甲磺酸银

甲磺酸银是一种磺酸盐，化学式为CH3SO3Ag。它可由甲磺酸和氧化银或碳酸银反应制得。

反应

甲磺酸银和三氯化六氨合钴(III)反应，可以定量地生成[Co(NH3)6](CH3SO3)3：Bala, Ritu; Sharma, Raj Pal; Bond, Andrew D. Second-sphere coordination in hexaamminecobalt(III) salt with organic sulphonate anion: Synthesis, characterization and X-ray crystal structure of [Co(NH3)6](CH3SO3)3. Journal of Molecular Structure, 2007. 830 (1-3): 198-203. .
 3 CH3SO3Ag + [Co(NH3)6]Cl3 → [Co(NH3)6](CH3SO3)3 + 3 AgCl↓

它和六水合哌嗪在氨水存在下于乙腈-乙醇中反应，可以得到[Ag(C4H10N2)]CH3SO3。Kokunov, Yu. V.; Gorbunova, Yu. E.; Kovalev, V. V. Coordination polymers of silver with piperazine and uncoordinated anions: Syntheses and crystal structures of [Ag(C4H10N2)]CH3SO3 and [Ag(C4H10N2)]PO2F2. Russian Journal of Coordination Chemistry, 2011. 37 (2): 95-99. .
参考文献

延伸阅读
 Tao, Xian; Shen, Ke-Cheng; Shen, Ying-Zhong. Syntheses, X-ray structures and CVD studies of trimethylphosphite stabilized silver(I) methanesulfonates. Journal of Organometallic Chemistry, 2011. 696 (13): 2681-2684. .

Category:银化合物
Category:甲磺酸盐