(环庚三烯基)(环戊二烯基)六氟磷酸锰

(环庚三烯基)(环戊二烯基)六氟磷酸锰是一种有机锰化合物，化学式为C12H12MnPF6。它可由(环庚三烯)(环戊二烯基)锰和三苯基六氟磷酸碳反应制得。P.L. Pauson; J.A. Segal (1973). Complete photochemical carbonyl substitution in cyclopentadienyltricarbonylmanganese. Journal of Organometallic Chemistry, 63. C13-C14. .它可以通过丙酮-乙醇或丙酮-乙醚重结晶。Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. .它的氧化电位为0.70 V，还原电位为−1.61 V。Reinhard Basse; et al. Cationic Cycloheptatrienyl Cyclopentadienyl Manganese Sandwich Complexes: Tromancenium Explored with High-Power LED Photosynthesis. Organometallics 2021, 40, 15, 2736–2749. .

参考文献

Category:环庚三烯基配合物
Category:茂金属
Category:六氟磷酸盐
Category:有机锰化合物