二铋化钯

二铋化钯是一种金属间化合物，化学式为PdBi2，或写作Bi2Pd。它可以硝酸铋和硝酸钯为原料，在PVP存在下于EG中反应得到。General synthesis and atomic arrangement identification of ordered Bi–Pd intermetallics with tunable electrocatalytic CO2 reduction selectivity. Nature Communications volume 15, 1573 (2024). .它是一种拓扑绝缘体，存在α相和β相。Superconducting Properties of Pd1–xPtxBi2 over a Wide Pressure Range. J. Phys. Chem. C 2022, 126, 23, 9948–9955. .它可以经电化学反应转化为Pd3Bi。Ordered Intermetallic Pd3Bi Prepared by an Electrochemically Induced Phase Transformation for Oxygen Reduction Electrocatalysis. ACS Nano 2019, 13, 9, 10818–10825. .它和溴化铋加热反应，可以得到Bi14PdBr16。A One-Dimensional Metal Embedded in Salt Matrices: Synthesis, Modulated Crystal Structures, Electrical Conductivity, and Chemical Bonding of 1∞[PdBi6][(Bi,Sn)1−δBr5−δ']. Z. Anorg. Allg. Chem. 2009, 635, 1979–1985. 它在自然界中以和的形式存在。 Michenerite and froodite, palladium bismuthide minerals [Ontario]. The Canadian Mineralogist (1958) 6 (2): 200–209.

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Category:铋化物
Category:钯化合物