钨酸亚铊

钨酸亚铊是一种无机化合物，化学式为Tl2WO4。它可由三氧化二铊或碳酸亚铊和三氧化钨加热反应制得，Macarovici, Dan; Gaultier, Max; Courtine, Pierre. Thermal synthesis and crystalline structure of thallium tungstate. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques (1968), 266(26), 1777-1779. .R.P. Rastogi; B.L. Dubey; Lakshmi; Ishwar Das (1977). Solid-state chemistry of thallous tungstates. J. Inorg. Nucl. Chem., 39 (12). .或由硝酸亚铊和钨酸钠在水溶液中反应得到。Goudarzi, Mojgan; Mir, Noshin; Amiri, Omid; Salavati-Niasari, Masoud. Photocatalytic degradation of antibiotic using Ni-doped thallium(I) orthotungstate nanorods: Hydrothermal synthesis and characterization. Journal of Alloys and Compounds (2021), 874, 159856. .它可以以三方晶系Pm1空间群结晶，晶胞参数a=6.278(1) Å，b=8.099(2) Å，Z=2。Okada, K.; Ossaka, J.; Iwai, S. Structure of dithallium tungstate(VI). Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry (1979), B35(9), 2189-2191. .它和三氧化钨加热反应，可以得到Tl2W2O7和Tl2W4O13。Arkhincheeva, S. I.; Bazarova, Zh. G.; Mokhosoev, M. V.; Munkueva, S. D. Reaction of thallium(I) tungstate with tungsten trioxide. Zhurnal Neorganicheskoi Khimii (1988), 33(8), 2089-2091. .

参考文献

Category:铊化合物
Category:钨酸盐