Chemical and physical aspects of soot/nano-particle formation in combustion.
Published: 2005
Language: eng
Number of pages: 271
Description: The chemical and physical processes underlying the formation of soot during combustion have been numerically studied using fundamental combustion chemistry and aerosol dynamics theory. A detailed gaseous phase reaction mechanism, which describes the formation and growth of soot precursors including PAH and polyynes, and soot chemistry, which includes the particle nucleation, heterogeneous surface growth, and PAH surface condensation, were coupled to an advanced sectional aerosol dynamics model which is able to calculate the coagulation process of soot agglomerates with fractal structures in three Knudson number regimes. Three studies have been carried out to predict major soot forming characteristics such as particle yield, total number density, averaged particle diameter, and particle size distribution. The first study focused on the investigation of surface growth and condensation processes related to the formation of soot in a Jet Stirred Reactor and Plug Flow Reactor system. The second study looked at the nucleation and surface growth processes during the early stages of soot formation. The third and final study involved modeling the formation of carbonaceous nano-particles during the thermal decomposition of hydrogen free carbon bearing molecules, such as C3O2 and CCl4, behind shock waves. The chemical kinetics concerning pure carbon clusters and particulate coagulation were studied for soot particle formation in the absence of the HACA surface growth mechanism. The numerical simulations showed that the sectional aerosol dynamics models developed in this study were able to be coupled with complex physical processes, such as thermal re-structuring, carbonization, and agglomerate coagulation. Studying the soot formation in a JSR/PFR system revealed that both the HACA surface growth mechanism and the PAH condensation process play significant roles in the growth of soot mass at larger residence times. The investigation of soot formation during the pyrolysis of C6H6 behind a shock wave demonstrated that both the PAH growth pathway and the fast polyyne polymerization process contribute to the early formation of soot particles. Finally, the simulation results of the pyrolysis of C3O2 behind a shock wave were in good agreement with measured characteristics of nano-particle yield.
Notes: Source: Dissertation Abstracts International, Volume: 66-10, Section: B, page: 5653.

Thesis (Ph.D.)--University of Toronto, 2005.

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