Electride. An electride is an ionic compound in which an electron serves the role of the anion. Solutions of alkali metals in ammonia are electride salts. In the case of sodium, these blue solutions consist of [Na(NH3)6]+ and solvated electrons: 
Na  +  6 NH3  →   [Na(NH3)6]+ + e−
The cation [Na(NH3)6]+ is an octahedral coordination complex. Despite the name, the electron does not leave the sodium-ammonia complex, but it is transferred from Na to the vacant orbitals of the coordinated ammonia molecules.

Solid salts
Addition of a complexant like crown ether or [2.2.2]-cryptand to a solution of [Na(NH3)6]+e− affords [Na (crown ether)]+e− or [Na(2,2,2-crypt)]+e−. Evaporation of these solutions yields a blue-black paramagnetic solid with the formula [Na(2,2,2-crypt)]+e−.

Most solid electride salts decompose above 240 K, although [Ca24Al28O64]4+(e−)4 is stable at room temperature. In these salts, the electron is delocalized between the cations. Properties of these salts have been analyzed.

ThI2 and ThI3 have also been proposed to be electride compounds.  Similarly, , , , and  are all electride salts with a tricationic metal ion.

Organometallic electrides

Magnesium reduced  nickel(II)-bipyridyl (bipy) complex have been labeled organic electrides.  An example is [(THF)4Mg4(μ2-bipy)4]–, in which the electride is the singly occupied molecular orbital (SOMO) formed by the Mg-square cluster within the larger complex.

"Inorganic electrides" have also been described.

Reactions
Electride salts are powerful reducing agents, as demonstrated by their use in the Birch reduction. Evaporation of these blue solutions affords a mirror of Na metal. If not evaporated, such solutions slowly lose their colour as the electrons reduce ammonia:
2[Na(NH3)6]+e− → 2NaNH2 + 10NH3 + H2
This conversion is catalyzed by various metals. An electride, [Na(NH3)6]+e−, is formed as a reaction intermediate.

High-pressure elements
In quantum chemistry, an electride is identified by a maximum of the electron density, characterized by a non-nuclear attractor, a large and negative Laplacian at the critical point, and an Electron Localization Function isosurface close to 1. Electride phases are typically semiconducting or have very low conductivity, usually with a complex optical response. A sodium compound called disodium helide has been created under  of pressure. It has been proven that the localized electron density in high-pressure electrides does not correspond to isolated electrons, but that it is generated by the formation of (multicenter) chemical bonds.

The intrinsic polarization between atomic nucleus and the electron anion in these high pressure electrides can lead to unique properties, such as the splitting of the longitudinal and transverse acoustic modes (i.e., LA-TA splitting, an analogue to the LO-TO splitting in ionic compound), the universal but robust gapless surface state in insulating electride that forming a de facto real space topological distribution of charge carriers, and the colossal charge state of some impurities in them.

Layered electrides (Electrenes)
Layered electrides or electrenes are single-layer materials consisting of alternating atomically thin two-dimensional layers of electrons and ionized atoms. The first example was Ca2N, in which the charge (+4) of two calcium ions is balanced by the charge of a nitride ion (-3) in the ion layer plus a charge (-1) in the electron layer.

See also
F-center

References

Further reading
 

Salts
Electron