pinecone/core-2020-05-10-deduplication huggingface dataset:
Where It All Began: Lending of Last Resort and Bank of England Monitoring During the Overend-Gurney Panic of 1866

International audienceThe National Monetary Commission was deeply concerned with importing best practice. One important focus was the connection between the money market and international trade. It was said that Britain's lead in the market for " acceptances " originating in international trade was the basis of its sterling predominance. In this article, we use a so-far unexplored source to document the portfolio of bills that was brought up to the Bank of England for discount and study the behavior of the Bank of England during the crisis of 1866 (the so-called Overend-Gurney panic) when the Bank began adopting lending of last resort policies (Bignon, Flandreau and Ugolini 2012). We compare 1865 (a " normal " year) to 1866. Important findings include: (a) the statistical predominance of foreign bills in the material brought to the Bank of England; (b) the correlation between the geography of bills and British trade patterns; (c) a marked contrast between normal times lending and crisis lending in that main financial intermediaries and the " shadow banking system " only showed up at the Bank's window during crises; (d) the importance of money market investors (bills brokers) as chief conduit of liquidity provision in crisis; (e) the importance of Bank of England's supervisory policies in ensuring lending-of-last-resort operations without enhancing moral hazard. An implication of our findings is that Bank of England's ability to control moral hazard for financial intermediaries involved in acceptances was another reason for the rise of sterling as an international currency
Evolution of porewater composition through time in limestone aquifers: Salinity and D/H of fluid inclusion water in authigenic minerals (Jurassic of the eastern Paris basin, France)

International audiencePast water circulations can significantly reduce the porosity and permeability of marine limestones. This is particularly the case in the Middle (Bathonian/Bajocian) to Upper (Oxfordian) Jurassic limestones from the eastern border of the Paris Basin. The knowledge of the timing, the temperature and composition of paleowaters is essential to model the hydrological evolution in this area where the Callovian–Oxfordian claystones are studied for the storage of nuclear wastes. In this way, fluid inclusions hosted in low-temperature (< 60°C) authigenic calcite, quartz and celestite crystals were analyzed by Raman spectroscopy and mass spectrometry to determine the chlorinity and D/H ratios. Chlorinity measurements (mmol Cl per liter of water) in fluid inclusions trapped in authigenic crystals during the late Jurassic/early Cretaceous period revealed unexpected high values, up to 3800 mmol l− 1, indicating that brines were involved in some of the diagenetic crystallization processes. By contrast, fluid inclusions in calcite cements of Cenozoic age within the Oxfordian limestones have low Cl concentration (less than 150 mmol l− 1), thus showing that a dilution event caused by water infiltrations during the Cretaceous uplift of this part of the basin has flushed out the original saline porewater. By coupling δD of fluid inclusion with δ18O of calcite crystals, we estimate that calcite precipitation occurred at temperatures between 25 and 53°C. The hydrogen isotope composition of calcite-forming water is different between the Middle Jurassic (δD ranging from − 20 to − 35.8‰V-SMOW) and the overlying Oxfordian limestone (δD from − 59.5 to − 44.8‰V-SMOW). Present-day groundwaters are also of distinct composition on both sides of the Oxfordian claystones, indicating that limestone aquifers underwent independent hydrologic evolutions since the early diagenetic Jurassic cementation
What can be done with an embedded stereo-rig in urban environments?

International audienceThe development of the Autonomous Guided Vehicles (AGVs) with urban applications are now possible due to the recent solutions (DARPA Grand Challenge) developed to solve the Simultaneous Localization And Mapping (SLAM) problem: perception, path planning and control. For the last decade, the introduction of GPS systems and vision have been allowed the transposition of SLAM methods dedicated to indoor environments to outdoor ones. When the GPS data are unavailable, the current position of the mobile robot can be estimated by the fusion of data from odometer and/or Inertial Navigation System (INS). We detail in this article what can be done with an uncalibrated stereo-rig, when it is embedded in a vehicle which is going through urban roads. The methodology is based on features extracted on planes: we mainly assume the road at the foreground as the plane common to all the urban scenes but other planes like vertical frontages of buildings can be used if the features extracted on the road are not enough relevant. The relative motions of the coplanar features tracked with both cameras allow us to stimate the vehicle ego-motion with a high precision. Futhermore, the features which don't check the relative motion of the considered plane can be assumed as obstacles
Silicon nanowires based resistors as gas sensors

International audienceSilicon nanowires (SiNWs) are synthesized following two methods: i) the VLS (Vapor-Liquid-Solid) growth technique (bottom up approach), and ii) the sidewall spacer fabrication (top down approach) commonly used in microelectronic industry. The VLS growth technique uses gold nanoparticles to activate the vapor deposition of the precursor gas and to initiate 100 nm diameter SiNWs network growth. In the case of the sidewall spacer method, a polysilicon layer is deposited by LPCVD (Low Pressure Chemical Vapor Deposition) technique on SiO2 wall patterned by conventional UV lithography technique. Polysilicon film is then plasma etched. Accurate control of the etching rate leads to the formation of spacers with a 100 nm curvature radius that can be used as polysilicon NWs. Each kind of nanowires is integrated into resistors fabrication. Electrical measurements show the potential use of these SiNWs based resistors as gas sensors for ammonia (NH3) and smoke detection
Depositional model and stratigraphic architecture of rift climax Gilbert-type fan deltas (Gulf of Corinth, Greece)

International audienceFacies, depositional model and stratigraphic architecture of Pleistocene giant Gilbert-type fan deltas are presented, based on outcrop data from the Derveni­Akrata region along the southern coast of the Gulf of Corinth, Greece. The common tripartite consisting of topset, foreset and bottomset [Gilbert, G.K., 1885. The topographic features of lake shores: Washington, D.C., United States Geol. Survey, 5th Annual Report, 69­123.] has been identified, as well as the most distal environment consisting of turbidites, and is organised in a repetitive pattern of four main systems tracts showing a clear facies and volumetric partitioning. The first systems tract (ST1) is characterised by the lack of topset beds and the development of a by-pass surface instead, thick foresets and bottomset beds, and thick well-developed turbiditic systems. This systems tract (ST1) is organised in an overall progradational pattern. The second systems tract (ST2) is characterised by a thin topset and almost no foreset equivalent. This systems tract is not always well-preserved and is organised in an overall retrograding trend with a landward shift in the position of the offlap break. The offshore is characterised by massive sandy turbidites. The third systems tract (ST3) is characterised by small-scale deltas prograding above the staked topsets of the giant Gilbert-type fan delta. Those small Gilbert-type fan deltas are generally organised in a pure progradation evolving to an aggradational­progradational pattern. In the distal setting of those small Gilbert-type fan deltas, almost no deposits are preserved on the remaining topography of the previous Gilbert-type fan delta. The fourth systems tract (ST4) is characterised by continuous vertically aggrading topsets that laterally pass into aggrading and prograding foresets. Bottomsets and distal turbiditic systems are starved. This fourth systems tract (ST4) is organised in an overall aggrading trend. These giant Gilbert-type fan deltas correspond to the Middle Group of the Corinth Rift infill and their stratigraphic development was strongly influenced by evolving rift structure. They record the migration of the depocenter from the rift shoulder to the rift axis in four main sequences from ca. 1.5 to 0.7 Ma, related to the migration of fault activity. It is worth noting that the maximum paleobathymetry was recorded during the final stage of the progradation of the Middle Group, suggesting that the rift climax was diachronous at the scale of the entire basin. The rapid (< 1 Ma) structural and sedimentological evolution, the migration of fault activity as well as the youth of the Corinth Rift, are probably exceptional factors allowing the characterisation of such diachronism
Hardness of longest common subsequence for sequences with bounded run-lengths

International audienceThe longest common subsequence (LCS) problem is a classic and well-studied problem in computer science with extensive applications in diverse areas ranging from spelling error corrections to molecular biology. This paper focuses on LCS for fixed alphabet size and fixed run-lengths (i.e., maximum number of consecutive occurrences of the same symbol). We show that LCS is NP-complete even when restricted to (i) alphabets of size 3 and run-length at most 1, and (ii) alphabets of size 2 and run-length at most 2 (both results are tight). For the latter case, we show that the problem is approximable within ratio 3/5
Experimental Analysis of Prepreg Tack

International audienceA probe tack test apparatus is designed to characterize the tack of carbon-epoxy prepreg. Tests are performed on both pure resin and prepreg. The maximum debonding force seems to be a relevant measure of tack. First, results show that the response of pure resin is similar to that of viscous silicon oil. Second, the shape of the response curve obtained for prepreg beyond the maximum value of the debonding force is mainly due to structural effects. Third, the influence of contact force, contact time, debonding rate, probe temperature and ageing conditions on the prepreg tack is investigated in relation with physical phenomena involved in the debonding phase
Paleosol charcoal : Reconstructing vegetation history in relation to agro−pastoral activities since the Neolithic. A case study in the Eastern French Pyrenees.

International audienceThis article uses a method that combines pedoanthracological and pedo-archaeological approaches to terraces, complemented with archaeological pastoral data, in order to reconstruct the history of ancient agricultural terraces on a slope of the Enveitg Mountain in the French Pyrenees. Four excavations revealed two stages of terrace construction that have been linked with vegetation dynamics, which had been established by analyses of charcoal from the paleosols and soils of the terraces. Pedo-archaeological descriptions of these terrace soils reveal their ancient origins and their long-term use. Their chronology was established by radiocarbon dating of single charcoal fragments and charcoal lenses originating in the paleosols. Combining radiocarbon dating with pedo-archaeology resulted in a more reliable chronology. Moreover, the Bronze Age was found to be a crucial period in the history of land-use. This study also highlights the role of fire in the construction of this land-use pattern
Progress toward a first observation of parity violation in chiral molecules by high-resolution laser spectroscopy

30 pages, 11 figures.International audienceParity violation (PV) effects in chiral molecules have so far never been experimentally observed. To take this challenge up, a consortium of physicists, chemists, theoreticians and spectroscopists has been established and aims at measuring PV energy differences between two enantiomers by using high-resolution laser spectroscopy. In this article, we present our common strategy to reach this goal, the progress accomplished in the diverse areas, and point out directions for future PV observations. The work of André Collet on bromochlorofluoromethane enantiomers, their synthesis and their chiral recognition by cryptophanes made feasible the first generation of experiments presented in this paper
Photochemical processes observed during the reaction of superoxide reductase from Desulfoarculus baarsii with superoxide: re-evaluation of the reaction mechanism.

International audienceSuperoxide reductase SOR is an enzyme involved in superoxide detoxification in some microorganisms. Its active site consists of a non-heme ferrous center in an unusual [Fe(NHis)(4) (SCys)(1)] square pyramidal pentacoordination that efficiently reduces superoxide into hydrogen peroxide. In previous works, the reaction mechanism of the SOR from Desulfoarculus baarsii enzyme, studied by pulse radiolysis, was shown to involve the formation of two reaction intermediates T1 and T2. However, the absorption spectrum of T2 was reported with an unusual sharp band at 625 nm, very different from that reported for other SORs. In this work, we show that the sharp band at 625 nm observed by pulse radiolysis reflects the presence of photochemical processes that occurs at the level of the transient species formed during the reaction of SOR with superoxide. These processes do not change the stoichiometry of the global reaction. These data highlight remarkable photochemical properties for these reaction intermediates, not previously suspected for iron-peroxide species formed in the SOR active site. We have reinvestigated the reaction mechanism of the SOR from D. baarsii by pulse radiolysis in the absence of these photochemical processes. The T1 and T2 intermediates now appear to have absorption spectra similar to those reported for the Archaeoglobus fulgidus SOR enzymes. Although for some enzymes of the family only one transient was reported, on the whole, the reaction mechanisms of the different SORs studied so far seem very similar, which is in agreement with the strong sequence and structure homologies of their active sites
Translation by Ribosomes with mRNA Degradation: Exclusion Processes on Aging Tracks

We investigate the role of degradation of mRNA on protein synthesis using the totally asymmetric simple exclusion process (TASEP) as the underlying model for ribosome dynamics. mRNA degradation has a strong effect on the lifetime distribution of the mRNA, which in turn affects polysome statistics such as the number of ribosomes present on an mRNA strand of a given size. An average over mRNA of all ages is equivalent to an average over possible configurations of the corresponding TASEP-both before steady state and in steady state. To evaluate the relevant quantities for the translation problem, we first study the approach towards steady state of the TASEP, starting with an empty lattice representing an unloaded mRNA. When approaching the high density phase, the system shows two distinct phases with the entry and exit boundaries taking control of the density at their respective ends in the second phase. The approach towards the maximal current phase exhibits the surprising property that the ribosome entry flux can exceed the maximum possible steady state value. In all phases, the averaging over the mRNA age distribution shows a decrease in the average ribosome density profile as a function of distance from the entry boundary. For entry/exit parameters corresponding to the high density phase of TASEP, the average ribosome density profile also has a maximum near the exit end
Plant-dominated assemblage and invertebrates from the lower Cenomanian of Jaunay-Clan, western France

International audienceTwo fossil localities are reported on the "LGV SEA" railroad from the Lower Cenomanianof Jaunay-Clan (JC), near Poitiers, western France. The laminated mudstones yielded plantfossils including ferns (Cladophlebis, Osmundophyllum, Ruffordia goeppertii, Sphenopteris),conifers (Brachyphyllum, Dammarophyllum, Pagiophyllum), and terrestrial and aquaticfreshwater angiosperms (Eucalyptolaurus depreii, Ploufolia). They are associated with acoleopteran insect that shows systematic affinities to the modern subfamily Chrysomeli-nae (Chrysomelidae). This assemblage suggests connections with arborescent vegetationgrowing in calm freshwater environment. Brackish to marine invertebrates also occurand include a dakoticancroid crab (Brachyura, Podotremata, Dakoticancroidea) and a fewbivalves (Brachidontes). They suggest brackish episodes during pond sedimentation in acoastal environment. Lastly, vertebrates are represented by an isolated feather
Wavelength selective light-induced magnetic effects in the binuclear spin crossover compound {[Fe(bt)(NCS)2]2(bpym)}

International audienceUsing Fourier transform infrared spectroscopy, x-ray diffraction, and magnetic susceptibility measurements under light irradiation, the selective light-induced excited spin state trapping (LIESST) and the reversible-LIESST effect have been evidenced and studied in depth in the binuclear spin crossover compound {[Fe(bt)(NCS)2]2bpym}. In this system, each magnetic site can switch from low spin (LS) to high spin (HS), so that three states exist, namely, the LS-LS, HS-LS, and HS-HS. All these techniques shine a new light on the high phototunability of this system. In addition to the direct photoswitching from the LS-LS to the HS-LS or to the HS-HS state, here we show that photoinduced switching between the excited photoinduced states can be triggered in a reversible way: from HS-LS to HS-HS (irradiation around 800 nm), or reverse from HS-HS to HS-LS (irradiation around 1300 nm). The nature of the intermediate HS-LS state during the thermal and light-induced spin state changes is also discussed by comparing the spectroscopic measurements and the structural analysis. The loss of inversion symmetry in the HS-LS molecular state, where the two magnetic Fe sites are no more equivalent, is not accompanied by any long-range ordering of the noncentrosymmetric molecules in the crystal. Therefore the continuous double-step spin conversion corresponds to a double crossover
Estimating Biophysical Parameters from BOLD Signals through Evolutionary-Based Optimization

International audiencePhysiological and biophysical models have been proposed to link neural activity to the Blood Oxygen Level-Dependent (BOLD) signal in functional MRI (fMRI). They rely on a set of parameter values that cannot always be extracted from the literature. Their estimation is challenging because there are more than 10 potentially interesting parameters involved in non-linear equations and whose interactions may result in identifiability issues. However, the availability of statistical prior knowledge on these parameters can greatly simplify the estimation task. In this work we focus on the extended Balloon model and propose the estimation of 15 parameters using an Evolutionary Computation (EC) global search method. To combine both the ability to escape local optima and to incorporate prior knowledge, we derive the EC objective function from Bayesian modeling. This novel method provides promising results on a challenging real fMRI data set involving rats with epileptic activity and compares favorably with the conventional Expectation Maximization Gauss-Newton approach
Rendezvous of Distance-aware Mobile Agents in Unknown Graphs

International audienceWe study the problem of rendezvous of two mobile agents starting at distinct locations in an unknown graph. The agents have distinct labels and walk in synchronous steps. However the graph is unlabelled and the agents have no means of marking the nodes of the graph and cannot communicate with or see each other until they meet at a node. When the graph is very large we want the time to rendezvous to be independent of the graph size and to depend only on the initial distance between the agents and some local parameters such as the degree of the vertices, and the size of the agent's label. It is well known that even for simple graphs of degree $\Delta$, the rendezvous time can be exponential in $\Delta$ in the worst case. In this paper, we introduce a new version of the rendezvous problem where the agents are equipped with a device that measures its distance to the other agent after every step. We show that these \emph{distance-aware} agents are able to rendezvous in any unknown graph, in time polynomial in all the local parameters such the degree of the nodes, the initial distance $D$ and the size of the smaller of the two agent labels $l = \min(l_1, l_2)$. Our algorithm has a time complexity of $O(\Delta(D+\log{l}))$ and we show an almost matching lower bound of $\Omega(\Delta(D+\log{l}/\log{\Delta}))$ on the time complexity of any rendezvous algorithm in our scenario. Further, this lower bound extends existing lower bounds for the general rendezvous problem without distance awareness
Ge2Sb2Te5 layer used as solid electrolyte in conductive-bridge memory devices fabricated on flexible substrate

7 pagesInternational audienceThis paper shows that the well-know chalcogenide Ge2Sb2Te5 (GST) in its amorphous state may be advantageously used as solid electrolyte material to fabricate Conductive-Bridge Random Access Memory (CBRAM) devices. GST layer was sputtered on preliminary inkjet-printed silver lines acting as active electrode on either silicon or plastic substrates. Whatever the substrate, the resistance switching is unambiguously attested at a nanoscale by means of conductive-atomic force microscopy (C-AFM) using a Pt-Ir coated tip on the GST surface acting as a passive electrode. The resistance change is correlated to the appearance or disappearance of concomitant hillocks and current spots at the surface of the GST layer. This feature is attributed to the formation/dissolution of a silver-rich protrusion beneath the AFM tip during set/reset operation. Beside, this paper constitutes a step toward the elaboration of crossbar memory arrays on flexible substrates since CBRAM operations were demonstrated on W/GST/Ag crossbar memory cells obtained from an heterogeneous fabrication process combining physical deposition and inkjet-printing
Multiple exposures to indoor contaminants: Derivation of benchmark doses and relative potency factors based on male reprotoxic effects

International audienceSemi-Volatile Organic Compounds (SVOCs) are commonly present in dwellings and several are suspected of having effects on male reproductive function mediated by an endocrine disruption mode of action. To improve knowledge of the health impact of these compounds, cumulative toxicity indicators are needed. This work derives Benchmark Doses (BMD) and Relative Potency Factors (RPF) for SVOCs acting on the male reproductive system through the same mode of action. We included SVOCs fulfilling the following conditions: detection frequency (&gt;10%) in French dwellings, availability of data on the mechanism/mode of action for male reproductive toxicity, and availability of comparable dose-response relationships. Of 58 SVOCs selected, 18 induce a decrease in serum testosterone levels. Six have sufficient and comparable data to derive BMDs based on 10 or 50% of the response. The SVOCs inducing the largest decrease in serum testosterone concentration are: for 10%, bisphenol A (BMD10= 7.72E-07 mg/kg bw/d; RPF10= 7033679); for 50%, benzo[a]pyrene (BMD50= 0.030 mg/kg bw/d; RPF50= 1630), and the one inducing the smallest one is benzyl butyl phthalate (RPF10 and RPF50= 0.095). This approach encompasses contaminants from diverse chemical families acting through similar modes of action, and makes possible a cumulative risk assessment in indoor environments. The main limitation remains the lack of comparable toxicological data