甲磺酸钴

甲磺酸钴是一种磺酸盐，化学式为Co(CH3SO3)2，它存在四水合物。它在空气中的热分解产物是四氧化三钴。Wang M, Song Z, Jiang H, et al. Thermal decomposition of metal methanesulfonates in air. Journal of thermal analysis and calorimetry, 2009, 98(3): 801-806. .它和（H2BPZ）在乙醇中于80 °C反应，可以得到Co(H2BPZ)2(CH3SO3)2。Freund R, Kraft M, Volkmer D. Influencing the dimensionality of Ni/Co‐Bipyrazole‐based coordination frameworks through anions and thermal activation. European Journal of Inorganic Chemistry, 2022, 2022(1): e202100853. .它可用于钴或钴合金的电化学沉积。Zhao F, Franz S, Vicenzo A, et al. Electrodeposition of nanostructured columnar cobalt for self-lubricant coatings. Electrochimica acta, 2011, 56(26): 9644-9651. .Sknar Y E, Sknar I V, Savchuk O O, et al. Electrodeposition of NiCo alloy from methansulfonate electrolyte. The role of the electrolyte pH in the anomalous codeposition of nickel and cobalt. Surface and Coatings Technology, 2020, 387: 125542.

参考文献

Category:甲磺酸盐
Category:钴化合物