硫氰酸二(吡啶)三苯基膦亚铜

硫氰酸二(吡啶)三苯基膦亚铜是一种配位化合物，化学式为Cu(NCS)(py)2(PPh)3，其中py为吡啶，Ph为苯基。它可由[Cu(NCS)(PPh3)]2（或CuNCS和PPh3Fabio Marchetti, Corrado Di Nicola, Riccardo Pettinari, Ivan Timokhin, and Claudio Pettinari. Synthesis of a Photoluminescent and Triboluminescent Copper(I) Compound: An Experiment for an Advanced Inorganic Chemistry Laboratory. J. Chem. Educ. 2012, 89, 5, 652–655. ）在热吡啶中结晶得到。Claudio Pettinari, Corrado di Nicola, Fabio Marchetti, Riccardo Pettinari, Brian W. Skelton, Neil Somers, Allan H. White, Ward T. Robinson, Michele R. Chierotti, Roberto Gobetto, Carlo Nervi. Synthesis, Characterization, Spectroscopic and Photophysical Properties of New [Cu(NCS){(L-N)2 or (L′-NN)}(PPh3)] Complexes (L-N, L′-NN = Aromatic Nitrogen Base). European Journal of Inorganic Chemistry. 2008. 12. 1974-1984. .

它可以以单斜晶系P21空间群结晶，晶胞参数a=9.44，b=15.19，c=10.24 Å，β=166.95°。它具有光致发光和摩擦发光特性。Anıl İncel, Canan Varlikli, Colin D. McMillen, and Mustafa M. Demir. Triboluminescent Electrospun Mats with Blue-Green Emission under Mechanical Force. J. Phys. Chem. C 2017, 121, 21, 11709–11716. 

参考文献

Category:三苯基膦配合物
Category:硫氰酸盐
Category:铜配合物
Category:吡啶配合物