癸五炔

癸五炔是一种有机化合物，化学式为C10H2。它可由碳化钙和含Cu+/Cu2+的氯化铵溶液反应制得，该反应还会生成和等多炔副产物。(a) Franco Cataldo. The simplest approach to prepare solutions of polyynes in hydrocarbons. Tetrahedron Letters, 2005. 46 (21): 3665-3667. ; (b) Franco Cataldo. A method for synthesizing polyynes in solution. Carbon, 2005. 43 (13): 2792-2800. .它可以通过与银氨溶液反应来提纯。Liang Fang; et al. Purification of polyynes via carbides. Carbon, 2021. 179. 28-32. .它在紫外线Cataldo, Franco; Strazzulla, Giovanni; Iglesias-Groth, Susana (2008). UV photolysis of polyynes at λ=254 nm and at λ>222 nm. International Journal of Astrobiology, 7(2). 或γ射线Cataldo, Franco; Ursini, Ornella; Angelini, Giancarlo; Strazzulla, Giovanni  (2008). Polyynes Decomposition with γ Radiation. Fullerenes, Nanotubes and Carbon Nanostructures, 16(4), 272–281.下可以发生分解。它可以和碘形成分子配合物。Wada, Yoriko; et al. Spectroscopic characterization of a series of polyyne-iodine molecular complexes H(C≡C)nH(I6) of n = 5-9. Chemical Physics Letters (2012), 541, 54-59. 

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Category:炔烃