4,4'-偶氮苯乙醚

4,4'-偶氮苯乙醚是一种有机化合物，化学式为C16H18N2O2，它可由4,4'-氧化偶氮苯乙醚还原制得，Nanjundaswamy, H. M.; Pasha, M. A.  (2005). Facile, Product‐Selective Reduction of Azoxyarenes into Azoarenes or Hydrazoarenes by Aluminium/Hydrazine Hydrate. Synthetic Communications, 35(16), 2163–2168. 或4-氨基苯乙醚的氧化偶联得到。Ádám Georgiádes; et al. Exploring New Parameter Spaces for the Oxidative Homocoupling of Aniline Derivatives: Sustainable Synthesis of Azobenzenes in a Flow System. ACS Sustainable Chem. Eng. 2015, 3, 12, 3388–3397. .

反应
它在甲醇中可以被锌/联氨甲酸盐还原为1,2-二(4-乙氧基苯基)肼。Prasad, H. S.; Gowda, Shankare; Abiraj, K.; Channe Gowda, D. (2003). Catalytic Transfer Hydrogenation of Azo Compounds to Hydrazo Compounds Using Inexpensive Commercial Zinc Dust and Hydrazinium Monoformate. , 33(4), 717–724. .

它和氯化钯反应，可以得到配合物Pd2(κ2:C, N-L2)(μ-Cl)2（其中L为4,4'-二乙氧基偶氮苯-3-基）。Amanpreet K. Sandhu; et al. Cyclopalladation of azobenzenes and their reactivity towards N-substituted imidazolidine-2-thiones and allied ligands: Synthesis, structures, spectroscopy and ESI-mass studies. Journal of Organometallic Chemistry, 2018. 861. 112-124. .
参考文献

Category:苯乙醚
Category:偶氮化合物