Creepdeformation insingle-phase ɤ-TiAlalloysmanufactured using differentprocessing techniques hasbeenanextensively studied topicowingtothehighspecificstrength andexcellent creepproperties ofthesealloysattemperatures between760and 1000°C.Inaddition,theselightweight andcreep-resistant alloysare beingpresently considered asreplacements tothecomparatively heavierNi-basedsuperalloys forapplication inthelow-pressure turbinebladesofthenext-generation gasturbineengines. However,thereislimitedinformation onthetensilecreepdeforma- tionbehaviour andcreeplifeofɤ-TiAlalloysat832°Cwherethese alloyshavebeenreportednottoexhibitsteady-state creep.To thisend,thepresentworkrevisitstheworkonunderstanding the tensilecreepdeformation behaviour ofwroughtsingle-phase ɤ-TiAl alloybySaha[1]andisaimedtodevelopanunderstanding of thetensilecreepdeformation behaviour at832°Candtheinfluence ofcreepactivation energyonthecreeplifeofwroughtsingle-phase ɤ-TiAlalloyforstresslevelsof69.4and103.4MPaat832°Cusing Monkman–Grant [2]approach.ARTICLE HISTORY Accepted 25June2021 KEYWORDS � -TiAl;Monkman–Grant parameter; Coblecreep; Nabarro–Herring creep; superdislocation; dislocation; Kuhlmann-Wilsdorf barrier 1.Introduction Nearγ-titanium aluminide (TiAl)alloysofferarangeofattractive properties suchashigh specificstrength andgoodhigh-temperature properties whichincludehighoxidation resistance andgoodcreepresistance [1�].Inaddition, single-phase γ-TiAlalloysexhibit muchbetterfracturetoughness andcreepresistance ascompared tothatofnearγ-TiAl alloys[2].Thismakessingle-hase γ-TiAlalloyspotential candidates forthereplacement ofthemuchheavierNi-based superalloys inthelow-pressure turbinebladesofthenext- generation gasturbineenginesinaircrafts. Ontheotherhand,thecreepactivation energies frombothbulkandgrainboundaries (GBs)simultaneously influence the creeplifeofthematerial forhigh-temperature applications [3].Thisnecessitates exten- sivecreepstudiesprimarily focusing ontheinfluence oftertiarycreepandcreepactiva- tionenergyonthecreeplifeofthesematerials. Aseriesofreportsontheroom temperature tensiledeformation behaviour ofsingle-phase ɤ-TiAlalloys(L10structure) showthatthenear-ɤ,twophasecompositions having~48at.%Alpossessveryhigh CONTACT MainakSaha mainaksaha1995@gmail.com Department ofMetallurgical andMaterials Engineering, NationalInstituteofTechnology (NIT),Durgapur, WestBengal713209,India�ADVANCES INMATERIALS ANDPROCESSING TECHNOLOGIES https://doi.org/10.1080/2374068X.2021.1949175 ©2021InformaUKLimited,tradingasTaylor&FrancisGroup Electronic copy available at: https://ssrn.com/abstract=4067222 toughness (ultimate tensilestrength ~844–1010 MPaandtensileductility ~3–4.6% at roomtemperature) [4–7].Extensive creepdeformation studieshavebeencarriedouton anumberoftwophasenear-ɤ-TiAl alloysproduced byvariousprocessing routes[4,8].In addition, compression creep-based investigations havebeenperformed onanumberof single-phase ɤ-TiAlalloysandanumber ofliteratures havereported thatminimum strainratesduringcreeptestingatdifferent regimesoftemperature andstresshugely influence thegrainsizeofsingle-phase ɤ-TiAlalloys(duringcreeptesting)[3,9,10]. Minimum strainrateofsuchintermetallic-based alloysmaybedefinedintermsof Mukherjee–Bird–Dorn (MBD)equation [11–13]. HayesandMartin[4]havepresented ananalysisoftheminimum strainratedeforma- tionofawrought single-phase ɤ-TiAlalloywithintemperature rangeof760–1000°C and stressrangeof32–345MPa.Inaddition, theaforementioned work[4]alsopredictsthe mainmechanism forcreepruptureatdifferent temperatures, inagivenstressrange, usingLarson–Miller (L-M)[14]andMonkman–Grant (M-G)plots[15]andextensive microstructural characterisation usingopticalmicroscope (OM)andthetransmission electron microscope (TEM).Besides,arecentreport(fromtheauthor)onthetensile creepdeformation behaviour ofɤ-TiAlhasdetermined thestressexponent andcreep activation energiesbetween760and900°Cat69.4and103.4MPa[16].Moreover, based oncreepactivation energies andstressexponents, ithasbeenreported thatthereis atransition fromdislocation-glide todislocation-climb controlled creepatverylowcreep stresslevels(~66.68MPa)[16]andthatthereissteady-state creepobserved forboth interrupted anduninterrupted creeptestsat832°C[4].Aprevious workbytheauthor [16]hasrefutedsomeofthemajorobservations oftheearlierworkbyHayesandMartin [4]whichare: ●Thereisnotertiarycreepbetween760and900°C,atstresslevelsof69.4and103.4 MPainwrought single-phase ɤ-TiAlalloy. ●Steady-state creepisobserved at832°C,atstresslevelsof69.4MPa,forboth interrupted anduninterrupted tests. ●Single-phase ɤ-TiAlalloydoesnotexhibitdislocation creepat760,832and900°C andatstresslevelsbetween 32and345MPa. Moreover, thereislimitedunderstanding ofcreepbehaviour andcreeprupturelifeas afunction ofstressat832°C.Tothisend,thepresentworkisaimedtowardsunder- standing thecreepdeformation behaviour at832°Candtheinfluence ofcreepactivation energies ontherupturelife(ofthematerial) forstresslevelsof69.4and103.4MPaat 832°CusingM-Gapproach. 832°Chasbeenchosenasthecreeptesttemperature and 69.4and103.4MPahavebeenchosenasthecreepstresslevelssincethecreepbehaviour andtheinfluence ofcreepactivation energies onthecreeplifeattheaforementioned temperature andstresslevelsarenotknowntilldate.Theapproach usedinthepresent workisthedetermination oftensilecreepdeformation behaviour fromstrainratevs. strainplotsat832°Cfollowed bythedetermination ofcreeplifefortwodifferent stress levels(69.4and103.4MPa)usingM-Gapproach andfinallycorrelating thecreep activation energies usingAshby’sapproach [17]forbothGBdiffusion creep(orCoble creep)andlatticediffusion creep[orNabarro–Herring (NH)creep]withtheoverall creeplife(ofɤ-TiAlalloy)at69.4and103.4MPaat832°C.2 M.SAHA Electronic copy available at: https://ssrn.com/abstract=4067222 2.Theoretical analysis Basedonthesingle-phase ɤ-TiAlalloycomposition andtensilecreeptestparameters usedbySaha[16],theminimum strainrate(εmin)vs.strain(ε)andln(εmin)vs.εplots havebeendetermined at832°Cfortwodifferent stresslevels,viz.,69.4and103.4MPafor thepurposeofunderstanding theinfluence ofcreepstressandtemperature onthethree creepregimes(viz.,primary, secondary andtertiary)andtheinfluence ofthesameonthe creeplifeofthematerial. Forcreeplifedetermination, M-Gapproach wasused.For M-Gapproach, thegoverning equation�is[3,18] εstrCMG (2) where,εsisthesteady-state creeprate(~εminbasedonthejustification thatmany metallicmaterials maynotexhibitsteady-state creep(provided inref[16].)),tristhe rupturetime(expressed inseconds) andCMG(~1.40at832°C)istheM-Gconstant (obtained fromref[16].). 3.Results Figure1(a,b)showsthevariation of_εwithε(inbothlinearandlogarithmic scales, respectively) forthreecases,viz.,uninterrupted creeptestingandinterrupted creep testingwithtermination strainsof0.18and0.5%.Figure1(b)showsthecreepregimes at832°C(forstresslevelsof69.4and103.4MPa,respectively) withahighersimplicity. BasedonFigure1,itisobserved thatthepresentmaterial(45.9Ti–0.91Nb–52.9Al (at.%)) showsaveryearlyonsetoftertiarycreepat832°Cforuninterrupted creeptestandfor creeptestterminated at0.5%strain,whereas thereisnoprimary (ortransient) creep observed duringcreeptestinterrupted atstrainof0.18%(Figure1),indicating thatthe material(usedinthepresentwork)doesnotexhibitresistance tocreepdeformation for theaforementioned deformation condition. Besidesthereisalimitedregimeoftertiary Figure1.Variation of(a)_εwithε,and(b)ln(_ε)withε.Inparts(a)and(b),theplotuninterrupted creep testhasbeenrepresented usingblackcolour,whereasthecreepteststerminated at0.18%and0.5% havebeenrepresented usingredandbluecolours,respectively. Theinsetimagesinpartsin(a)and(b) represent thedifferent creepregimesinbothinterrupted anduninterrupted creeptestswithahigh levelofclarity(reproduced withpermission fromref[16]).ADVANCES INMATERIALS ANDPROCESSING TECHNOLOGIES 3 Electronic copy available at: https://ssrn.com/abstract=4067222 creepobserved forcreepteststerminated a0.18%and0.5%strain(Figure1).Inaddition, thematerialshowsadominant tertiarycreepregimeforthecaseofuninterrupted tensile creeptesting(Figure1).Secondary (orsteady-state creep)isnotobserved inanycase (Figure1).Inotherwords,theinterrupted creeptestsleadtoahigherrateofvacancy formation atGBsnormaltothetensilestresssubsequently followed byvoidgrowthand coalescence, leadingtoanintergranular fracture, asmentioned inrefs.[19–21]. Explanation oftheabovetendencies duringinterrupted anduninterrupted tensile creeptest(at832°C)issubjecttoextensive microstructural investigations whichis beyondthescopeofthepresentdiscussion. Foruninterrupted creeptesting,thereisadominant tertiarycreepregime(Figure1). Moreover, ithasbeenreported thattheextentoftertiarycreephugelyinfluences the creeplifeofthematerial [20,22–24]. Tothisend,creeplifedetermination hasbeen performed forsamples(withuninterrupted creeptesting)at832°C.Figure2showsthe creeplifeplots(foruninterrupted creeptesting)basedonM-Gapproach forstresslevels of69.4and103.4MPaat832°C.FromFigure2,itisobserved thattrdecreases with increasing _εminat832°C(basedonequation 2).Moreover, theslope(p)oftheM-Gcurve (inFigure2)iscalculated as−1.33whichsuggeststhatthemechanism ofcreepruptureis power-law breakdown at832°C(usingthecriteriamentioned inrefs.[3,25–30]). Hayes andMartin[4]andSaha[16]havereported that_εmindecreases withincreasing stress levels(from69.4to103.4MPa)at832°C.Moreover, Saha[16]hasreported thatthecreep mechanisms operating atdifferent stresslevels(69.4and103.4MPa)at832°Care independent ofeachotherand,hence,arenotsequential. Hence,combining thetrend observed between_εminwithtr(Figure2)withtheaforementioned reports([4,16]),itmay beinferred thatM-G-based approach todetermine thecreeplifealsopredictsthattr decreases withincreasing stresslevels(from69.4to103.4MPa)at832°C. Figure2.M-Gplotsfordetermining creeplifefor69.4and103.4MPaat832°C._εminhasbeen normalised withrupturestrain(εr)determined fromFigure1.Ajustification oftheabovenormal- isation(forM-Gplots)hasbeenprovided inref[14].4 M.SAHA Electronic copy available at: https://ssrn.com/abstract=4067222 BasedontheAshby’smodel[25],theconstitutive equation forNH(orlatticediffusion creep)isgivenas lε9B3DlGb kTb d��2σ G�� (3) where lεisthestrainrate,Dlisthelatticediffusivity, bistheBurgersvector,disthegrain size,kistheBoltzmann constant, σisthecreepstressandGistheshearmodulus ofthe material. Similarly, usingAshby’smodel,theconstitutive equation forCoblecreep(or GBdiffusion creep)isgivenas lε33B4DGBGb kTb d��3σ G��δ b�� (4) whereistheGB�widthandDGBistheactivation energyforGBdiffusion. BothDGBandDl arehighlytemperature-dependent [25].However, themagnitude ofDGBishigherthanthat ofDlatlowerhomologous temperatures, whereasthemagnitude ofDlishigherthanthatof DGBathigherhomologous temperatures [31,32].ThisisbecauseGBsofferahigherpathway fordiffusion atlowertemperatures whencompared withthatofthelattice[33].Moreover, acomparison ofequations (3)and(4)showsthatCoblecreephasahighergrain-size dependence ascompared tothatofNHcreep.Inotherwords,although bothCobleandNH creepmayoperatesimultaneously, Coblecreepisthedominant diffusion creepmechanism forfinegrainsizesatlowertemperatures whereasNHcreepdominates forcomparatively coarsergrainsathighertemperatures. However, boththesemechanisms showasimilar sensitivity towardsσ(asshowninequations (3)and(4)).Basedontheprevious reports [4,16],dhasminimalinfluence onlε.Thedirectproportionality between lεadσinequations (3)and(4)alsoexplainstheprevious observations (inrefs.[4,16,34]) ontheincreasing magnitude oflεwithincreasing stresslevelsfrom69.4to103.4MPa.Besides,G,σ,T(~832° C)andbareconstant inthepresentwork.Table1showsthecreepactivation energyfor stresslevelsof69.4and103.4MPaat832°Candhasbeenobtained fromref.[16].Basedon thevaluesofNHandCoblecreepactivation energies(QlandQGB,respectively) reportedfor 69.4MPa(QGB~210kJ/molandQl350kJ/molat832°Cinref.[16])andfor103.4MPa (QGB~151.88kJ/molandQl253.13kJ/molat832°Cinref.[16]),itmaybeinferredthat adecrease inthecreepactivation energy(forbothCobleandNHcreep)significantly reducesthecreeplifeofthematerialwithincreasing stresslevelsfrom69.4to103.4MPa. 4.Discussion Ashighlighted byLuandHemker[35],themaindeformation mechanisms duringtensile creepinabsenceofsteady-state creepat832°Careasfollows.Table1.CobleandNabarro–Herring (NH)creepactivation energies(QGBandQl,respectively) forstress levelsof69.4and103.4MPaat832°C[16]. Stresslevel (MPa)Testtemperature (°C)Coblecreepactivation energy(QGB) (kJ/mol)Nabarro–Herring creepactivation energy (Ql)(kJ/mol) 69.4 832 210 350 103.4 832 151.88 253.13ADVANCES INMATERIALS ANDPROCESSING TECHNOLOGIES 5 Electronic copy available at: https://ssrn.com/abstract=4067222 4.1.Superdislocations Thesehavebeenobserved intwodifferent forms:(i)formation offaultdipolesand(ii) rectilinear Kuhlmann-Wilsdorf (KW)typeofbarrierstodislocation motion[36].For instance, inversecreepinNi3Almaybeassociated withthebowingoutofsuperdisloca- tionsandtheirmovement alongcubecross-slip plane[37].Ni3Alandɤ-TiAlalloysshow similarinversecreepbehaviour, suggesting thatsuperdislocation associated deformation behaviour issimilarinbothNi3Alandɤ-TiAlalloys[35].Moreover, inboththeafore- mentioned alloys,thedisappearance offaultdipolesandlinearprofileoflockedscrew superdislocations atlaterstagesofcreepdeformation suggeststhatthesuperdislocation activityonlyinfluences theprimary creepbehaviour inboththeaforementioned alloys[35]. Moreover, thedrasticdecrease increeprateduringprimary creepstageforunin- terrupted creeptestandcreeptestinterrupted at0.5%straintofailure(Figure1)maybe attributed totheexhaustion ofsuperdislocation movement. Forinstance, duringyield- ing,themotionofsuperdislocations hasbeenreported tobeinhibited bythetwo competing mechanisms, viz.,(i)Localised pinningandformation offaultdipoles[35] and(ii)globalcrossslipwithformation ofKWtypeofrectilinear barriers[35].The formation offaultdipolesatlowertemperatures hasbeenattributed tothelocalised pinningofsuperdislocations followed bythebypassing ofpinnedsegments (ofsuper- dislocations) andthesubsequent drawing outoffaultdipolewhosestrainenergyis reduced bythepassageofpartialdislocations, leadingtotheformation ofextrinsic stacking faults.Theinstability offaultdipolesathighertemperatures maybeusedto understand thetemperature dependence ofprimarycreep[35,38].However, theforma- tionofKWtypeofbarriershasbeenobserved todominate athighertemperatures and forlongertimes.Earlierhigh-resolution transmission electron microscopy (HRTEM) observations [38]haverevealed thatthesebarriersundergo dissociation inanonplanar configuration, andhence,actasverystrongobstacles tothefurthermovement of superdislocations. Thereishardlyanyinfluence ofsuperdislocation movement onthetertiarycreepofɤ- TiAlalloyassuggested bythemacroscopic shapeofthecreepcurvesforbothunin- terrupted andinterrupted creeptesting(Figure1).Thetemperature dependence of tertiarycreephasbeenreported tobecomparatively lesserinɤ-TiAlthanthatinNi3 Al.Thehightemperature dependence oftertiarycreepinNi3Alhasbeenattributed tothe Peierls-like motionofsuperdislocations onthecubecross-slip plane[35].Cross-slipped superpartials (orsuperpartial dislocations) havebeenobserved tobemorewidelydis- sociatedinɤ-TiAlthanthatinNi3Al,resulting inahigherPeierlsstressforɤ-TiAlthan thatinNi3Al[35,37].Inthislight,themoremoderate temperature dependence exhibited byɤ-TiAlindicates thatglideofsuperdislocations (alongcubic{100}planeinɤ-TiAl) cannotbeusedtoexplaintertiarycreepinthisalloy. 4.2.Ordinary dislocations Theextended natureoftertiarycreepthathasbeenshownfortheuninterrupted creep test(Figure1)maybeattributed totheincreased activityofordinary dislocations. Although presentduringprimarycreep,theimportance ofordinary dislocation motion6 M.SAHA Electronic copy available at: https://ssrn.com/abstract=4067222 hasbeenreported tooccurafteracomplete exhaustion ofsuperdislocation movement [35].Pinning andaligning ofordinary dislocations alongthescrewdirection during primary creepsuggests thattheirmotionisinitiallyinhibited bytheintrinsic process whichhavebeenpreviously usedtodescribe theyieldstrength anomaly inTiAl.These intrinsic processes involveadoublecross-slip phenomenon bywhichadislocation undergoes cross-slip toasecondary octahedral slipplaneandthencomesbacktothe primary slipsystemasshowninFigure3(a-c))[35].Whenadislocation attains aconfiguration similartotheoneasshowninFigure3(c)[35],thejoggedsegment is unabletoundergo aforwardglidewiththeremaining partofthedislocation lineleading tooneoftheseveralnon-conservative phenomenon: (i)zippingofthejog(alongthe lateraldirection) leadingtothegrowthofonesegment attheexpense oftheother (Figure3(d))[35],(ii)forwardclimbing ofthejog(Figure3(e))[35],(iii)pinching off oftheleadingdislocation leadingtoasmallloopintheirneighbourhood (Figure3(f)) [35]and(iv)spiralmotionofthejogsegments andtheiroperationas aZ-millsource provided thatthejogissufficiently high(Figure3(g))[35]. Theincreasingly bowedshapeoftheordinary dislocations (Figure3)associated with thelatterstagesoftensilecreepsuggests thatoneormoreoftheaforementioned processes occurifthereissufficient timeallocated foradislocation atahighhomologous temperature [35].Boththeexpansion ofdislocation loopsandthespiralling ofaZ-mill source(Figure3(g))mayleadtoanincreaseintheoveralldislocation density[35,39,40]. Thismaybeusedtodescribe theextended tertiarycreepregimeforcontrolling the Figure3.Movement ofordinary dislocation inTiAl:alocalised segment ofascrewdislocation (a) undergoing cross-slip toasecondary octahedral {111}plane(b)andthencomesbacktotheprimary slipplaneleadingtotheformation of(c)twoedgesegment jogswhichcannotundergoglidewiththe restofthedislocation (reproduced withpermission fromref.[35]).ADVANCES INMATERIALS ANDPROCESSING TECHNOLOGIES 7 Electronic copy available at: https://ssrn.com/abstract=4067222 overallcreepbehaviour duringinterrupted creeptestingofɤ-TiAl(Figure1).Theroleof diffusion inthisparticular processisclearlyunderstood. Themeasured creepactivation energiesatstresslevelsof69.4MPaand103.4MPaat832°C(Qcreep=QGB+Ql~560kJ/ molat69.4MPa,832°Cand405.01kJ/molat103.4MPa,832°C,QGBandQlobtained fromTable1)aremuchhigherthanthatfordiffusion ofTiinTiAl(~291kJ/mol, reported inref.[35]).Theactivation energyofAlinTiAlisnotaccurately measured till date.Qcreepbecomes important inthecontextofdiffusion creepwhichrequires the diffusion ofbothTiandAlinTiAl[40].Following thisprinciple,Qcreepmayberelatedto theclimbofjogsatdifferent pinningpoints.Inthiscontext,itisworthmentioning that thermalactivation ofdislocation motionalsoplaysakeyroleduringdiffusion creepinɤ- TiAl[40].However, theinfluence ofmechanical twinning (athermalprocess) onthe dislocation motionattheaforementioned stressandtemperature inɤ-TiAlalloyisyetto beinvestigated andisbeyondthescopeofthepresentdiscussion. 5.Conclusions Thepresentworkhighlights thetensilecreepdeformation behaviour at832°Candthe influence ofcreepactivation energies(forbothCobleandNHcreep)onthecreeplife(of singlephaseɤ-TiAlalloy)asafunction ofincreasing stresslevelsfrom69.4to103.4MPa at832°C(wherethereisnooccurrence ofsteady-state creep).Theapproach usedinthe presentworkisbasedonthedetermination ofdifferent creepregimesat832°Cfollowed bythedetermination ofcreeplifefortwodifferent stresslevels(69.4and103.4MPa) usingM-Gapproach andfinallycorrelating thecreepactivation energies(forbothCoble andNHcreep)withtheoverallcreeplifeat69.4and103.4MPaat832°C.Moreover, the mechanisms ofsuperdislocation andordinary dislocation motionoperative during tensilecreepdeformation attheaforementioned stressandtemperature havealsobeen elucidated. Thefollowing maybeconcluded basedontheresultsobtained inthepresent work: ●At832°C, ɤ-TiAlalloy(45.9Ti–0.91Nb–52.9Al (at.%))showsadominant tertiary creepregimeforuninterrupted creeptesting,whereas thereisalimitedtertiary creepregimeforcreeptests(underthesametemperature andstresses) forcreep testsinterrupted at0.18%and0.5%,indicating thatduringinterrupted creep testing,thereisahigherrateofvacancy formation alongGBsnormaltothe appliedtensilestressfollowed byvoidcoalescence andgrowthleadingtointer- granular fracture. Moreover, thedominant creepregimefortheuninterrupted creeptestat832°Cmaybeattributed totheincreased activityofdislocations duringtertiarycreep. ●At832°Cforstresslevelsof69.4and103.4MPa,adrasticdecrease increepratewith creepstrainduringprimarycreepstageforuninterrupted creeptestandcreeptest interrupted at0.5%ofthestraintofailuremaybeattributed totheexhaustion of superdislocation activityduringprimarycreepattheaforementioned temperature andstresslevels.Besides,themacroscopic natureofcreepcurvesforbothunin- terrupted andinterrupted creeptestssuggests thatthereishardlyanyroleof superdislocations onthetertiarycreepattheaforementioned temperature andstress levels.8 M.SAHA Electronic copy available at: https://ssrn.com/abstract=4067222 ●M-Gapproach (forcreeplifedetermination) showsthatcreeplife(foruninter- ruptedcreeptesting)decreases withincreaseinstresslevelsfrom69.4to103.4MPa. Inaddition, M-Gplotsindicatethemodeofrupture(foruninterrupted creeptest)at 832°C(forstresslevelsof69.4and103.4MPa)ispower-law breakdown. ●Adecrease increepactivation energy(forbothCobleandNHcreep)reducesthe creeplifeofthematerial withincreasing stresslevelfrom69.4to103.4MPa, highlighting thatcreepactivation energylargelyinfluences thecreeplifeofsingle- phaseɤ-TiAlalloyat832°C. 6.Futureworktobedone Extensive TEM-based microstructural investigations arerequired tofurthervalidatethe observations obtained fromcreepcurvesandcorrelate thedifferent creepmechanisms withthearrangement ofbothdislocations andsuperdislocations duringthedifferent creepregimesforbothuninterrupted andinterrupted creeptestingat832°C.Thiswould provideanexperimental evidence forunderstanding theinfluence ofcreepactivation energyonthecreeplifeofsingle-phase ɤ-TiAlalloy. Acknowledgments MSwouldliketoacknowledge theDepartment ofMetallurgical andMaterials Engineering, NIT Durgapur, fordetaileddiscussions duringthepreparation ofthemanuscript. Disclosure statement Nopotential conflictofinterestwasreported bytheauthor(s).� ORCID MainakSaha http://orcid.org/0000-0001-8979-457X