1-碘-3,4-亚甲基二氧苯

1-碘-3,4-亚甲基二氧苯是一种有机化合物，化学式为C7H5IO2。它可由1,3-苯并二氧戊环和N-碘代丁二酰亚胺在三氟乙酸催化下于乙腈中反应制得；Jeon, Hongjun; et al. Proline Ester Enolate Claisen Rearrangement and Formal Total Synthesis of (-)-Cephalotaxine. Journal of Organic Chemistry (2019), 84(12), 8080-8089. .或由相应的胺转化为重氮盐，再和碘化钾反应得到。He, Huazhong; et al. Identification of Potent Water Soluble Purine-Scaffold Inhibitors of the Heat Shock Protein 90. Journal of Medicinal Chemistry (2006), 49(1), 381-390. .它和三甲基硅基乙炔在催化下反应，可以得到1-三甲基硅基乙炔基-3,4-亚甲基二氧苯。Lu, Xiyan; et al. An efficient synthesis of (±)-isohinokinin from the acyclic ester precursor. Synlett (1993), (1), 68-70. .
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Category:苯并二𫫇茂