1,1'-双(二环己基膦基)二茂铁

1,1'-双(二环己基膦基)二茂铁（1,1'-bis(dicyclohexylphosphino)ferrocene，简写dcpf）是一种有机铁化合物，化学式为C34H52FeP2，它是一种膦类配体。

反应
它和M(CO)6（M=Cr, Mo, W）在三甲胺-N-氧化物存在下反应，可以得到M(CO)4(dcpf)。Berstler J, Lopez A, Ménard D, et al. Synthesis and spectroelectrochemistry of transition metal carbonyls with 1, 1′-bis (phosphino) metallocene ligands. Journal of Organometallic Chemistry, 2012, 712: 37-45. .

它和二(苯甲腈)氯化钯或二乙腈合二氯化铂反应，可以得到MCl2(dcpf)（M=Pd, Pt）。Hagopian L E, Campbell A N, Golen J A, et al. Synthesis and electrochemistry of late transition metal complexes containing 1, 1′-bis (dicyclohexylphosphino) ferrocene (dcpf). The X-ray structure of [PdCl2(dcpf)] and Buchwald–Hartwig catalysis using [PdCl2(bisphosphinometallocene)] precursors. Journal of organometallic chemistry, 2006, 691(23): 4890-4900. .

参考文献

Category:膦
Category:二茂铁