Microscale analysis of cemented paste backfill.
Published: 2005
Language: eng
Number of pages: 257
Description: This study shows that wave-based techniques provide insight into some of the factors that affect the behaviour of CPB. Electromagnetic wave-based measurements are sensitive to changes in structure, free water content, bound water content, and ion availability and/or mobility. This research shows that the effective conductivity is a useful parameter to monitor the hydration process, even in low cement content pastes. Shear wave-based measurements are a useful tool to monitor the stiffness evolution in CPB. Apparent yield stress measurements are sensitive to particle-particle interactions and reflect changes in the material's composition, including water content, binder content and type, and chemical additives. All tests show that during the early stages, Portland cement hydration has little effect on the microstructure development, stiffness and flow characteristics of cement-containing pastes.The macroscopic properties of cemented paste backfill (CPB), including fluidity and strength, depend on particle-particle and particle-fluid interactions; thus, it is important to determine the fundamental interactions between the paste constituents to optimize paste design. Specific topics of interest in this study include the effects of paste composition (e.g., binder content and type, and pore fluid chemistry) on the microstructure development, and electromagnetic, rheological and mechanical properties (e.g., setting time, unconfined compressive strength and stiffness) with time.The effect of the pore fluid chemistry on the properties of the CPB depends on the type and amount of the additive. In CPB, calcium chloride and sodium chloride accelerate cement hydration and improve the UCS during the first six months of hydration. Conversely, ferric chloride and hydrochloric acid retard the hydration and setting of CPB. The tested superplasticizers retard cement hydration, increase the UCS and lower the apparent yield stress of CPB. A drawback to using the superplasticizers tested in this study is that a high shear stress is required to re-initiate flow in the pastes.
Notes: Thesis (Ph.D.)--University of Toronto, 2005.

Electronic version licensed for access by U. of T. users.

Source: Dissertation Abstracts International, Volume: 66-06, Section: B, page: 3294.