五均三甲苯基五铜

五均三甲苯基五铜是一种有机铜化合物，化学式为C45H55Cu5，或简写为Cu5Mes5或(CuMes)5，其中Mes表示均三甲苯基。该化合物最初于1981年被报道。Michael Stollenz; Franc Meyer. Mesitylcopper – A Powerful Tool in Synthetic Chemistry. Organometallics 2012, 31, 22, 7708–7727. .它可由和氯化亚铜在四氢呋喃中反应制得。Edouard Marc Meyer; et al. Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines. Organometallics 1989, 8, 4, 1067–1079. .它和双(三氟甲磺酰基)胺（HNTf2）反应，可以得到[Cu(MesH)2][Cu(NTf2)2]。Marion Stricker; et al. Copper(I) and Silver(I) Bis(trifluoromethanesulfonyl)imide and Their Interaction with an Arene, Diverse Olefins, and an NTf2−-Based Ionic Liquid. Chem Eur J. 2013. 19 (3): 1042-1057. 

参考文献

Category:有机铜化合物
Category:均三甲苯基化合物
Category:含金属-金属键的化合物
Category:1980年代发现的物质