N-异氰基亚氨基三苯基磷

N-异氰基亚氨基三苯基磷是一种有机磷化合物，化学式为C19H15N2P。它可由甲酰肼、三苯基膦、DBU和四氯化碳在乙腈中反应制得。Lingnan Chen; et al. Silver-promoted regio- and stereoselective aminocyanation of alkynes for the synthesis of β-aminoacrylonitriles using N-isocyanoiminotriphenylphosphorane. Tetrahedron Letters, 2019. 60 (25): 1678-1681. .它在碳酸银存在下和芳基乙炔反应，可以得到(Z)-3-氨基-3-芳基丙烯腈。它和十羰基二氢三锇反应，可以得到十羰基氢化(三苯基𬭸基亚甲基)三锇。Te-Wei Chiu; et al. Synthesis, Structure, and Transformation of Novel Osmium Azine and Ylide Complexes. Inorg. Chem. 2005, 44, 18, 6425–6430. .

参考文献

Category:异腈
Category:λ5-磷烷