硼烷肼

硼烷肼是一种无机化合物，化学式为N2H4BH3。它可由硫酸肼和硼氢化钠反应制得。Goubeau, J.; Ricker, E. Borinhydrazin und seine Pyrolyseprodukte. Zeitschrift fuer Anorganische und Allgemeine Chemie (1961), 310, 123-142. .它也能在氢溴酸肼和硼氢化镁的反应中生成：Margaret Fitzgerald; et al. Low-Temperature Dehydrogenation of Vapor-Deposited Magnesium Borohydrides Imaged Using Identical Location Microscopy. J. Phys. Chem. C 2022, 126, 45, 19024–19034. .
 2 N2H5Br + Mg(BH4)2 → 2 N2H4BH3 + MgBr2 + 2 H2↑
性质
硼烷肼在液态肼中会发生自催化分解，生成H2BNHNH2和H2Zakharov, V. V.; Nikitin, V. S.; Zhigach, A. F.; Manelis, G. B.; Nechiporenko, G. N. Kinetics and mechanism of the thermal decomposition of hydrazineborane solutions in hydrazine. I. Kinetics of thermal decomposition. Zhurnal Fizicheskoi Khimii (1975), 49(10), 2595-2599. .；它热分解生成(H2BNHNHBH2)n。Zhigach, A. F.; Zakharov, V. V.; Manelis, G. B.; Nechiporenko, G. N.; Nikitin, V. S.; Esel'son, B. M. Kinetics of the thermal decomposition of hydrazineborane. Zhurnal Neorganicheskoi Khimii (1973), 18 (7), 1762-1766. 

它可以水解：Zakharov, V. V.; Nechiporenko, G. N.; Manelis, G. B. Kinetics and mechanism of the thermal decomposition of hydrazineborane solutions in hydrazine. II. Mechanism of thermal decomposition. Zhurnal Fizicheskoi Khimii (1975), 49 (10), 2600-2604. .
 H3BNH2NH2 + 3 H2O → H3BO3 + N2H4 + 3 H2↑

它可以和氢化钾剧烈反应，生成KN2H3BH3。S. Pylypko; et al. Metal hydride–hydrazine borane: Towards hydrazinidoboranes or composites as hydrogen carriers. International Journal of Hydrogen Energy, 2015. 40 (43): 14875-14884. .
参考文献

参见
 硼烷氨（NH3BH3）

Category:硼-氮化合物
Category:硼烷配合物
Category:肼配合物