氯化三(三苯基胂)合铑(I)

氯化三(三苯基胂)合铑(I)是一种配位化合物，化学式为RhCl(AsPh3)3，其中Ph表示苯基。它是氯化三(三苯基膦)合铑(I)的胂类似物。

它可由双(乙烯)氯化铑(I)二聚体和三苯基胂在热的甲醇中反应得到。J. T. Mague  and  G. Wilkinson. Tris(triphenylarsine)- and tris(triphenylstibine)-chlororhodium(I) complexes and their reactions with hydrogen, olefins, and other reagents. J. Chem. Soc. A, 1966, 1736-1740. .它和硫或硒反应，可以得到{RhE2Cl(AsPh3)}n（E=S，棕色；E=Se，棕黑色）。A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen. Disulfur and diselenium complexes of rhodium and iridium. Inorg. Chem. 1982, 21, 10, 3666–3681. .它和羰基硫反应，得到羰基配合物：S. K. Tewari &K. K. Pandey. Reactions of Carbonyl Sulfide and Carbon Disulfide with Rhodium Complexes, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 1988, 19 (6). 545-556. .
 RhCl(AsPh3)3 + COS → Rh(CO)Cl(AsPh3)2 + SAsPh3
参考文献

Category:胂配合物
Category:铑化合物