4-甲基苯硼酸新戊二醇酯

4-甲基苯硼酸新戊二醇酯是一种有机硼化合物，化学式为C12H17BO2，它是4-甲基苯硼酸和2,2-二甲基-1,3-丙二醇（新戊二醇）形成的酯。

合成与反应
它可由三(4-甲基苯基)锑、三氯化硼和新戊二醇反应制得，Yasuike, Shuji ; Nakata, Kazuhide; Qin, Weiwei; Matsumura, Mio; Kakusawa, Naoki; Kurita, Jyoji. Synthesis of arylboronates by boron-induced ipso-deantimonation of triarylstibanes with boron trihalides and its application in one-pot two-step transmetallation/cross-coupling reactions. Journal of Organometallic Chemistry, 2015. 788, 9-16. 或由4-甲基苯硼酸和新戊二醇在硫酸镁存在下反应得到。Tianhao Zhang; Itsuki Nohira; Naoto Chatani. Nickel-catalyzed Suzuki–Miyaura cross-coupling of C–F bonds. Org. Chem. Front., 2021,8, 3783-3787. .

它和N-溴代丁二酰亚胺、过氧化苯甲酰在四氯化碳中回流反应，可以得到4-(溴甲基)苯硼酸新戊二醇酯。Zhiqiang Lu, Xin Zhou, Sheng Hu, Xin Shu, Yuan Tian, and Jin Zhu. Interfacial Assembly of Nanoparticles with Fluorous-Tagged Organic Molecules. J. Phys. Chem. C 2010, 114, 32, 13546–13550. .
参考文献

Category:硼酸酯