二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂

二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂是一种配位化合物，化学式为PtCl2P2C12H24N6。它可由四氯合铂(II)酸钾和1,3,5-三氮杂-7-磷杂金刚烷（PTA）在乙醇中反应制得，，或通过PtCl2(COD)（COD=1,5-环辛二烯）和PTA反应得到。Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. .它在0.1 mol/L的盐酸溶液中可以结晶出无色的cis-[PtCl2(PTAH)2]Cl2晶体。Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. .它的配位氯可以被含硫配体取代。Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. .
参考文献

Category:铂配合物
Category:二价铂化合物
Category:膦配合物
Category:氯配合物