Emulsification and polymerization of alkyd resins
By: Jan W. Gooch.
Series: Topics in applied chemistry
Publisher: Kluwer Academic/Plenum Publishers; Springer
Published: 2002
Place of publication: New York
Language: eng
Number of pages: 223
Subjects: Alkyd resins.; Emulsification.
Notes: Includes bibliographical references (p. 215-218) and index.
Table of contents: title: Machine generated contents note: I; title: I; title: 1. ALKYD RESINS, VEGETABLE OILS AND AUTOXIDATIVE; title: POLYMERIZATION; title: 1.1. Goals of Research and Development in Alkyd Emulsions; title: 1.2. Historical Background of Alkyds, Oils and Emulsions; title: 1.2.1. Vegetable Oils and Resins; title: 1.2.2. Autoxidative Polymerization of Vegetable Oils and; title: Resins; title: 1.2.3. Emulsified Oils and Resins; title: 1.3. Theoretical Considerations; title: 1.3.1. Intrinsic Viscosity; title: 1.3.2. Hydrophile-Lipophile Balance (HLB); title: 1.3.3. Diffusion of Oxygen in an Emulsion; title: 1.3.4. Solubility of Air and Oxygen in Aqueous Phase; title: 1.3.5. Swelling Ratio; title: 1.4. Justification for Research and Development; title: 2. SYNTHESIS AND POLYMERIZATION OF ALKYDS; title: 2.1. Alkyd Synthesis Procedure; title: 2.2. Emulsification Procedure; title: 2.3. Autoxidation Procedure; title: 2.4. Materials; title: 2.5. Characterization; title: 2.5.1. Emulsion Particle Size; title: 2.5.2. Emulsion Characterization; title: 2.5.3. Film Characterization; title: 2.5.4. Intrinsic Viscosity Measurement; title: 2.5.5. Swell Ratio; title: 2.5.6. Turbidimetric Measurement of Swelling Ratio; title: 2.5.7. Dissolved Oxygen in Aqueous Phase; title: 3. EMULSION AND KINETIC STUDIES OF AUTOXIDATIVE; title: POLYMERIZATION; title: 3.1. Emulsifier Studies; title: 3.1.1. Emulsifier Sources and Chemical Structures; title: 3.1.2. Emulsifiers and Emulsion Stability; title: 3.1.3. Emulsifiers and Freeze-Thaw Stability; title: 3.1.4. Emulsifiers and Film Characterization; title: xiii; title: 3.2. Phase Ratio and Co-Solvent Study; title: 3.2.1. Solvent Alkyd Emulsions; title: 3.2.2. Co-Solvent Containing Emulsions; title: 3.3. Studies on the Autoxidative Crosslinking of Emulsified; title: Soya Oil; title: 3.3.1. Autoxidation Reaction of Emulsified Soya Oil; title: 3.3.2. Catalysis of Autoxidation Reaction of Soya Oil; title: 3.4. Studies of the Autoxidative Crosslinking of Emulsified; title: Alkyd Particles; title: 3.4.1. Autoxidation Reaction of Emulsified Alkyd Resins; title: 3.4.2. Non-catalyzed Autoxidation Reaction; title: 3.4.3. Benzoyl Peroxide Catalysis in the Alkyd Phase; title: 3.4.4. Cobalt Naphthenate Catalysis in Aqueous Phase; title: 3.4.5. Autoxidized Emulsion Characterization; title: 3.4.6. Post pH-Adjustment of Autoxidized Emulsion; title: 3.4.7. pH Adjustment Prior to the Autoxidation; title: 3.4.8. Cobalt Naphthenate Catalysis in Alkyd Phase; title: 3.4.9. Post-Addition of Emulsifier; title: 3.4.10. pH Effect on Reaction Rate; title: 3.4.11. Increased Oxygen Concentration and Catalysis; title: 3.4.12. Scanning Electron Microscopy; title: 3.4.13. Water Clean-Up of Emulsion; title: 3.4.14. Comparison to Alkyd-Solvent System; title: 3.4.15. Effect of Emulsifier Structure on Reaction Rate; title: 3.5. Kinetic Study; title: 3.5.1. Oxygen Concentration Relationship; title: 3.5.2. Correlation of Swell Ratio and Percent Transmittance; title: 3.5.3. Catalysis Effect; title: 3.5.4. Temperature Effect; title: 3.5.5. Agitation Rate Effect; title: 3.5.6. Molecular Weight Effect; title: 3.6. Studies on Emulsion Particle Size; title: 3.6.1. Particle Size with Reaction Time; title: 3.6.2. Average Particle Size with Homogenization; title: 3.6.3. Particle Size after One Year of Shelf Life; title: 3.7. Alkyd Oil Length and Conjugation Study; title: 3.7.1. Alkyd Oil Length Study; title: 3.7.2. Alkyd Conjugation Study; title: 4. EXPERIMENTAL RESULTS, RESEARCH; title: AND COMMERCIALIZATION OF TECHNOLOGY; title: 4.1. Autoxidative Crosslinking of Vegetable Oil; title: 4.2. Autoxidative Crosslinking of Vegetable Oil Alkyds; title: 4.3. Emulsification; title: 4.4. Continuing Research and Developments; title: 4.5. Commercialization of Alkyd Emulsions; title: APPENDIX - FIGURES; title: APPENDIX - TABLES; title: REFERENCES; title: INDEX.