三氟甲磺酸铥

三氟甲磺酸铥是一种无机化合物，化学式为Tm(CF3SO3)3。它可由氧化铥和三氟甲磺酸反应制得，从溶液中可以结晶出九水合物。Congting SunOrcid, Xiaoyan Chen, and Dongfeng Xue. Hydrogen Bonding Dependent Mesoscale Framework in Crystalline Ln(H2O)9(CF3SO3)3. Cryst. Growth Des. 2017, 17, 5, 2631–2638. .从九水合物晶体占位因子（occupancy factor）的精修得出，每个Tm3+的水合数为8.84(5)。Abbasi, Alireza; Lindqvist-Reis, Patric; Eriksson, Lars; Sandstroem, Dick; Lidin, Sven; Persson, Ingmar; Sandstroem, Magnus. Highly Hydrated Cations: Deficiency, Mobility, and Coordination of Water in Crystalline Nonahydrated Scandium(III), Yttrium(III), and Lanthanoid(III) Trifluoromethanesulfonates. Chemistry - A European Journal (2005), 11(14), 4065-4077. .它和石墨化钾在dme中反应，可以得到二价铥的化合物[Tm(CF3SO3)2(dme)2]n。Xemard, Mathieu; Jaoul, Arnaud; Cordier, Marie; Molton, Florian; Cador, Olivier ; Le Guennic, Boris ; Duboc, Carole; Maury, Olivier; Clavaguera, Carine; Nocton, Gregory. Divalent Thulium Triflate: A Structural and Spectroscopic Study. Angewandte Chemie, International Edition (2017), 56(15), 4266-4271. .

参考文献

Category:铥化合物
Category:三氟甲磺酸盐