4-氯甲苯

4-氯甲苯是一种有机化合物，化学式为C7H7Cl，它可由4-氯苯甲醛在催化下加氢还原制得。Wang, Shuguo; et al. Selective deoxygenation of carbonyl groups at room temperature and atmospheric hydrogen pressure over nitrogen-doped carbon supported Pd catalyst. Journal of Catalysis (2018), 368, 207-216. .

反应

4-氯甲苯和在碳酸铯存在下、钯配合物催化下反应，可以得到4-甲基-4'-甲氧基二苯胺。van der Westhuizen, Danielle; et al. Bulky, electron-rich, renewable: analogues of Beller's phosphine for cross-couplings。 Catalysis Science & Technology (2023), 13(23), 6733-6742. 

它在钯催化下可以被甲酸铵脱卤还原为甲苯。Ryu Nakao, Hakjune Rhee, and Yasuhiro Uozumi. Hydrogenation and Dehalogenation under Aqueous Conditions with an Amphiphilic-Polymer-Supported Nanopalladium Catalyst. Org. Lett. 2005, 7, 1, 163–165. .

参考文献

Category:对氯苯基化合物
Category:对甲苯基化合物