1-甲基-1,4,7,10-四氮杂环十二烷

1-甲基-1,4,7,10-四氮杂环十二烷是一种胺类有机物，化学式为C9H22N4。它可由1,4,7,10-四氮杂环十二烷在硅基保护下和碘甲烷反应，再在酸性条件下水解脱保护制得；Annaïg Roignant, Isabelle Gardinier, Hélène Bernard, Jean-Jacques Yaouanc and Henri Handel. Mono- and N1,N7-dialkylation of 1,4,7,10-tetraazacyclododecane via silicon protection. J. Chem. Soc., Chem. Commun., 1995, 1233-1234. .它也可由1,4,7,10-四氮杂环十二烷先后和乙二醛、碘甲烷和水合肼反应得到。Rodriguez-Rodriguez, Aurora; Regueiro-Figueroa, Martin; Esteban-Gomez, David; Rodriguez-Blas, Teresa; Patinec, Veronique; Tripier, Raphael; Tircso, Gyula; Carniato, Fabio; Botta, Mauro; Platas-Iglesias, Carlos. Definition of the Labile Capping Bond Effect in Lanthanide Complexes. Chemistry A European Journal. 2017. 23 (5): 1110-1117. .它可以和高氯酸镍在乙醇中反应，得到黄色的[Ni(C9H22N4)](ClO4)2。魏平荣; 金天柱; 韩玉真; 徐光宪; 马喆生. 1-甲基-1,4,7,10-四氮杂环十二烷镍配合物的晶体结构. 北京大学学报(自然科学版), 1993 (2). .

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Category:胺