甲磺酸铀酰

甲磺酸铀酰是一种无机化合物，化学式为UO2(CH3SO3)2。它可由乙酸铀酰二水合物和甲磺酸以及少量的甲磺酸酐在140 °C反应制得Ulf Betke; Kai Neuschulz; Mathias S. Wickleder (2011). Methanesulfonates of High-Valent Metals: Syntheses and Structural Features of MoO2(CH3SO3)2, UO2(CH3SO3)2, ReO3(CH3SO3), VO(CH3SO3)2, and V2O3(CH3SO3)4 and Their Thermal Decomposition under N2 and O2 Atmosphere. Chem Eur J, 17(45), 12784–12801. .；它的一水合物可由三氧化铀和甲磺酸在甲磺酸胍存在下反应、结晶得到。Andreev G B, Budantseva N A, Tananaev I G, et al. A second polymorph of catena-poly [[aquadioxidouranium(VI)]bis(μ-methanesulfonato-κ2O: O′)]. Acta Crystallographica Section E: Structure Reports, 2007, 63(12): m3159-m3159. 

它在氮气中的热分解产物为U3O7。

参考文献

Category:铀酰化合物
Category:甲磺酸盐