高氯酸锡

高氯酸锡是一种无机化合物，化学式为Sn(ClO4)4。它可由六氧化二氯和四氯化锡反应，得到(ClO2)2Sn(ClO4)6后在真空中热分解得到。红外和拉曼光谱表明该化合物中每个Sn周围存在两个单齿高氯酸根配体和四个桥联双齿高氯酸根配体。Fourati, M.; Chaabouni, M. Synthesis and spectroscopic analysis of a new perchlorato complex: tin(IV) perchlorate. Journal de la Societe Chimique de Tunisie (1988), 2(8), 35-39. 它和四氯化锡反应，可以得到SnCl2(ClO4)2。Fourati, Mohieddine; Chaabouni, Moncef; Belin, Claude; Pascal, Jean Louis; Potier, Jacqueline. Chemical behavior of perchlorato ligand with tin(IV). Syntheses and structural analyses of dichlorobis(perchlorato)tin(IV) [SnCl2(ClO4)2], dichlorobis(μ-perchlorato)tin(IV) [(SnCl2(ClO4)2)x], di(perchlorato)bis(μ-perchlorato)tin(IV), [(Sn(ClO4)4)x], and chloryl hexakis(perchlorato)stannate(IV), [(ClO2)2Sn(ClO4)6]. A first x-ray structural approach of a chloryl perchlorato metallate. New Journal of Chemistry (1990), 14(8-9), 695-700. .

参考文献

Category:锡化合物
Category:高氯酸盐