Chemical Thermodynamics
Publisher: Bookboon.com
Published: 2013
ISBN-13: 9788776814977
Table of contents: title: Content; title: 1. Introduction; title: 1.1. Basic concepts; title: 1.2. Brief review of thermodynamics; title: 1.3. The fundamental equation of thermodynamics; title: 1.4. The calculus of thermodynamics; title: 1.5. Open systems; title: 1.6. Legendre transforms and free energies; title: 2. Single component systems; title: 2.1. General phase behavior; title: 2.2. Conditions for phase equilibrium; title: 2.3. The Clapeyron equation; title: 3. Multicomponent systems; title: 3.1. Thermodynamics of multicomponent systems; title: 3.2. Binary mixtures; title: 3.3. Ternary mixtures; title: 4. The ideal solution model; title: 4.1. Definition of the ideal solution model; title: 4.2. Derivation of Raoult’s law; title: 5. Partial molar properties; title: 5.1. Definition; title: 5.2. Relationship between total properties and partial molar properties; title: 5.3. Properties changes on mixing; title: 5.4. Graphical representation for binary systems; title: 6. Nonideal solutions; title: 6.1. Deviations from Raoult’s law and the activity coefficient; title: 6.2. Modified Raoult’s law; title: 6.3. Empirical activity coefficient models; title: 6.4. The Gibbs-Duhem equation; title: 6.5. Azeotropic systems; title: 7. Stability; title: 7.1. Introduction; title: 7.2. Liquid-liquid equilibrium; title: 8. Solid-liquid equilibrium; title: 8.1. Introduction; title: 8.2. Phase behavior; title: 8.3 Conditions for equilibrium; title: 9. Gas solubility and Henry’s law; title: 9.1. Henry’s law; title: 9.2. Activity coefficients; title: 10. Equations of state; title: 10.1 The principle of corresponding states; title: 10.2. The van der Waals equation and cubic equations of state; title: 10.3. Equations of state for mixtures; title: 11. Thermodynamics from equations of state; title: 11.1 The residual Helmholtz free energy; title: 11.2. Fugacity; title: 11.3. Vapor-liquid equilibrium with a non-ideal vapor phase; title: 12. Chemical reaction equilibria; title: 12.1 Conditions for equilibrium; title: 12.2. The phase rule for chemically reacting systems; title: 12.3. Gas phase reactions; title: 12.4. The standard Gibbs free energy of formation; title: 12.5. The influence of temperature; title: 12.6. Liquid phase reactions