pinecone/core-2020-05-10-deduplication huggingface dataset:
Pair breaking versus symmetry breaking : origin of the Raman modes in superconducting cuprates

We performed Raman scattering experiments on superconductivity-induced features in Bi2Sr2(Ca1−xYx)Cu2O8+δ (Bi-2212), YBa2Cu3O6+x (Y-123), and Tl2Ba2CuO6+δ (Tl-2201) single crystals. The results in combination with earlier ones enable us to systematically analyze the spectral features in the doping range 0.07⩽p⩽0.24. In B2g (xy) symmetry, we find universal spectra and the maximal gap energy Δ0 to scale with the superconducting transition temperature Tc. The B1g (x2−y2) spectra in all three compounds show an anomalous increase of the intensity toward overdoping. The energy scale of the corresponding peak is neither related to the pairing energy nor to the pseudogap, but possibly stems from a symmetry breaking transition at the onset point of superconductivity at psc2≃0.27
Exploring fusion at extreme sub barrier energies with weakly bound nuclei

Accepted for publication in Physical Review LettersResults of measurement of residues formed in fusion of 6Li with 198Pt in the energy range of 0.68< E/$V_b$ <1.3 using a new sensitive off-beam technique are reported. The fusion excitation function and the derived average angular momenta do not indicate a change of slope at deep sub-barrier energies, contrary to recent observations. The present results for a system with weakly bound projectile confront the current understanding of the fusion hindrance at these low energies, underlying the role of internal re-organization on the dynamical path towards fusion
Diagnosis of Wing Icing Through Lift and Drag Coefficient Change Detection for Small Unmanned Aircraft

This paper address the issue of structural change, caused by ice accretion, on
UAVs by utilising a Neyman Pearson (NP) based statistical change detection approach, for
the identi cation of structural changes of  xed wing UAV airfoils. A structural analysis is
performed on the nonlinear aircraft system and residuals are generated, where a generalised
likelihood ratio test is applied to detect faults. Numerical simulations demonstrate a robust
detection with adequate balance between false alarm rate and sensitivity.© 2015 Published by Elsevier Ltd. This is the authors' accepted and refereed manuscript to the article. Locked until 2017-01-01
Polarity reversal in homologous series of surfactant-free Janus nanoparticles : toward the next generation of amphiphiles

The ability to finely tune the amphiphilic balance of Janus nanoparticles (JNPs) could represent a step forward toward creating the next generation of solid-state amphiphiles with significant potential for applications. The inherent amphiphilicity of JNPs stemming from an intrinsic polarity contrast between two surface regions is well-acknowledged, but remained difficult to demonstrate experimentally in the absence of surfactants and stabilizers. We have designed two homologous series of surfactant-free polymeric JNPs starting from polystyrene (PS) seed nanoparticles (NPs) on which we grew Janus lobes of different sizes via seed polymerization and phase separation of the 3-(triethoxysilyl)propyl-methacrylate (3-TSPM) monomer. The two series differ only by the radical initiator used in the seed polymerization: polar ionic ammonium persulfate (APS) vs nonpolar oil-soluble 2,2'-azobis(2-methylpropionitrile) (AIBN). To compare the two series, we employed them in the emulsification of water with heptane or molten paraffin wax. A polarity reversal of the JNPs within AIBN-JNP series could be observed from the catastrophic and transitional emulsion phase inversions and occurred when the more polar lobe was larger than the nonpolar seed PS lobe. Furthermore, the AIBN-JNPs appeared to be amphiphilic and adopt preferred orientation within the monolayer at the oil/water interface. We therefore demonstrated that in the absence of surfactants the amphiphilicity of the JNPs depends not only on the relative size of the lobes, but also on the surface polarity contrast, which can be tuned by changing the nature of radical initiator
The Dawning of the Ethics of Environmental Robots

Environmental scientists and engineers have been exploring research and monitoring applications of robotics, as well as exploring ways of integrating robotics into ecosystems to aid in responses to accelerating environmental, climatic,and biodiversity changes. These emerging applications of robots and other autonomous technologies present novel ethical and practical challenges. Yet, the critical applications of robots for environmental research, engineering, protection and remediation have received next to no attention in the ethics of robotics literature to date. This paper seeks to fill that void, and promote the study of environmental robotics. It provides key resources for further critical examination of the issues environmental robots present by explaining and differentiating the sorts of environmental robotics that exist to date and identifying unique conceptual, ethical, and practical issues they present
A pragmatist view of the metaphysics of entanglement

Quantum entanglement is widely believed to be a feature of physical reality with undoubted (though debated) metaphysical implications. But Schrödinger introduced\ud
entanglement as a theoretical relation between representatives of the quantum states of two systems. Entanglement represents a physical relation only if quantum states are elements of physical reality. So arguments for metaphysical holism or nonseparability from entanglement rest on a questionable view of quantum theory.\ud
Assignment of entangled quantum states predicts experimentally confirmed violation of Bell inequalities. Can one use these experimental results to argue directly\ud
for metaphysical conclusions? No. Quantum theory itself gives us our best explanation of violations of Bell inequalities, with no superluminal causal influences and no metaphysical holism or nonseparability—but only if quantum states are understood as objective and relational, though prescriptive rather than ontic. Correct quantum state assignments are backed by true physical magnitude claims: but backing is not grounding. Quantum theory supports no general metaphysical holism or nonseparability; though a claim about a compound physical system may be significant and true while similar claims about its components are neither. Entanglement may well have have few, if any, first-order metaphysical implications. But the quantum theory of entanglement has much to teach the metaphysician about the roles of chance, causation, modality and explanation in the epistemic and practical concerns of a physically\ud
situated agent
Sustaining international partnerships : the European master of science programme in occupational therapy, a case study

International partnerships are a mechanism for supporting the academic development of occupational therapy and promoting cultural competence. This case study describes the factors that have helped to sustain a post-qualifying programme implemented by five higher education institutions in Denmark, the Netherlands, Sweden, Switzerland and the UK since 1999. Data collection methods were documentary analysis and the reflections of a purposive sample of six key informants. Cohort and outcome data, from 193 students from 31 countries who enrolled between 1999 and 2011, are reported. Each cohort comprises students from an average of eight countries to optimize inter-cultural dialogue. Four factors support sustainability. These are 1) supportive professional European networks; 2) timeliness and alignment with European higher education policy; 3) partnership structures and processes that emphasize joint decision making and accountability; and 4) the stimulus and satisfaction associated with internationalization. The main limitations are considering the OT-EuroMaster as an intrinsic case study and using opportunistic data collection that undermines the rigor and transferability of the findings. Future opportunities include doctoral networks, transnational research and sharing our curricula design with other Regions to spread the collaborative, capacity building endeavours more widely
Fault Tolerant Multiphase Electrical Drives: The Impact of Design

La version editeur de cet article est disponible à l'adresse suivante :
http://journals.cambridge.org/action//displayFulltext?type=1&fid=8024174&jid=JAP&volumeId=43&issueId=02&aid=8024172&bodyId=&membershipNumber=&societyETOCSession=This paper deals with fault tolerant multiphase electrical drives. The quality of the torque of a vector-controlled Permanent Magnet (PM) Synchronous Machine supplied by a multi-leg Voltage Source Inverter (VSI) is examined in normal operation and when one or two phases are open-circuited. It is then deduced that a seven-phase machine is a good compromise allowing high torque-to-volume density and easy control with smooth torque in fault operation. Experimental results confirm the predicted characteristics
A constraint-based approach to quality assurance in service choreographies.

Knowledge about the quality characteristics (QoS) of service com- positions is crucial for determining their usability and economic value. Ser- vice quality is usually regulated using Service Level Agreements (SLA). While end-to-end SLAs are well suited for request-reply interactions, more complex, decentralized, multiparticipant compositions (service choreographies) typ- ically involve multiple message exchanges between stateful parties and the corresponding SLAs thus encompass several cooperating parties with interde- pendent QoS. The usual approaches to determining QoS ranges structurally (which are by construction easily composable) are not applicable in this sce- nario. Additionally, the intervening SLAs may depend on the exchanged data. We present an approach to data-aware QoS assurance in choreographies through the automatic derivation of composable QoS models from partici- pant descriptions. Such models are based on a message typing system with size constraints and are derived using abstract interpretation. The models ob- tained have multiple uses including run-time prediction, adaptive participant selection, or design-time compliance checking. We also present an experimen- tal evaluation and discuss the benefits of the proposed approach
An algorithm for ordinal sorting based on ELECTRE with categories defined by examples

Abstract  This work proposes a Progressive Assisted Sorting Algorithm (PASA) based on a multicriteria evaluation ELECTRE-type method. The purpose of the PASA is to aid a decision maker to progressively sort a set of alternatives into a set of categories, which we considered are ordered (ordinal sorting), following a consistency principle. We consider the principle that if an alternative outranks (is as good as) a second one, then it must belong to the same category or to a better category. The set of alternatives already sorted by the decision maker will implicitly define the categories, and will constrain the range of categories where other alternatives may be sorted. We show how the same idea may be used in an aggregation/disaggregation approach, considering some parameters of ELECTRE are not fixed a priori, but are constrained only by the examples provided. In this context, we establish a “convex-shape property” stating that the range of possible categories for an alternative is always an interval of categories. A discussion contrasting this approach with ELECTRE TRI is included in the conclusions.http://dx.doi.org/10.1007/s10898-007-9240-
From Biomass to Sugar Alcohols: Purification of Wheat Bran Hydrolysates Using Boronic Acid Carriers Followed by Hydrogenation of Sugars over Ru/H-ZSM-5

Wheat bran is a lignocellulosic waste of milling industry. It contains hemicelluloses, which can be valorized into arabitol and xylitol via a few-step approach. It begins with extraction and hydrolysis of hemicelluloses to produce a solution of xylose and arabinose, along with proteins and inorganic salts. This work focuses on the purification of sugars of this hydrolysate and the subsequent catalytic production of sugar alcohols. A purification process based on the recovery of sugars by anionic extraction with a boronic acid, followed by back-extraction and a further refining step with ion exchange resins is described. After this process, a high purity sugars solution (∼90%) free of inorganic elements and proteins was obtained. The feasibility of the process was also highlighted by a successful recycling of the organic phase containing the boronic acid. The hydrogenation of purified sugars was then performed over Ru/H-ZSM-5. A high yield into pentitols of ∼70% with 100% selectivity was achieved. Importantly, the catalytic hydrogenation of sugars in the hydrolysate
prior to purification did not occur. We determined that proteins caused the deactivation of the catalyst, and consequently, the
inhibition of the production of sugar alcohols
Supersonic regime of the Hall-magnetohydrodynamics resistive tearing instability

An earlier analysis of the Hall-magnetohydrodynamics (MHD) tearing instability [E. Ahedo and J. J. Ramos, Plasma Phys. Controlled Fusion 51, 055018 (2009)] is extended to cover the regime where the growth rate becomes comparable or exceeds the sound frequency. Like in the previous subsonic work, a resistive, two-fluid Hall-MHD model with massless electrons and zero-Larmor-radius ions is adopted and a linear stability analysis about a force-free equilibrium in slab geometry is carried out. A salient feature of this supersonic regime is that the mode eigenfunctions become intrinsically complex, but the growth rate remains purely real. Even more interestingly, the dispersion relation remains of the same form as in the subsonic regime for any value of the instability Mach number, provided only that the ion skin depth is sufficiently small for the mode ion inertial layer width to be smaller than the macroscopic lengths, a generous bound that scales like a positive power of the Lundquist numbe
2+1 gravity, chaos and time machines

2+1 gravity for spacetimes with topology RxT^2 has been much studied. We add
a description of how to extend these spacetimes across a Cauchy horizon into a
region where the torus becomes Lorentzian. The result is a one parameter family
of tori given by a geodesic in the "Teichmueller space" of Lorentzian tori. We
describe this in detail. We also point out that if the modular group is
regarded as part of the gauge group then these spacetimes offer a nice toy
model for the dynamics of Bianchi IX models; in the region where the tori are
spacelike the dynamics is described exactly by a hyperbolic billiard. On the
other hand the modular group acts ergodically on the Teichmueller space of
Lorentzian tori
Hamilton Formalism in Non-Commutative Geometry

We study the Hamilton formalism for Connes-Lott models, i.e., for Yang-Mills
theory in non-commutative geometry. The starting point is an associative
$*$-algebra $\cA$ which is of the form $\cA=C(I,\cAs)$ where $\cAs$ is itself a
associative $*$-algebra. With an appropriate choice of a k-cycle over $\cA$ it
is possible to identify the time-like part of the generalized differential
algebra constructed out of $\cA$. We define the non-commutative analogue of
integration on space-like surfaces via the Dixmier trace restricted to the
representation of the space-like part $\cAs$ of the algebra. Due to this
restriction it possible to define the Lagrange function resp. Hamilton function
also for Minkowskian space-time. We identify the phase-space and give a
definition of the Poisson bracket for Yang-Mills theory in non-commutative
geometry. This general formalism is applied to a model on a two-point space and
to a model on Minkowski space-time $\times$ two-point space.Comment: 35
DNA Single-Strand Break Repair and Spinocerebellar Ataxia with Axonal Neuropathy-1

DNA single-strand breaks (SSBs) are the commonest DNA lesions arising spontaneously in cells, and if not repaired may block transcription or may be converted into potentially lethal/clastogenic DNA double-strand breaks (DSBs). Recently, evidence has emerged that defects in the rapid repair of SSBs preferentially impact the nervous system. In particular, spinocerebellar ataxia with axonal neuropathy (SCAN1) is a human disease that is associated with mutation of TDP1 (tyrosyl DNA phosphodiesterase 1) protein and with a defect in repairing certain types of SSBs. Although SCAN1 is a rare neurodegenerative disorder, understanding the molecular basis of this disease will lead to better understanding of neurodegenerative processes. Here we review recent progress in our understanding of TDP1, single-strand break repair (SSBR), and neurodegenerative disease
The presence of 5-hydroxymethylcytosine at the gene promoter and not in the gene body negatively regulates gene expression

5-Hydroxymethylcytosine (5hmC) was recently described as a stable modification in mammalian DNA. 5hmC is formed by the enzymatic oxidation of 5-methylcytosine (5meC). Overwhelming evidence supports the notion that 5meC has a negative effect on transcription; however, only recently has the effect that 5hmC has on transcription begun to be studied. Using model substrates including the CMVIE promoter and a generic gene body we have directly assessed the effect that 5hmC, both at the promoter and in the gene body, has on in vitro gene transcription. We show that the presence of the 5hmC modifications strongly represses transcription. We also demonstrate that the inhibition of transcriptional activity is primarily due to the presence of 5hmC in the promoter and that 5hmC in the gene body has a minimal effect on transcription. Thus, we propose that the presence of 5hmC in promoter prevents the binding of essential transcription factors or recruits factors that repress transcription
Optical in situ calibration of Sb to grow disordered GaInP by MOVPE

Reflectance anisotropy spectroscopy (RAS) was employed to determine the optimal specific molar flow of Sb needed to grow GaInP with a given order parameter by MOVPE. The RAS signature of GaInP surfaces exposed to different Sb/P molar flow ratios were recorded, and the RAS peak at 3.02 eV provided a feature that was sensitive to the amount of Sb on the surface. The range of Sb/P ratios over which Sb acts as a surfactant was determined using the RA intensity of this peak, and different GaInP layers were grown using different Sb/P ratios. The order parameter of the resulting layers was measured by PL at 20 K. This procedure may be extensible to the calibration of surfactant-mediated growth of other materials exhibiting characteristic RAS signatures
Impact of hypertension on the outcome of patients admitted with acute coronary syndrome

OBJECTIVE  The role of hypertension and its impact on outcome in patients with acute coronary syndrome (ACS) is still debated. This study aimed to compare the outcomes of hypertensive and nonhypertensive ACS patients.  METHODS  Using data of ACS patients enrolled in the Acute Myocardial Infarction in Switzerland Plus Registry from 1997 to 2013, characteristics at presentation and outcomes in hospital and after 1 year were analyzed. Hypertension was defined as previously diagnosed and treated by a physician. The primary endpoint was mortality. Data were analyzed using multiple logistic regressions.  RESULTS  Among 41 771 ACS patients, 16 855 (40.4%) were without and 24 916 (59.6%) with preexisting hypertension. Patients with preexisting hypertension had a more favorable in-hospital outcome [odds ratio (OR) in-hospital mortality 0.82, 95% confidence interval (CI) 0.73-0.93; P = 0.022]. The independent predictors of in-hospital mortality for patients with preexisting hypertension were age, Killip class greater than 2, Charlson Comorbidity Index greater than 1, no pretreatment with statins and lower admission systemic blood pressure. Preexisting hypertension was not an independent predictor of 1-year mortality in the subgroup of patients (n = 7801) followed: OR 1.07, 95% CI 0.78-1.47; P = 0.68. Independent predictors of mortality 1 year after discharge for the 4796 patients with preexisting hypertension were age, male sex and comorbidities. Angiotensin-converting enzyme inhibitors or angiotensin II receptor antagonists and statins prescribed at discharge improved the outcomes.  CONCLUSION  Outcome of ACS patients with preexisting hypertension was associated with an improved in-hospital prognosis after adjustment for their higher baseline risk. However, this effect was not long-lasting and does not necessarily mean a causal relationship exists. Short-term and long-term management of patients with hypertension admitted with ACS could be further improved
Chemical versus van der Waals Interaction: The Role of the Heteroatom in the Flat Absorption of Aromatic Molecules C6H6, C5NH5, and C4N2H4 on the Cu(110) Surface

We perform first-principles calculations aimed at investigating the role of a heteroatom such as N in the chemical and long-range van der Waals (vdW) interactions for a flat adsorption of several pi-conjugated molecules on the Cu(110) surface. Our study reveals that the alignment of the molecular orbitals at the adsorbate-substrate interface depends on the number of heteroatoms. As a direct consequence, the molecule-surface vdW interactions involve not only pi-like orbitals which are perpendicular to the molecular plane but also sigma-like orbitals delocalized in the molecular plane
Electromagnetic instability in holographic QCD

Using the AdS/CFT correspondence, we calculate the vacuum decay rate for the Schwinger effect in confining large N c gauge theories. The instability is induced by thecorrespondence, we calculate the vacuum quark antiquark pair creation triggered by strong electromagnetic fields. The decay rate is obtained as the imaginary part of the Euler-Heisenberg effective Lagrangian evaluated from the D-brane action with a constant electromagnetic field in holographic QCD models such as the Sakai-Sugimoto model and the deformed Sakai-Sugimoto model. The decay rate is found to increase with the magnetic field parallel to the electric field, while it decreases with the magnetic field perpendicular to the electric field. We discuss generic features of a critical electric field as a function of the magnetic field and the QCD string tension in the Sakai-Sugimoto model
Molecular imprinted polymer functionalized carbon nanotube sensors for detection of saccharides

In this work, we report the synthesis and fabrication of an enzyme-free sugar sensor based on molecularly imprinted polymer (MIP) on the surface of single walled carbon nanotubes (SWNTs). Electropolymerization of 3-aminophenylboronic acid (3-APBA) in the presence of 10 M d-fructose and fluoride at neutral pH conditions resulted in the formation of a self-doped, molecularly imprinted conducting polymer (MICP) via the formation of a stable anionic boronic ester complex between poly(aniline boronic acid) and d-fructose. Template removal generated binding sites on the polymer matrix that were complementary to d-fructose both in structure, i.e., shape, size, and positioning of functional groups, thus enabling sensing of d-fructose with enhanced affinity and specificity over non-MIP based sensors. Using carbon nanotubes along with MICPs helped to develop an efficient electrochemical sensor by enhancing analyte recognition and signal generation. These sensors could be regenerated and used multiple times unlike conventional affinity based biosensors which suffer from physical and chemical stability