三氨三羰基铬

三氨三羰基铬是一种有机铬化合物，化学式为Cr(CO)3(NH3)3。它可由六羰基铬和氢氧化钾在乙醇中（或和四甲基氢氧化铵在甲醇中Timothy J. McNeese; Maurice B. Cohen; Bruce M. Foxman. Synthesis, structure, and reactivity of a polynuclear chromium tetraanion, tetrakis[(μ3-methoxo)tricarbonylchromate(0)]. Organometallics 1984, 3, 4, 552–556. ）和浓氨水反应制得。Tucker M. Folsom; Gulzar A. Bhat; Ahmed Z. Rashad; Donald J. Darensbourg. Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes. Macromolecules 2019, 52, 14, 5217–5222. .它可以和芳烃（arene）反应，形成(arene)Cr(CO)3配合物。E. V. Sazonova;A. N. Artemov;V. I. Faerman;N. A. Aksenova;A. A. Timofeeva;Yu. A. Zaytseva;N. V. Somov;N. Yu. Grishina; (2021). Synthesis of (η6-arene)tricarbonylchromium derivatives of 1,4-dihydro-3,1-benzoxazines . Russian Chemical Bulletin, 70 (1). 

参考文献

Category:有机铬化合物
Category:羰基配合物
Category:氨配合物