the rapidly expanding plethora of information. It briefly covers key areas of setting objectives for river ecosystems, examining pressures that constrain reaching these objectives, the level of detail needed, implementation, and how future changes affect environmental flow assessments