七磷化三铷

七磷化三铷是一种无机化合物，化学式为Rb3P7，它由笼状的P73−阴离子和Rb+构成。Bolduan, F.; Hoenle, W.; Hochheimer, H. D.; Henkel, W. Temperature and High Pressure Raman Study of M3P7 (M = Li, Na, K, Rb, Cs) Compounds. Physica Status Solidi B: Basic Research (1985), 132(1), 41-50. .它可由铷和红磷按化学计量比在高温反应制得。K. Tentschev; E. Gmelin; W. Hönle (1985). Phase transitions crystalline to plastic-crystalline and the specific heat of M3P7 compounds (M = Li, Na, K, Rb, Cs). Thermochimica Acta, 85, 151–154. 它和四甲基碘化铵在液氨中反应，可以得到[(CH3)4N]2RbP7(NH3)。Korber, Nikolaus; von Schnering, Hans Georg. Alkali metal polyphosphides in low dimensions. Preparation and structure of [Me4N]2RbP7(NH3) and [Et4N]Cs2P11. Chemische Berichte (1996), 129(2), 155-159. 
参考文献

Category:铷化合物
Category:磷化物