pinecone/core-2020-05-10-deduplication huggingface dataset:
Physical and Mechanical Properties of CrAlN and CrSiN Ternary Systems for Wood Machining Applications

Nowadays, almost all the cutting tools in metal machining are protected with a surface treatment. Nevertheless, this is not the case in woodmachining where no tools are protected, except by thermal treatments, and so they present a previous wear because of the use of steel or carbide materials in milling, sawing, routing, etc. During these processes, the tools are particularly exposed to abrasive and shock wear. To enhance their wear resistance, one solution is to protect them with hard coatings. The present study deals with the development of ternary systems (CrAlN and CrSiN) obtained by two PVD different magnetron sputtering systems [‘A’ (laboratory where CrAlN layers
have been obtained) and ‘B’ (laboratory where CrSiN layers have been obtained) in the following text] on carbide WC–Co tools used in second transformation of wood to be compared to the binary CrN one. CrAlN and CrSiN films were deposited with different Al and Si contents, respectively, in order to check the effect of the additive element (Al or Si) on the different properties of the Cr–N system. The different coatings were characterized by SEM and EDS for thickness measurements, morphology and composition analyses, respectively, by nanoindentation for hardness and Young’s modulus measurements and by pin-on-disc to determine their friction coefficient. Routing of medium density fibreboard (MDF) was realized employing untreated or modified carbide WC–Co
tools in order to compare their wear resistance. We observed that the Al and the Si addition improved the hardness and the Young’s modulus of the Cr–N system (‘A’: 29 and 410 GPa, respectively, ‘B’: 18 and 280 GPa, respectively). Indeed, the hardness values are 15–36GPa for CrAlN and 15–24 GPa for CrSiN coatings. Besides, the Young’s modulus values are 331–520GPa for CrAlN and 260–320 GPa for CrSiN coatings. The friction coefficient of the CrAlN layers varied between 0.6 and 0.7 and it increased slightly with the Al content. For the CrSiN coatings, the friction coefficient
was lower and about 0.4. In both cases, the CrN layers ‘A’ and ‘B’ presented similar friction coefficient than CrAlN and CrSiN, respectively. During the routing of MDF, the CrN ‘A’ coating has a similar wear behaviour than the optimized CrAlN one (5 at.% of Al) while the optimized CrSiN coating (1.2 at.% of Si) showed a better behaviour against wear than the CrN ‘B’ one. The wear resistance of CrAlN- and CrSiN-coated carbide tools ecreased when the Al and Si contents increased.Regional Council of Burgundy
Regional Council of Franche-Comté
ISOROY Franc
Plasma Functionalization of Multiwalled Carbon Nanotubes and Their Use in the Preparation of Nylon 6-Based Nanohybrids

The possibility to obtain carbon nanotubes (CNT)/polyamide 6 composites with excellent mechanical properties in a simple, industrially scalable way is investigated. Commercial CNTs are treated by plasma while changing some key parameters (exposure time, plasma power, type of gas) in order to optimize the process and to achieve a sufficient degree of functionalization. The treated samples are characterized by Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The most interesting samples are selected to be used as reinforcing fillers, in different concentrations, in a polyamide 6 matrix. The mechanical tests show a dramatic increase of both tensile and impact properties, due to the achievement of a good wettability, and an efficient dispersion of the CNTs in the polymer matrix, as confirmed by scanning electron microscopy observations
Effect of particle size on silver nanoparticle deposition onto dielectric barrier discharge (DBD) plasma functionalized polyamide fabric

The effect on the deposition of three different size silver nanoparticles (AgNPs) onto a polyamide 6,6 (PA) fabric pre-treated using air dielectric barrier discharge (DBD) plasma was investigated. The SEM, EDS, and XPS analysis confirm that the smaller is the diameter of AgNPs, the higher the amount of adsorbed NPs on the PA. The DBD treatment on PA induces a threefold increase in Ag adsorption. The result confirms a dual effect on the wettability of the plasma treated PA substrate. AgNPs slightly enhance hydrophobicity of the PA surface and, at the same time, protect it against the plasma aging effect. The effect on the deposition of three different size silver nanoparticles (AgNPs) onto a Polyamide 6,6 (PA) fabric pre-treated using air dielectric barrier discharge (DBD) plasma was investigated. The smaller is the size, the higher the loaded AgNPs. The DBD treatment induces a threefold increase in Ag adsorption. AgNPs enhance hydrophobicity of the PA surface and reduce the plasma aging effect.Fundação para a Ciência e a Tecnologia (FCT
Plasma treatment in textile industry

Plasma technology applied to textiles is a dry, environmentally- and worker-friendly method
to achieve surface alteration without modifying the bulk properties of different materials.
In particular, atmospheric non-thermal plasmas are suited because most textile materials
are heat sensitive polymers and applicable in a
continuous processes. In the last years plasma
technology has become a very active, high growth
research field, assuming a great importance among
all available material surface modifications in
textile industry. The main objective of this review
is to provide a critical update on the current state of
art relating plasma technologies applied to textile
industryFernando Oliveira (SFRH/BD/65254/2009) acknowledges Fundacao para a Cioncia e Tecnologia, Portugal, for its doctoral grant financial support. Andrea Zille (C2011-UMINHO-2C2T-01) acknowledges funding from Programa Compromisso para a Cioncia 2008, Portugal
Ag:TiN-Coated Polyurethane for Dry Biopotential Electrodes: From Polymer Plasma Interface Activation to the First EEG Measurements

Several plasma treatments using argon, oxygen, and nitrogen are studied in order to increase the interfacial adhesion of the polyurethane/Ag:TiN system to be used as biopotential electrodes. The optimized plasma treatments conditions (100 W, 15 min, regardless of the gas) promote a steep decrease of the water contact angle values. The observed chemical and topographic alterations translate into excellent polyurethane/Ag:TiN interfacial adhesion of the plasma treated samples. The in-service validation of the proposed Ag:TiN-coated PU multipin electrodes is performed by acquiring EEG signals in parallel with the standard wet Ag/AgCl electrodes. No considerable differences are found in terms of shape, amplitude, and spectral characteristics of the signals when comparing reference wet and dry electrodes.This research is partially sponsored by FEDER funds through the program COMPETE – Programa Operacional Factores de Competitividade and by national funds through FCT – Fundação para a Ciência e a Tecnologia, under the projects PEst-C/EME/UI0285/2011, PTDC/SAU-ENB/116850/2010, PTDC/CTM-NAN/112574/2009 and Programa Pessoa 2012/2013 Cooperação Portugal/França, Project no. 27306UA Porous architectures in GRAded CERamic thin films for biosensors - GRACER. The authors would also like to acknowledge CEMUP for SEM analysis and Yantai Wanhua Polyurethanes Co., Ltd for providing the thermoplastic polyurethane pellets. P. Pedrosa acknowledges FCT for the Ph.D. grant SFRH/BD/70035/2010. P. Fiedler acknowledges the German Federal Ministry of Education and Research project – 03IPT605A. P. Pedrosa and P. Fiedler both acknowledge FP7-People Marie Curie IAPP project 610950 (ANDREA) and German Academic Exchange Services for the Germany/Portugal bi-lateral project – D/57036536
Quantum-mechanical calculations of cross sections for electron
  collisions with atoms and molecules

An overview of quantum-mechanical methods to generate cross-section data for
electron collisions with atoms and molecules is presented. Particular emphasis
is placed on the time-independent close-coupling approach, since it is
particularly suitable for low-energy collisions and also allows for systematic
improvements as well as uncertainty estimates. The basic ideas are illustrated
with examples for electron collisions with argon atoms and methane. For many
atomic systems, such as e-Ar collisions, highly reliable cross sections can now
be computed with quantified uncertainties. On the other hand, while electron
collision calculations with molecules do provide key input data for plasma
models, the methods and computer codes presently used require further
development to make these inputs robust.Comment: in press with Plasma Processes and Polymer
Particle-in-Cell/Test-Particle Simulations of Technological Plasmas:
  Sputtering Transport in Capacitive Radio Frequency Discharges

The paper provides a tutorial to the conceptual layout of a self-consistently
coupled Particle-In-Cell/Test-Particle model for the kinetic simulation of
sputtering transport in capacitively coupled plasmas at low gas pressures. It
explains when a kinetic approach is actually needed and which numerical
concepts allow for the inherent nonequilibrium behavior of the charged and
neutral particles. At the example of a generic sputtering discharge both the
fundamentals of the applied Monte Carlo methods as well as the conceptual
details in the context of the sputtering scenario are elaborated on. Finally,
two in the context of sputtering transport simulations often exploited
assumptions, namely on the energy distribution of impinging ions as well as on
the test particle approach, are validated for the proposed example discharge
Psychotherapy under Capitalism: The Production, Circulation and Management of Value and Subjectivity

This article is concerned with the place of psychotherapy under capitalism. This is addressed using elements of the critique of political economy undertaken by Marx. I also argue that a Marxist critique of capitalist political economy is also necessarily feminist. I include analyses of the “feminisation” of work in order to grasp how value is produced, circulated and managed by psychotherapy, how subjectivity is targeted. Three aspects of psychotherapy are discussed to illustrate the value of a Marxist feminist approach to this particular practice of the self: the question of payment for the labour of a psychotherapist (and the labour of the client); the question of public health provision, focusing here on the UK's National Health Service; and the continuing debates about the role of the State and the regulation of public and private provision of psychotherapy. Copyright © 2014 John Wiley & Sons, Ltd.Peer-reviewedPost-prin
Characterisation of the Permafrost Carbon Pool

The current estimate of the soil organic carbon (SOC) pool in the northern permafrost region of 1672 Petagrams (Pg),C is much larger than previously reported and needs to be incorporated in global soil carbon (C) inventories. The Northern Circumpolar Soil Carbon Database (NCSCD), extended to include the range 0–300 cm, is now available online for wider use by the scientific community. An important future aim is to provide quantitative uncertainty ranges for C pool estimates. Recent studies have greatly improved understanding of the regional patterns, landscape distribution and vertical (soil horizon) partitioning of the permafrost C pool in the upper 3m of soils. However, the deeper C pools in unconsolidated Quaternary deposits need to be better constrained. A general lability classification of the permafrost C pool should be developed to address potential C release upon thaw. The permafrost C pool and its dynamics are beginning to be incorporated into Earth System models, although key periglacial processes such as thermokarst still need to be properly represented to obtain a better quantification of the full permafrost C feedback on global climate change
Non-invasive geophysical investigation and thermodynamic analysis of a palsa in Lapland, northwest Finland

Non-invasive geophysical prospecting and a thermodynamic model were used to examine the structure, depth and lateral extent of the frozen core of a palsa near Lake Peerajärvi, in northwest Finland. A simple thermodynamic model verified that the current climatic conditions in the study area allow sustainable palsa development. A ground penetrating radar (GPR) survey of the palsa under both winter and summer conditions revealed its internal structure and the size of its frozen core. GPR imaging in summer detected the upper peat/core boundary, and imaging in winter detected a deep reflector that probably represents the lower core boundary. This indicates that only a combined summer and winter GPR survey completely reveals the lateral and vertical extent of the frozen core of the palsa. The core underlies the active layer at a depth of ~0.6 m and extends to about 4 m depth. Its lateral extent is ~15 m x ~30 m. The presence of the frozen core could also be traced as minima in surface temperature and ground conductivity measurements. These field methods and thermodynamic models can be utilized in studies of climate impact on Arctic wetlands
Impact of Lake-Level and Climate Changes on Microbial Communities in a Terrestrial Permafrost Sequence of the El'gygytgyn Crater, Far East Russian Arctic

Microbial permafrost communities play an important role in carbon cycling and greenhouse gas fluxes. Despite the importance of these processes, there is a lack of knowledge about how environmental and climatic changes affect the abundance and composition of microorganisms. Here, we investigated the changing distribution of permafrost microorganisms in response to climate and lake-level changes. The permafrost core was drilled at the near shore of Lake El'gygytgyn, Far East Russian Arctic, and a combined microbiological and lipid biomarker approach was applied. The lower part of the permafrost core, deposited under subaquatic conditions, contains only small amounts of microbial signals; total organic carbon (TOC) content is sparse. After exposure of the site to subaerial conditions during the Allerød, the abundance of Bacteria and Archaea started to increase and the lake-level change is especially evidenced by the relative proportion of archaeal biomarkers. This increase is supported by rising bacterial and archaeal 16S ribosomal ribonucleic acid (rRNA) gene copy numbers and significant amounts of TOC during the late Allerød. After a small decrease during the colder Younger Dryas, the TOC content and the microbial signals strongly increase during the Holocene, presumably stimulated by pedogenesis. The occurrence of intact phospholipids indicates the presence of living microorganisms in these deposits. Our data suggest that methane formation is mainly expected for the subaerial interval, especially the Holocene where methanogens were identified by fingerprinting. This study emphasises the role of the uppermost permafrost deposits as a hotspot of carbon cycling in arctic environments, especially in the light of expected future global warming
Feasibility of Ice Segregation Location by Acoustic Emission Detection: A Laboratory Test in Gneiss

Large slope failures in steep alpine bedrock present significant geological hazards. Ice segregation is thought to be one of the mechanisms involved in high-mountain bedrock fracture but has not been reproduced experimentally in hard, intact rock. Here, we report results from a 3 month freezing experiment that aimed to reproduce ice-lens growth at the interface between the active layer and permafrost in a 15 cm cube of hard, intact rock (Arolla gneiss). Monitoring of acoustic emissions (AEs) recorded the propagation of microcracks horizontally through the block, resulting in a continuous and thick macrocrack near the base of the artificial active layer. Microcracking occurred within an approximate temperature range of 0.5 °C to 2.7 °C, consistent with ice segregation theory. Hypocentres of recorded AE events were concentrated in a 40mm thick band between depths of 4.5 and 8 cm in the block. The band approximately coincides with the frozen fringe and indicates that ice segregation can induce micro- and macrocracking in gneis
Characteristics and origin of rock glaciers in northern Tien Shan (Kazakhstan/Kyrgyzstan)

Northern Tien Shan is characterised by a distinct periglacial belt that contains many rock glaciers with an area of 1km² or more. To investigate the reason for their large size and variable occurrence, we analysed a representative subsample of the rock glaciers with respect to topographic and climatic variables. A simple permafrost model indicates that the rock glaciers originate in the zone where permafrost occurrence is very likely and some large rock glaciers flow down to elevations where permafrost is unlikely to exist outside the rock glaciers themselves. Correlation and multiple regression analyses revealed that the occurrence and characteristics of the rock glaciers can only be partly explained by the characteristics of the contributing area (e.g. its area or the headwall height). The correlation is greater with talus-type rock glaciers than with moraine-type rock glaciers. The climate can explain the general occurrence of rock glaciers but not their specific characteristics. It is hypothesised that the main reason for the specific distribution and characteristics of these large rock glaciers relates to the interaction with polythermal glaciers, topographic characteristics, intensive weathering and rock avalanches triggered by seismic activity
Assessing Permafrost Degradation and Land Cover Changes (1986-2009) using Remote Sensing Data over Umiujaq, Sub-Arctic Québec

Recent land cover changes in the Umiujaq region of northern Québec, Canada, have been quantified in order to estimate changes in the extent of discontinuous permafrost that strongly affect the forest-tundra ecotone. Changes in the areas covered by different vegetation types, thermokarst lakes, and degradation of lithalsas, have been investigated over an area of 60 km², extending from widespread discontinuous permafrost in the north to areas of scattered permafrost in the south, and from Hudson Bay in the west to the Lac Guillaume-Delisle graben 10 km further east. We used high resolution remote-sensing images (QuickBird 2004, GeoEye 2009) and four Landsat scenes (1986, 1990, 2001, 2008) as well as ground based data (vegetation, active layer thickness (ALT), snow parameters) collected between 2009 and 2011. Two change detection methods applied to estimate the land cover changes between 1986 and 2009 showed an overall increase in vegetation extent between 1986 and 2009, and a 21% increase in tall vegetation (spruce and tall shrubs) between 2004 and 2009 at the expense of low vegetation (lichens, prostrate shrubs, herbaceous vegetation). Thermokarst lakes and lithalsas in 10 sub-areas were mapped manually from satellite imagery. The area covered by water decreased by 24% between 2004 and 2009, often due to vegetation colonizing the margins of lakes, and ninety three of the observed lakes disappeared completely over that period. The area covered by lithalsas declined by 6%. Our results demonstrate the viability of using high resolution satellite imagery to detect changes in the land surface that can serve as indicators of permafrost degradation in the sub-Arctic
Mid-Wisconsin to Holocene Permafrost and Landscape Dynamics based on a\ud
Drained Lake Basin Core from the Northern Seward Peninsula, Northwest Alaska

Permafrost-related processes drive regional landscape dynamics in the Arctic terrestrial system. A better understanding of past periods indicative of permafrost degradation and aggradation is important for predicting the future response of Arctic landscapes to climate change. Here, we used a multi-proxy approach to analyse a ~ 4m long sediment core from a drained thermokarst lake basin on the northern Seward Peninsula in western Arctic Alaska (USA). Sedimentological, biogeochemical, geochronological, micropalaeontological (ostracoda, testate amoebae) and tephra analyses were used to determine the long-term environmental Early-Wisconsin to Holocene history preserved in our core for central Beringia. Yedoma accumulation dominated throughout the Early to Late-Wisconsin but was interrupted by wetland formation from 44.5 to 41.5 ka BP. The latter was terminated by the deposition of 1 m of volcanic tephra, most likely originating from the South Killeak Maar eruption at about 42 ka BP. Yedoma deposition continued until 22.5 ka BP and was followed by a depositional hiatus in the sediment core between 22.5 and 0.23 ka BP. We interpret this hiatus as due to intense thermokarst activity in the areas surrounding the site, which served as a sediment source during the Late-Wisconsin to Holocene climate transition. The lake forming the modern basin on the upland initiated around 0.23 ka BP and drained catastrophically in spring 2005. The present study emphasises that Arctic lake systems and periglacial landscapes are highly dynamic and that permafrost formation as well as degradation in central Beringia was controlled by regional to global climate patterns as well as by local disturbances
Post-Little Ice Age development of a High Arctic paraglacial beach complex.

We reconstruct the behaviour of a High Arctic gravel-dominated beach complex that has developed in central Spitsbergen, Svalbard, since the end of the Little Ice Age (LIA). The studied coastal environment in northern Billefjorden (Petuniabukta) is characterised by limited wave action and ephemeral sediment delivery from non-glaciated, mainly snow-fed fans and talus slopes. Aerial photographic evidence and morpho-sedimentological observations of a beach-ridge plain and spit complex in northern Billefjorden reveal a dynamic coastal system. During the post-LIA period, a prominent coastal barrier at the mouth of the Ebbaelva migrated seawards several tens of metres and prograded northwards to form new spit systems, each > 150 m in length. The post-LIA coastal evolution occurred in two main phases. In the first half of the 20th century, increased paraglacial sediment released by retreating land-based glaciers led to the development of a subaqueous spit platform and the progradation of an ebb-tide delta into the mouth of the Ebbaelva, diverting its mouth to the northwest. In the second half of the 20th century, the barrier prograded onto this platform, promoting the development of three massive spits. Sedimentological data suggest that changes in beach-ridge composition that occurred during the 20th century are linked to episodic sediment delivery from an adjacent permafrost and snow-fed alluvial fan and delta system. Our work provides a basis for a new model of paraglacial barrier development that recognises the fundamental role of climate and sediment supply as two intimately connected processes that control coastal development in the High Arctic over decadal to centennial timescales