# 3-ethyl-1,6,7,11b-tetrahydro-9,10-dimethoxy-4H-benzo[a]quinolizine-2-acetic acid SDS

# SAFETY DATA SHEETS

## According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

### 1.Identification

###  1.1  GHS Product identifier

Product name | 2-(3-ethyl-9,10-dimethoxy-4,6,7,11b-tetrahydro-1H-benzo[a]quinolizin-2-yl)acetic acid  
---|---  
  
###  1.2  Other means of identification

Product number | -  
---|---  
Other names | EINECS 282-541-4  
  
###  1.3  Recommended use of the chemical and restrictions on use

Identified uses |  For industry use only.   
---|---  
Uses advised against | no data available  
  
###  1.4  Supplier's details

###  1.5  Emergency phone number

Emergency phone number | -  
---|---  
Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).  
  
### 2.Hazard identification

###  2.1  Classification of the substance or mixture

no data available

###  2.2  GHS label elements, including precautionary statements

Pictogram(s) |  no data available   
---|---  
Signal word |  no data available  
Hazard statement(s) |  no data available  
Precautionary statement(s)  
Prevention |  no data available  
Response |  no data available  
Storage |  no data available  
Disposal |  no data available  
  
###  2.3  Other hazards which do not result in classification

no data available

### 3.Composition/information on ingredients

###  3.1  Substances

Chemical name | Common names and synonyms | CAS number | EC number | Concentration  
---|---|---|---|---  
2-(3-ethyl-9,10-dimethoxy-4,6,7,11b-tetrahydro-1H-benzo[a]quinolizin-2-yl)acetic acid  | 2-(3-ethyl-9,10-dimethoxy-4,6,7,11b-tetrahydro-1H-benzo[a]quinolizin-2-yl)acetic acid |  84254-95-5 |  none  | 100%  
  
### 4.First-aid measures

###  4.1  Description of necessary first-aid measures

#### General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

#### If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. 

#### In case of skin contact

Wash off with soap and plenty of water. Consult a physician. 

#### In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. 

#### If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 

###  4.2  Most important symptoms/effects, acute and delayed

no data available

###  4.3  Indication of immediate medical attention and special treatment needed, if necessary

no data available

### 5.Fire-fighting measures

###  5.1  Extinguishing media

#### Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 

###  5.2  Specific hazards arising from the chemical

no data available

###  5.3  Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

### 6.Accidental release measures

###  6.1  Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

###  6.2  Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 

###  6.3  Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal. 

### 7.Handling and storage

###  7.1  Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

###  7.2  Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 

### 8.Exposure controls/personal protection

### 8.1 Control parameters

#### Occupational Exposure limit values

no data available

#### Biological limit values

no data available

###  8.2  Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

###  8.3  Individual protection measures, such as personal protective equipment (PPE)

#### Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). 

#### Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. 

#### Respiratory protection

Wear dust mask when handling large quantities. 

#### Thermal hazards

no data available 

### 9.Physical and chemical properties

Physical state | no data available  
---|---  
Colour | no data available  
Odour | no data available  
Melting point/ freezing point | no data available  
Boiling point or initial boiling point and boiling range | 484.6oC at 760 mmHg  
Flammability |  no data available   
Lower and upper explosion limit / flammability limit | no data available  
Flash point | 246.9oC  
Auto-ignition temperature | no data available  
Decomposition temperature | no data available  
pH | no data available  
Kinematic viscosity | no data available  
Solubility | no data available  
Partition coefficient n-octanol/water (log value) | no data available  
Vapour pressure | no data available  
Density and/or relative density | 1.22g/cm3  
Relative vapour density | no data available  
Particle characteristics | no data available  
  
### 10.Stability and reactivity

###  10.1  Reactivity

no data available

###  10.2  Chemical stability

Stable under recommended storage conditions. 

###  10.3  Possibility of hazardous reactions

no data available 

###  10.4  Conditions to avoid

no data available

###  10.5  Incompatible materials

no data available 

###  10.6  Hazardous decomposition products

no data available 

### 11.Toxicological information

#### Acute toxicity

  * Oral: no data available
  * Inhalation: no data available
  * Dermal: no data available



#### Skin corrosion/irritation

no data available

#### Serious eye damage/irritation

no data available

#### Respiratory or skin sensitization

no data available

#### Germ cell mutagenicity

no data available

#### Carcinogenicity

no data available 

#### Reproductive toxicity

no data available 

#### STOT-single exposure

no data available

#### STOT-repeated exposure

no data available

#### Aspiration hazard

no data available

### 12.Ecological information

###  12.1  Toxicity

  * Toxicity to fish: no data available
  * Toxicity to daphnia and other aquatic invertebrates: no data available
  * Toxicity to algae: no data available
  * Toxicity to microorganisms: no data available



###  12.2  Persistence and degradability

no data available

###  12.3  Bioaccumulative potential

no data available

###  12.4  Mobility in soil

no data available

###  12.5  Other adverse effects

no data available

### 13.Disposal considerations

###  13.1  Disposal methods

#### Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. 

#### Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

### 14.Transport information

###  14.1  UN Number

ADR/RID: no data available | IMDG: no data available | IATA: no data available  
---|---|---  
  
###  14.2  UN Proper Shipping Name

ADR/RID: no data available  
---  
IMDG: no data available  
IATA: no data available  
  
###  14.3  Transport hazard class(es)

ADR/RID: no data available | IMDG: no data available | IATA: no data available  
---|---|---  
  
###  14.4  Packing group, if applicable

ADR/RID: no data available | IMDG: no data available | IATA: no data available  
---|---|---  
  
###  14.5  Environmental hazards

ADR/RID: no | IMDG: no | IATA: no  
---|---|---  
  
###  14.6  Special precautions for user

no data available

###  14.7  Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

### 15.Regulatory information

###  15.1  Safety, health and environmental regulations specific for the product in question

Chemical name | Common names and synonyms | CAS number | EC number  
---|---|---|---  
2-(3-ethyl-9,10-dimethoxy-4,6,7,11b-tetrahydro-1H-benzo[a]quinolizin-2-yl)acetic acid | 2-(3-ethyl-9,10-dimethoxy-4,6,7,11b-tetrahydro-1H-benzo[a]quinolizin-2-yl)acetic acid | 84254-95-5 | none  
European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed.  
EC Inventory | Listed.  
United States Toxic Substances Control Act (TSCA) Inventory | Not Listed.  
China Catalog of Hazardous chemicals 2015 | Not Listed.  
New Zealand Inventory of Chemicals (NZIoC) | Not Listed.  
Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Not Listed.  
Vietnam National Chemical Inventory | Not Listed.  
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Not Listed.  
  
### 16.Other information

#### Information on revision

Creation Date | Aug 18, 2017  
---|---  
Revision Date | Aug 18, 2017  
  
#### Abbreviations and acronyms

  * CAS: Chemical Abstracts Service 
  * ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  * RID: Regulation concerning the International Carriage of Dangerous Goods by Rail 
  * IMDG: International Maritime Dangerous Goods
  * IATA: International Air Transportation Association
  * TWA: Time Weighted Average
  * STEL: Short term exposure limit
  * LC50: Lethal Concentration 50%
  * LD50: Lethal Dose 50%
  * EC50: Effective Concentration 50%



#### References

  * IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  * HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  * IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  * eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  * CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  * ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  * ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  * Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  * ECHA - European Chemicals Agency, website: https://echa.europa.eu/