四氰合铜(I)酸钾

四氰合铜(I)酸钾是一种配位化合物，化学式为K3Cu(CN)4。它可由氰化钾和氰化亚铜反应制得，在50%的甲醇水溶液中可以结晶。Llewellyn H. Jones. Vibrational Spectrum and Structure of Metal‐Cyanide Complexes in the Solid State. IV. K3Cu(CN)4. J. Chem. Phys. 29, 463–466 (1958). 它在水溶液中和臭氧反应，可以得到氢氧化铜和氰酸铜。Hyksova, D.; Sauman, Z.; Valtr, Z. Ozonolysis of copper(I) and nickel (II) cyanocompplexes. Collection of Czechoslovak Chemical Communications (1972), 37(5), 1637-1644.它可用于合成CuCN基的配位聚合物。A new nanosized host-guest supramolecular coordination polymer based on copper cyanide network and 1,7-diaminoheptane: Comparative structure study and catalytic activity. Journal of Molecular Structure, 2021. 130915. .
参考文献

Category:铜配合物
Category:氰配合物
Category:一价铜化合物