苯硫酚亚铜

苯硫酚亚铜是一种硫酚盐，化学式为C6H5SCu，可溶于吡啶，难溶于水。它可由二苯基二硫和铜粉在二甲基乙酰胺中反应制得。J. Robert Campbell. Reduction of Disulfides with Copper. Preparation of Some Thioethers. J. Org. Chem. 1962, 27, 6, 2207–2209. .或由铜(II)盐和苯硫酚反应得到：Michael E. Peach (1979). Preparation and thermal decomposition of some metal thiophenolates. J. Inorg. Nucl. Chem., 41(9), 0–1392. .Bowmaker, GA; Tan, L  (1979). The Preparation and Low-Frequency Vibrational Spectra of Some Copper(I) and Silver(I) Alkane- and Arene-monothiolate Complexes. Australian Journal of Chemistry, 32(7), 1443. .
 2 Cu2+ + 4 PhSH → 2 CuSH + PhSSPh （Ph=C6H5）
它和甲基锂在乙醚-四氢呋喃于低温中反应，可以得到CH3Cu(SPh)Li(THF)3。Steven H. Bertz; et al. First X-Ray Crystal Structure and Internal Reference Diffusion-Ordered NMR Spectroscopy Study of the Prototypical Posner Reagent, MeCu(SPh)Li(THF)3. Chemistry - A European Journal (2013), 19(31), 10138-10141. .

它的热分解产物为硫化铜。
参考文献

Category:一价铜化合物
Category:硫酚盐