NU-1000

NU-1000是由锆和1,3,6,8-四(4-羧基苯基)芘（H4L）构成的介孔金属有机框架材料，化学式为C88H60O32Zr6，最初于美国西北大学（Northwestern University）合成，它的Zr6簇具有八面体结构，簇的三角面与μ3-氧或μ3-羟基相连。Design and Advanced Manufacturing of NU-1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications. Small, 2023. 2306353. .

合成
NU-1000可由四氯化锆、苯甲酸和H4L在120 °C于DMF中反应得到。Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies. J. Am. Chem. Soc. 2013, 135, 45, 16801–16804. .

相关化合物
NU-1000的异构体ISO-NU-1000可由四氯化锆和4,5,9,10-四(4-羧基苯基)芘在甲酸存在下反应得到，它的孔径和NU-1000相比有所变化。Isomer of NU-1000 with a Blocking c-pore Exhibits High Water–Vapor Uptake Capacity and Greatly Enhanced Cycle Stability. J. Am. Chem. Soc. 2023, 145, 7, 4150–4157. .

参考文献

Category:锆化合物
Category:金属有机框架材料