氰化二(三苯基膦)亚铜

氰化二(三苯基膦)亚铜是一种配位化合物，化学式为(Ph3P)2CuCN，其中Ph为苯基。它在稀溶液中以单体的形式存在Reichie W T. Preparation, physical properties and reactions of copper(I)-triphenyl-M complexes (M= P, As, Sb). Inorganica Chimica Acta, 1971, 5: 325-332. .，并可以P空间群的六聚体的形式结晶。Donghae Kim; et al. Copper-Catalyzed Selective Arylations of Benzoxazoles with Aryl Iodides. J. Org. Chem. 2015, 80, 7, 3670–3676. .它可由三苯基膦和氰化亚铜在三氯甲烷中反应制得。Walter T. Reichle (1969). Three-coordinated complexes of copper(I). Inorg. Nucl. Chem. Letters, 5(12), 981–984. .

它在苯中和邻菲啰啉反应，可以得到氰化(邻菲啰啉)(三苯基膦)亚铜。Ramsharan Singh; S.K. Dikshit (1993). Cyano-bridged copper(I)-ruthenium(II) complexes: syntheses, characterization and spectroscopic studies. Polyhedron, 12(13), 1697–1703. .
参考文献

Category:一价铜化合物
Category:氰配合物
Category:三苯基膦配合物