十氯化五硅

十氯化五硅或十氯环戊硅烷是一种无机化合物，化学式为Si5Cl10，它是对水和空气敏感的晶体。它可由十苯基环戊硅烷和HCl反应制得，Hengge, E.; Kovar, D. Zur reaktion der silicium—phenyl-bindung mit HCl. Journal of Organometallic Chemistry (1977), 125(2), C29-C32. 三氯化铝可作为这一反应的催化剂。Lee, Dong Won; Park, Young-ae Whang; Han, Joon Soo; Yoo, Bok Ryul. Dephenylation of decaphenylcyclopentasilane with HCl catalyzed by aluminum chloride: facile synthetic route to cyclopentasilane. Bulletin of the Korean Chemical Society (2009), 30(10), 2443-2445. .它和二甲基锌反应，可以得到十甲基环戊硅烷。Hengge, E.; Schuster, H. G.; Peter, W. Eine neue darstellungsmethode für permethylierte cyclosilane。 Journal of Organometallic Chemistry (1980), 186(2), C45-C48. .它和双(三甲基硅基)氨基锂在庚烷中反应，可以得到双(三甲基硅基)氨基九氯环戊硅烷。Waltraud Gollner, Karin Renger, and Harald Stueger. Linear and Cyclic Polysilanes Containing the Bis(trimethylsilyl)amino Group: Synthesis, Reactions, and Spectroscopic Characterization. Inorg. Chem. 2003, 42, 15, 4579–4584. .

参考文献

Category:卤化硅
Category:氯硅烷