Faraday cup. A Faraday cup is a metal (conductive) cup designed to catch charged particles. The resulting current can be measured and used to determine the number of ions or electrons hitting the cup. The Faraday cup was named after Michael Faraday who first theorized ions around 1830.

Examples of devices which use Faraday cups include space probes (Voyager 1, & 2, Parker Solar Probe, etc.) and mass spectrometers. Faraday cups can also be used to measure charged aerosol particles.

Principle of operation

When a beam or packet of ions or electrons (e.g. from an electron beam) hits the metallic body of the cup, the apparatus gains a small net charge. The cup can then be discharged to measure a small current proportional to the charge carried by the impinging ions or electrons. By measuring the electric current (the number of electrons flowing through the circuit per second) in the cup, the number of charges can be determined. For a continuous beam of ions (assumed to be singly charged) or electrons, the total number N hitting the cup per unit time (in seconds) is

where I is the measured current (in amperes) and e is the elementary charge (1.60 × 10−19 C). Thus, a measured current of one nanoamp (10−9 A) corresponds to about 6 billion singly charged particles striking the Faraday cup each second.

Faraday cups are not as sensitive as electron multiplier detectors, but are highly regarded for accuracy because of the direct relation between the measured current and number of ions.

In plasma diagnostics

The Faraday cup uses a physical principle according to which the electrical charges delivered to the inner surface of a hollow conductor are redistributed around its outer surface due to mutual self-repelling of charges of the same sign – a phenomenon discovered by Faraday.

The conventional Faraday cup is applied for measurements of ion (or electron) flows from plasma boundaries and comprises a metallic cylindrical receiver-cup – 1 (Fig. 1) closed with, and insulated from, a washer-type metallic electron-suppressor lid – 2 provided with the round axial through enter-hollow of an aperture with a surface area .  Both the receiver cup and the electron-suppressor lid are enveloped in, and insulated from, a grounded cylindrical shield – 3 having an axial round hole coinciding with the hole in the electron-suppressor lid – 2. The electron-suppressor lid is connected by 50 Ω RF cable with the source   of variable DC voltage . The receiver-cup is connected by 50 Ω RF cable through the load resistor  with a sweep generator producing saw-type pulses . Electric capacity     is formed of the capacity of the receiver-cup – 1 to the grounded shield – 3 and the capacity of the RF cable. The signal from  enables an observer to acquire an I-V characteristic of the Faraday cup by oscilloscope. Proper operating conditions:   (due to possible potential sag) and , where  is the ion free path. Signal from  is the Faraday cup I-V characteristic  which can be observed and memorized by oscilloscope

In Fig. 1: 1 – cup-receiver, metal (stainless steel). 2 – electron-suppressor lid, metal (stainless steel). 3 – grounded shield, metal (stainless steel). 4 – insulator (teflon, ceramic).  – capacity of Faraday cup.  – load resistor.

Thus we measure the sum   of the electric currents through the load resistor :   (Faraday cup current) plus the current   induced through the capacitor  by the saw-type voltage of the sweep-generator: The current component  can be measured at the absence of the ion flow and can be subtracted further from the total current  measured with plasma to obtain the actual Faraday cup I-V characteristic  for processing.  All of the Faraday cup elements and their assembly that interact with plasma are fabricated usually of temperature-resistant materials (often these are stainless steel and teflon or ceramic for insulators).  For processing of the Faraday cup I-V characteristic, we are going to assume that the Faraday cup is installed far enough away from an investigated plasma source where the flow of ions could be considered as the flow of particles with parallel velocities directed exactly along the Faraday cup axis. In this case, the elementary particle current  corresponding to the ion density differential  in the range of velocities between  and  of ions flowing in through operating aperture  of the electron-suppressor can be written in the form

where

 is elementary charge,  is the ion charge state, and  is the one-dimensional ion velocity distribution function. Therefore, the ion current at the ion-decelerating voltage  of the Faraday cup can be calculated by integrating Eq. () after substituting Eq. (),

where the lower integration limit is defined from the equation  where   is the velocity of the ion stopped by the decelerating potential  , and   is the ion mass. Thus Eq. () represents the I-V characteristic of the Faraday cup.  Differentiating Eq. () with respect to , one can obtain the relation

where the value    is an invariable constant for each measurement. Therefore, the average velocity   of ions arriving into the Faraday cup and their average energy   can be calculated (under the assumption that we operate with a single type of ion) by the expressions

where    is the ion mass in atomic units. The ion concentration   in the ion flow at the Faraday cup vicinity can be calculated by the formula

which follows from Eq. ()  at ,

and from the conventional condition for distribution function normalizing
 

Fig. 2 illustrates the I-V characteristic   and its first derivative   of the Faraday cup with   installed at output of the Inductively coupled plasma source powered with RF 13.56 MHz and operating at 6 mTorr of H2. The value of the electron-suppressor voltage (accelerating the ions) was set experimentally at , near the point of suppression of the secondary electron emission from the inner surface of the Faraday cup.

Error sources
The counting of charges collected per unit time is impacted by two error sources: 1) the emission of low-energy secondary electrons from the surface struck by the incident charge and 2) backscattering (~180 degree scattering) of the incident particle, which causes it to leave the collecting surface, at least temporarily. Especially with electrons, it is fundamentally impossible to distinguish between a fresh new incident electron and one that has been backscattered or even a fast secondary electron.

See also
 Nanocoulombmeter
 Electron multiplier
 Microchannel plate detector
 Daly detector
 Faraday cup electrometer
 Faraday cage
 Faraday constant
 SWEAP

References

External links
 Detecting Ions in Mass Spectrometers with the Faraday Cup By Kenneth L. Busch

Mass spectrometry
Measuring instruments
Plasma diagnostics