PCN-224

PCN-224是锆和5,10,15,20-四(4-羧基苯基)卟啉（TCPP）形成的金属有机框架（MOF）之一，其结构可以表示为[Zr6O4(OH)4][TCPP]1.5，其无序变体表示为dPCN-224。它可由四氯化锆、TCPP和苯甲酸在DMF中反应得到。Dawei Feng, Wan-Chun Chung, Zhangwen Wei, Zhi-Yuan Gu, Hai-Long Jiang, Ying-Pin Chen, Donald J. Darensbourg, and Hong-Cai Zhou. Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination. J. Am. Chem. Soc. 2013, 135, 45, 17105–17110. .它的理论表面积为2985 m2/g。Understanding the structure-dependent adsorption behavior of four zirconium-based porphyrinic MOFs for the removal of pharmaceuticals. Microporous and Mesoporous Materials. 2024. .
参考文献

Category:锆化合物
Category:卟啉
Category:金属有机框架材料