4-氯二苯乙炔

4-氯二苯乙炔是一种有机氯化合物，化学式为C14H9Cl。它可由苯乙炔和4-氯溴苯（或4-氯碘苯）在乙酸钠存在下、钯催化下反应得到。Li, Xing; Gong, Xiaolei; Li, Zhipeng; Chang, Honghong; Gao, Wenchao; Wei, Wenlong. Ligand- and copper-free Sonogashira and Heck couplings of (Het)aryl chlorides and bromides catalyzed by palladium nanoparticles supported on in situ generated Al(OH)3. RSC Advances (2017), 7(5), 2475-2479. .Kim, Miran; Kang, Hyuntae; Park, Kang Hyun. Pd nanoparticles supported on Fe3O4@amine-functionalized graphene composite and catalytic performance in Sonogashira cross-coupling reactions. Catalysis Communications, 2015. 72: 150-155. .它和四苯基环戊二烯酮在二苯醚中反应，可以得到4-氯六苯基苯。Kojima, Tatsuo; Hiraoka, Shuichi. Selective Alternate Derivatization of the Hexaphenylbenzene Framework through a Thermodynamically Controlled Halogen Dance. Org. Lett. 2014. 16 (3): 1024-1027. .

参考文献

Category:苯乙炔
Category:对氯苯基化合物