二氯化二(2,6-二均三甲苯基苯基)二锡

二氯化二(2,6-二均三甲苯基苯基)二锡是一种有机化合物，化学式为C48H50Cl2Sn2，或写作[Sn(Cl)(C6H3Mes2)]2，其中Mes表示2,4,6-三甲苯基。它可由2,6-二均三甲苯基苯基锂在甲苯中和氯化亚锡反应制得。Simons, Richard S.; Pu, Lihung; Olmstead, Marilyn M.; Power, Philip P. Synthesis and Characterization of the Monomeric Diaryls M{C6H3-2,6-Mes2}2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me3C6H2-) and Dimeric Aryl-Metal Chlorides [M(Cl){C6H3-2,6-Mes2}]2 (M = Ge or Sn). Organometallics (1997), 16(9), 1920-1925. .它和金属钾在四氢呋喃中反应，可以得到紫色的Sn8(C6H3Mes2)4。Eichler, Barrett E.; Power, Philip P. Synthesis and characterization of [Sn8(2,6-Mes2C6H3)4] (Mes = 2,4,6-Me3C6H2): a Main group metal cluster with a unique structure. Angewandte Chemie, International Edition (2001), 40(4), 796-797. 它和Cp*(IPr)Co反应，可以得到深紫色的Sn4(C6H3Mes2)4。Rex C. Handford, T. Alex Wheeler, Prof. T. Don Tilley. Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. Chemistry - A European Journal (2020), 26 (28), 6126-6129. . Note: Cp* = η5-C5Me5, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene.
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Category:有机锡化合物
Category:均三甲苯基化合物