六氟磷酸亚铊

六氟磷酸亚铊是一种无机化合物，化学式为TlPF6，它在200 K时以Fmm空间群结晶。它可由铊在低温和五氟化磷的无水氟化氢溶液反应，升温后结晶得到；Evgeny Goreshnik , Zoran Mazej. Single crystal structures of InPF6, InAsF6, TlPF6 and TlAsF6. Solid State Sciences, 2008. 10 (3). 或由六氟磷酸铵和氢氧化亚铊反应制得。Hans Bode, Günter Teufer. Die Kristallstruktur des Thalliumhexafluorophosphats. Zeitschrift fur anorganische und allgemeine Chemie. 1952. 268 (3). .

反应
六氟磷酸亚铊和[nBu4N][TCNE]或[TDAE][TCNE]反应，可以得到Tl[TCNE]或Tl2[TCNE]（其中TCNE为四氰基乙烯的阴离子）。Mitchell T. Johnson; et al. Synthesis and Reactivity of the TlI salts of [TCNE]·− and [TCNE]2−: The Structural Determination of TlI[TCNE] and [TDAE][TCNE]2 and Evidence for a Chelated [TCNE]·−. Chemistry A European Journal, 2000. 6 (10). .

它可以分解为氟化亚铊和五氟化磷。Adli S Kana'an; Carlos Gonzalez; Joseph K Kanamueller (1986). Equilibrium decomposition pressures of thallium(I) hexafluorophosphate. J. Chem. Thermodynamics, 18(3), 285–294. 
参考文献

Category:铊化合物
Category:六氟磷酸盐