二氯化三甲基钽

二氯化三甲基钽是一种，化学式为Ta(CH3)3Cl2，它是浅黄色晶体，对空气和水十分敏感，可以在室温真空下升华。它是首个被报道的钽的σ键，于1964年由Gordon L. Juvinall合成。Juvinall, Gordon L. (1964). "σ-Bonded Alkyl Compounds of Niobium and Tantalum. Trimethyldichloroniobium and Trimethyldichlorotantalum". Journal of the American Chemical Society. 86 (19): 4202–4203. . .它可以和下图所示二氢吖啶二胺配体反应：Jack Underhill, Eric S. Yang, Till Schmidt-Räntsch, Dr. William K. Myers, Jose M. Goicoechea, Josh Abbenseth. Dioxygen Splitting by a Tantalum(V) Complex Ligated by a Rigid, Redox Non-Innocent Pincer Ligand. Chemistry A European Journal. 2023. 29 (5). e202203266. .
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参考文献

Category:甲基配合物
Category:有机钽化合物