pinecone/core-2020-05-10-deduplication huggingface dataset:
Optical Matrix Element in InAs/GaAs Quantum Dots: Dependence on Quantum Dot Parameters

<p>We present a theoretical analysis of the optical matrix element between the electron and hole ground states in InAs/GaAs quantum dots (QDs) modeled with a truncated pyramidal shape. We use an eight-band k center dot p Hamiltonian to calculate the QD electronic structure, including strain and piezoelectric effects. The ground state optical matrix element is very sensitive to variations in both the QD size and shape. For all shapes, the matrix element initially increases with increasing dot height, as the electron and hole wave functions become more localized in k space. Depending on the QD aspect ratio and on the degree of pyramidal truncation, the matrix element then reaches a maximum for some dot shapes at intermediate size beyond which it decreases abruptly in larger dots, where piezoelectric effects lead to a marked reduction in electron-hole overlap.</p
On worst-case investment with applications in finance and insurance mathematics

We review recent results on the new concept of worst-case portfolio optimization, i.e. we consider the determination of portfolio processes which yield the highest worst-case expected utility bound if the stock price may have uncertain (down) jumps. The optimal portfolios are derived as solutions of non-linear differential equations which itself are consequences of a Bellman principle for worst-case bounds. They are by construction non-constant ones and thus differ from the usual constant optimal portfolios in the classical examples of the Merton problem. A particular application of such strategies is to model crash possibilities where both the number and the height of the crash is uncertain but bounded. We further solve optimal investment problems in the presence of an additional risk process which is the typical situation of an insurer
Electrochemical codeposition of nickel oxide and polyaniline

Nickel oxide (NiOx) and polyaniline (PAni) were\ud
electrocodeposited from NiSO4 and aniline through cyclic\ud
voltammetric scans to afford PAni–NiOx composite film at\ud
controlled pH environment. The electrochemical activities of\ud
the film were investigated by cyclic voltammetry in 0.1 M\ud
NaOH and 0.1 M H2SO4, respectively. Typical redox couples\ud
of PAni in 0.1 M H2SO4 appeared at approximately 0.2 and\ud
0.4 V vs. saturated calomel electrode (SCE); Ni(II)/Ni(III)\ud
redox couple was observed at approximately 0.4 V vs. SCE in\ud
0.1 M NaOH. The morphologies and elemental components\ud
of the films were inspected by scanning electron microscopy\ud
and energy dispersive X-ray diffraction. The stability of nickel\ud
oxide in the films was found to be enhanced against acidic\ud
environments. Electrochemical catalytic behavior of NiOx\ud
within the composite film was conserved and demonstrated\ud
by catalytic oxidation of methanol and ethanol
Photoionization of the Ne-like Si4+ ion in ground and metastable states in the 110–184-eV photon energy range

We present measurements of the absolute photoionization cross section of the neonlike Si4+ ion over the 110–184 eV photon energy range. The measurements were performed using two independent merged-beam setups at the super-ACO and ASTRID synchrotron-radiation facilities, respectively. Signals produced in the photoionization of the 2p subshell of the Si4+ ion both from the 2p6 1S0 ground state and the 2p53s 3P0,2 metastable levels were observed. Calculations of the 2p photoionization cross sections were carried out using a multi-configuration Dirac-Fock code. They give results in good agreement with the measured spectra. Comparison with other available theoretical results is also presented
Effect of temperature on the durability of class C fly ash belite cement in simulated radioactive liquid waste: Synergy of chloride\ud
and sulphate ions

The durability of class C fly ash belite cement (FABC-2-W) in simulated radioactive liquid waste (SRLW) rich in a mixed sodium chloride and sulphate solution is presented here. The effect of the temperature and potential synergic effect of chloride and sulfate ions are discussed. This study has been carried out according to theKoch–Steinegger test, at the temperature of 20 ◦Cand 40 ◦Cduring a period of 180days. The durability has been evaluated by the changes of the flexural strength of mortar, fabricatedwith this cement, immersed in a simulated radioactive liquid waste rich in sulfate (0.5 M), chloride (0.5M) and sodium (1.5M) ions – catalogued like severely aggressive for the traditional Portland cement – and demineralised water, which was used as reference. The reaction mechanism of sulphate, chloride and sodium ions with the mortar was evaluated by scanning electron microscopy (SEM), porosity and pore-size distribution, and X-ray diffraction (XRD). The results showed that the chloride binding and formation of Friedel’s salt was inhibited by the presence of sulphate. Sulphate ion reacts preferentially with the calcium aluminate hydrates forming non-expansive ettringite which precipitated inside the pores; the microstructure was refined and the mechanical properties enhanced. This process was faster and more marked at 40 ◦C
Programmed design of ship forms

This paper describes a new category of CAD applications devoted to the definition and parameterization of hull forms, called programmed design. Programmed design relies on two prerequisites. The first one is a product model with a variety of types large enough to face the modeling of any type of ship. The second one is a design language dedicated to create the product model. The main purpose of the language is to publish the modeling algorithms of the application in the designer knowledge domain to let the designer create parametric model scripts. The programmed design is an evolution of the parametric design but it is not just parametric design. It is a tool to create parametric design tools. It provides a methodology to extract the design knowledge by abstracting a design experience in order to store and reuse it. Programmed design is related with the organizational and architectural aspects of the CAD applications but not with the development of modeling algorithms. It is built on top and relies on existing algorithms provided by a comprehensive product model. Programmed design can be useful to develop new applications, to support the evolution of existing applications or even to integrate different types of application in a single one. A three-level software architecture is proposed to make the implementation of the programmed design easier. These levels are the conceptual level based on the design language, the mathematical level based on the geometric formulation of the product model and the visual level based on the polyhedral representation of the model as required by the graphic card. Finally, some scenarios of the use of programmed design are discussed. For instance, the development of specialized parametric hull form generators for a ship type or a family of ships or the creation of palettes of hull form components to be used as parametric design patterns. Also two new processes of reverse engineering which can considerably improve the application have been detected: the creation of the mathematical level from the visual level and the creation of the conceptual level from the mathematical level. © 2012 Elsevier Ltd. All rights reserved. 1. Introductio
Questioning polycentric development and its effects: issues of definition and measurement for the Italian NUTS 2 Regions

Polycentric development is a widely-used term both in academic research and in the normative agenda. However, its theoretical foundations and economic implications are still unknown and the concept of polycentricity still does not have a shared definition, or a shared measurement method. The aim of this paper is twofold. Firstly polycentricity is defined and measured at a NUTS 2 regional level, by comparing functional and morphological methods. Secondly, in the light of the role assigned to polycentric development in terms of policy, the paper investigates the relationships between the degree of regional polycentricity and the key economic variables of performance – namely competitiveness, social cohesion and environmental sustainability.  The main finding was that functional and morphological methods led to similar results. In addition, a correlation was found between polycentricity and a more unequal income distribution and a higher level of productivity, especially when polycentricity was measured in functional terms. No stable correlations were found between polycentricity and measures of environmental sustainability, such as land consumption and greenhouse emissions.
Estimation and Regularization Techniques for Regression Models with Multidimensional Prediction Functions

Boosting is one of the most important methods for fitting regression models and building prediction rules from high-dimensional data. A notable feature of boosting is that the technique has a built-in mechanism for shrinking coefficient estimates and variable selection. This regularization mechanism makes boosting a suitable method for analyzing data characterized by small sample sizes and large numbers of predictors. We extend the existing methodology by developing a boosting method for prediction functions with multiple components. Such multidimensional functions occur in many types of statistical models, for example in count data models and in models involving outcome variables with a mixture distribution. As will be demonstrated, the new algorithm is suitable for both the estimation of the prediction function and regularization of the estimates. In addition, nuisance parameters can be estimated simultaneously with the prediction function.
Investigation of flow structures involved in sound generation by two- and three-dimensional cavity flows

Proper Orthogonal Decomposition and Stochastic Estimation are combined to shed some light on the link between organized flow structures and noise generation by turbulent flows. Proper Orthogonal Decomposition (POD) is firstly used to extract selected flow events. Based on the knowledge of these structures, the Quadratic Stochastic Estimation of the acoustic pressure field is secondly performed. Both procedures are successively applied to two- and three-dimensional numerical databases of a flow over a cavity. It is demonstrated that POD can extract selected aerodynamic events which can be associated with selected frequencies in the acoustic spectra. Reconstructed acoustic fields also indicate the aerodynamic events which are responsible of the main energy of the noise emission. Such mathematical tools offer new perspectives in analysing flow structures involved in sound generation by turbulent flows and in the experimental design of a flow control strategy
A general kinetic model for the photothermal oxidation of polypropylene

A general kinetic model for the photothermal oxidation of polypropylene has been derived from the basic auto-oxidation mechanistic scheme in which the main sources of radicals are the thermolysis and photolysis of the most unstable species, i.e hydroperoxides. Thermolysis is a uni- or bi-molecular reaction whose rate constant obeys an Arrhenius law. In contrast, photolysis is exclusively a unimolecular reaction and its rate constant is independent of temperature. According to the quantum theory, this latter is proportional to the energy absorbed by photosensitive species and thus, accounts for the impact of UV-light intensity and wavelength on the global oxidation kinetics.
The validity of this model has been checked on iPP films homogeneously oxidized in air over a wide range of temperatures and UV-light sources. It gives access to the concentration changes of: (i) primary (hydroperoxides) and secondary (carbonyls) oxidation products, (ii) double bonds, (iii) chain scissions and crosslinking nodes, but also to the subsequent changes in molecular masses. These calculations are in full agreement with the photolysis results reported by Carlsson and Wiles in the 70s [1–3]. However, the model seems to be only valid for UV-light energies equivalent to about 10 suns as upper boundary, presumably because of multiphotonic excitations or chromophores photosensitization (i.e. termolecular photo-physical reactions), both enhanced at high irradiances
Long repeat tracts at SCA8 in major psychosis

Expansion at a recently identified unstable trinucleotide repeat on chromosome 13q21 has been reported as the molecular cause for spinocerebellar ataxia type 8 (SCA8). The trinucleotide repeat, which consists of a [CTA]n repeat and adjacent [CTG]n repeat, was reported to have a pathogenic range of 107-127 CTG repeats (or 110-130 combined CTA and CTG repeats) in a large ataxia kindred. This repeat region was also cloned by our group from a bipolar affective disorder (BPAD) patient, who has approximately 600 combined repeats, and large alleles (>100 repeats) were reported to be present in 0.7% of controls and 1.5% of major psychosis patients (n = 710 and n = 1,120, respectively). We have followed up these findings by screening three new samples of BPAD and schizophrenia (SCZ) patients and controls, including 272 individuals from 14 BPAD families from Sweden, 130 individuals from 32 SCZ and BPAD families/trios from the Azores Islands, and 206 SCZ individuals from the United Kingdom and Ireland, and 219 matched controls. We found large repeat alleles above the SCA8 pathogenic range in individuals from 3 of 32 Azorean pedigrees and in 1 of 206 SCZ individuals from the United Kingdom, and repeat alleles within the SCA8 pathogenic range in 1 of 14 Swedish families. Although the rarity of major psychosis patients carrying the SCA8 expansion mutation would require a much larger sample size to reach statistical significance, these results support the previously reported observation of increased occurrence of large repeats at SCA8 in major psychosis. Am. J. Med. Genet. (Neuropsychiatr. Genet.) 96:873-876, 2000. © 2000 Wiley-Liss, Inc.http://dx.doi.org/10.1002/1096-8628(20001204)96:6<873::AID-AJMG37>3.0.CO;2-
Control of ZnO nanowire arrays by nanosphere lithography (NSL) on laser-produced ZnO substrates

Nanosphere lithography (NSL) is a successful technique for fabricating highly ordered arrays of ZnO nanowires typically on sapphire and GaN substrates. In this work, we investigate the use of thin ZnO films deposited on Si by pulsed laser deposition (PLD) as the substrate. This has a number of advantages over the alternatives above, including cost and potential scalability of production and it removes any issue of inadvertent n-type doping of nanowires by diffusion from the substrate. We demonstrate ordered arrays of ZnO nanowires, on ZnO-coated substrates by PLD, using a conventional NSL technique with gold as the catalyst. The\ud
nanowires were produced by Vapor Phase Transport (VPT) growth in a tube furnace system and grew only on the areas pre-patterned by Au. We have also investigated the growth of ZnO nanowires using ZnO catalyst points deposited by PLD through an NSL mask on a bare silicon substrate
Teacher professional development to support teacher professional learning: Systemic Factors from Irish case studies

Teacher professional learning is widely accepted as a mediating factor for enhancing student outcomes. While many teachers across the world engage in professional development (PD) to enhance their professional learning, what is 10 less evident is how to support that learning to result in change following teacher PD. Acknowledging that not all teacher PD needs to result in new practices and change this paper focuses on a transformative model of PD, focused on implementing and sustaining change. This paper offers evidence of successful implementation and sustainability of practices by drawing from in-depth 15 semi-structured interviews with teachers and principals in five Irish case study schools. It reports on the Systemic Factors to support implementation and\ud
sustainability of change: Support, Initiative design and Impact and Teacher Agency. Implications are drawn for bridging the gap between knowledge and practice or teacher PD and change within schools
Theory Assessment and Final Theory Claim in String Theory

String theory has by now maintained a highly influential position in high energy physics for more than a quarter of a century. The present article analyses the reasons for the considerable trust exponents of string theory have in their theory even though it has neither found empirical confirmation nor a complete formulation up to this point. It is argued that this trust can be understood in terms of an emerging new conception of theory assessment that relies strongly on the identification of limitations to the underdetermination of scientific theory building. The second part of the paper makes the point that another conspicuous element of string theoretical reasoning, the prominent role of the notion of a final theory, can be understood in terms of this altered notion of theory assessment as well
Solution-phase racemization in the presence of an enantiopure solid phase.

Solution-phase racemization\ud
drives the evolution of single chirality\ud
in the solid phase by the "chiral amnesia"\ud
process first described by Viedma.\ud
The current investigations lay the basis\ud
for a better understanding of the mechanism\ud
of the solid-phase deracemization\ud
by uncoupling the chemical rate\ud
processes associated with the interconversion\ud
of enantiomers in the solution\ud
phase from the physical processes associated\ud
with solution-solid phase transfer\ud
via dissolution and reaccretion of\ud
molecules onto crystals. In addition,\ud
the enantiomer concentration profiles\ud
presented in this work, together with\ud
an analytical treatment of the racemization\ud
process in the presence of excess\ud
enantiopure solid, unequivocally reconfirm\ud
the validity of the Meyerhoffer\ud
double solubility rule for systems\ud
under solution racemization conditions
Natural selection on cork oak: allele frequency reveals divergent selection in cork oak populations along a temperature cline

A recent study of population divergence at neutral markers and adaptive traits in cork oak has observed an association between genetic distances at locus QpZAG46 and genetic distances for leaf size and growth. In that study it was proposed that certain loci could be linked to genes encoding for adaptive traits in cork oak and, thus, could be used in adaptation studies. In order to investigate this hypothesis, here we (1) looked for associations between molecular markers and a set of adaptive traits in cork oak, and (2) explored the effects of the climate on among-population patterns in adaptive traits and molecular markers. For this purpose, we chose 9-year-old plants originating from thirteen populations spanning a broad range of climatic conditions. Plants established in a common garden site were genotyped at six nuclear microsatellites and phenotypically characterized for six functional traits potentially related to plant performance. Our results supported the proposed linkage between locus QpZAG46 and genes encoding for leaf size and growth. Temperature caused adaptive population divergence in leaf size and growth, which was expressed as differences in the frequencies of the alleles at locus QpZAG46
Theoretical optimization of GaInP/GaAs dual-junction solar cell: Toward a 36% efficiency at 1000 suns

A theoretical conversion efficiency of 36.4% at 1000 suns concentration has been determined by means of realistic models and an improved optimization routine. The starting point device was the recent world-record monolithic GaInP/GaAs dual-junction solar cell that was grown lattice matched on a GaAs substrate by MOVPE, which has an efficiency of 32.6% at 1000 suns. Using previously calibrated models developed at our institution, IES-UPM, together with Silvaco ATLAS TCAD software, we reproduced the characteristics of the world-record solar cell, and then determined a cell configuration that would yield greater efficiency by using an optimization routine to hone the doping concentration and the thickness of each layer
Symmetry issues in Directly Irradiated Targets

In direct drive Inertial Conﬁnement Fusion (ICF), the typical laser beam to laser beam angle is around 30o. This fact makes the study of the irradiation symmetry agenuine 3D problem. In this paper we use the three dimensional version of the MULTI hydrocode to assess the symmetry of such ICF implosions. More speciﬁcally, we study a shock-ignition proposal for the Laser-M´egajoule facility (LMJ) in which two of the equatorial beam cones are used to implode and pre compress a spherical capsule (the “reference” capsule of HiPER project) made of 0.59 mg of pure Deuterium-Tritium mixture. The symmetry of this scheme is analysed and optimized to get a design inside the operating limits of LMJ. The studied conﬁguration has been found essentially axial-symmetric, so that the use of 2D hydrocodes would be appropriate for this speciﬁc situatio
TIDA: A spanish EHR semantic search engine

Electronic Health Records (EHR) and the constant adoption of Information Technologies in healthcare have dramatically increased the amount of unstructured data stored. The extraction of key information from this data will bring better caregivers decisions and an improvement in patients? treatments. With more than 495 million people talking Spanish, the need to adapt algorithms and technologies used in EHR knowledge extraction in English speaking countries, leads to the development of different frameworks. Thus, we present TIDA, a Spanish EHR semantic search engine, to give support to Spanish speaking medical centers and hospitals to convert pure raw data into information understandable for cognitive systems. This paper presents the results of TIDA?s Spanish EHR free-text treatment component with the adaptation of negation and context detection algorithms applied in a semantic search engine with a database with more than 30,000 clinical notes