四氯合铝酸五铋

四氯合铝酸五铋是一种无机化合物，化学式为Bi5(AlCl4)3。它可由金属铋、氯化铋和氯化铝共熔反应制得：Robert C. Burns; Ronald J. Gillespie Woon-Chung Luk. The preparation, spectroscopic properties, and structure of the pentabismuth(3+) cation, Bi53+. Inorg. Chem. 1978, 17, 12, 3596–3604. 
4 Bi + BiCl3 + 3 AlCl3 → Bi5(AlCl4)3
它也可由相同的反应物在[BMIM]Cl/AlCl3（BMIM+=1-正丁基-3-甲基咪唑鎓）离子液体中于室温反应得到。Ahmed, Ejaz; Koehler, Daniel; Ruck, Michael. Room-temperature synthesis of bismuth clusters in ionic liquids and crystal growth of Bi5(AlCl4)3. Zeitschrift fuer Anorganische und Allgemeine Chemie (2009), 635(2), 297-300. .

它也是氯化铝和硫化铋在[BMIM]Cl/AlCl3中反应的副产物。Groh, Matthias F.; Isaeva, Anna; Mueller, Ulrike; Gebauer, Paul; Knies, Maximilian; Ruck, Michael. Controlled Synthesis of Pnicogen-Chalcogen Polycations in Ionic Liquids. European Journal of Inorganic Chemistry (2016), 2016(6), 880-889. .

参考文献

Category:铋化合物
Category:氯铝酸盐