二硫化二锡三钴

二硫化二锡三钴是一种无机化合物，化学式为Co3Sn2S2，其中Co为0价及+2价（Co0:Co2+≈1:2）Atsushi Umetani; et al. Electronic and magnetic nature of shandite-type A2Co3S2 (A=Sn, In). Physica B: Condensed Matter, 2008. 403 (5-9): 1356-1358. .，Sn为0价Jack Corps; et al. Interplay of Metal-Atom Ordering, Fermi Level Tuning, and Thermoelectric Properties in Cobalt Shandites Co3M2S2 (M = Sn, In). Chem. Mater. 2015, 27, 11, 3946–3956. .，它具有结构。Zabel, Manfred; Wandinger, Sigrid; Range, Klaus Juergen. Ternary chalcogenides M3M2'X2 with shandite-type structure. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie (1979), 34B (2), 238-241.它可由锡、钴和硫在真空（10−5 Torr）的石英管内于高温反应制得。S. Natarajan; G.V.Subba Rao; R. Baskaran; T.S. Radhakrishnan (1988). Synthesis and electrical properties of shandite-parkerite phases, A2M3Ch2. Journal of the Less-Common Metals, 138 (2), 215–224. .它是一种外尔半金属。Yuxiang Gao et al (2021). Electronic structures of vacancies in Co3Sn2S2. Chinese Phys. B. 30. 077102. .

参考文献

Category:锡化合物
Category:零价钴化合物
Category:二价钴化合物
Category:硫化物