3-甲基亚苄基丙二腈

3-甲基亚苄基丙二腈是一种有机化合物，化学式为C11H8N2。它可由和丙二腈加热反应得到。Weifan Wang; et al. Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes. ACS Sustainable Chem. Eng. 2019, 7, 1, 1718–1722. .

反应

3-甲基亚苄基丙二腈可以被硼氢化钠在甲醇中还原为3-甲基苄基丙二腈。Dapeng Zhang; et al. Preparation of O-Protected Cyanohydrins by Aerobic Oxidation of α-Substituted Malononitriles in the Presence of Diarylphosphine Oxides. Org. Lett. 2019, 21, 8, 2597–2601. .它和異丙苯氫過氧化物在催化下于三氟甲苯中反应，可以得到1-(3-甲基苯基)-2,2-二氰基环氧乙烷。Ogino, Eri; et al. Chiral C2-Symmetric Aminomethylbinaphthol as Synergistic Catalyst for Asymmetric Epoxidation of Alkylidenemalononitriles: Easy Access to Chiral Spirooxindoles. Organic Letters (2021), 23(6), 1980-1985. .

参考文献

Category:丙二腈
Category:间甲苯基化合物