6-溴-5-己炔腈

6-溴-5-己炔腈是一种有机溴化合物，化学式为C6H6BrN。它可由和N-溴代丁二酰亚胺在硝酸银催化下于丙酮中反应制得。Li Shang; et al. Redox-Neutral α-Arylation of Alkyl Nitriles with Aryl Sulfoxides: A Rapid Electrophilic Rearrangement. J. Am. Chem. Soc. 2017, 139, 11, 4211–4217. .它和硫氰酸钾在乙酸银催化下于乙腈中加热反应，可以得到(1Z)-1-溴亚甲基-4-氰基硫氰酸丁酯。Jiang, Guangbin; et al. Silver-Catalyzed Regio- and Stereoselective Thiocyanation of Haloalkynes: Access to (Z)-Vinyl Thiocyanates. Advanced Synthesis & Catalysis (2017), 359(7), 1208-1212. .
参考文献

Category:溴代炔烃
Category:腈