Chemical Thermodynamics
Publisher: Bookboon
Published: 2013
ISBN-13: 9788776814977
Table of contents: title: Introduction; title: Basic concepts; title: Brief review of thermodynamics; title: The fundamental equation of thermodynamics; title: The calculus of thermodynamics; title: Open systems; title: Legendre transforms and free energies; title: Single component systems; title: General phase behavior; title: Conditions for phase equilibrium; title: The Clapeyron equation; title: Multicomponent systems; title: Thermodynamics of multicomponent systems; title: Binary mixtures; title: Ternary mixtures; title: The ideal solution model; title: Definition of the ideal solution model; title: Derivation of Raoult’s law; title: Partial molar properties; title: Definition; title: Relationship between total properties and partial molar properties; title: Properties changes on mixing; title: Graphical representation for binary systems; title: Nonideal solutions; title: Deviations from Raoult’s law and the activity coefficient; title: Modified Raoult’s law; title: Empirical activity coefficient models; title: The Gibbs-Duhem equation; title: Azeotropic systems; title: Stability; title: Introduction; title: Liquid-liquid equilibrium; title: Solid-liquid equilibrium; title: Introduction; title: Phase behavior; title: Conditions for equilibrium; title: Gas solubility and Henry’s law; title: Henry’s law; title: Activity coefficients; title: Equations of state; title: The principle of corresponding states; title: The van der Waals equation and cubic equations of state; title: Equations of state for mixtures; title: Thermodynamics from equations of state; title: The residual Helmholtz free energy; title: Fugacity; title: Vapor-liquid equilibrium with a non-ideal vapor phase; title: Chemical reaction equilibria; title: Conditions for equilibrium; title: The phase rule for chemically reacting systems; title: Gas phase reactions; title: The standard Gibbs free energy of formation; title: The influence of temperature; title: Liquid phase reactions