Algebraic approach to simple quantum systems
Subtitle: with applications to perturbation theory
By: Barry G. Adams.
Publisher: Springer-Verlag
Published: 1994
Place of publication: Berlin; New York
Language: eng
Number of pages: 451
Subjects: Perturbation (Quantum dynamics); Lie algebras.; Chemistry, Physical and theoretical.; Mathematical physics.
Description: This monograph is primarily aimed at advanced undergraduates and first-year graduate students and researchers in theoretical and computational chemistry. It will also be useful to researchers in mathematical physics. It is the first book to systematically explore the application of Lie algebraic methods to simple quantum systems and perturbation theory with an emphasis on symbolic computation. Many exercises complete with solutions are also included.

In the first part of the book the basic concepts of Lie algebras are presented in a pedagogical manner, first in the familiar context of angular momentum theory, and then for the important Lie algebras so (2,1), so (4) and so(4,2).

Next, a novel feature is the application of the algebraic methods to obtain the energy and wavefunctions of the standard textbook problems of the non-relativistic and relativistic hydrogenic atoms and the harmonic oscillator. This provides an elegant and algebraic alternative to the usual approach using series solutions of differential equations.

In the second part of the book applications of these algebraic methods to large order algebraic perturbation theory are considered for the Stark and Zeeman effect and spherically symmetric systems with charmonium, harmonium and screened Coulomb perturbations using the Maple computer algebra system. Application of the Hellman-Feynman and Hypervirial theorems to the perturbation theory of spherically symmetric systems is also considered using Maple.

A disk containing Maple programs and data files is also included.
Notes: Includes bibliographical references (p. [435]-442) and indexes.
System requirements for computer disk: IBM-compatible PC; DOS.