碘酸钚(IV)

碘酸钚(IV)是一种无机化合物，化学式为Pu(IO3)4，它在540 °C以上分解为二氧化钚。它可以在硝酸钚(IV)和碘酸反应中生成，但这种方法不能得到纯净的产物；Dawson, J. K.; Elliott, R. M. The thermogravimetry of some plutonium compounds. Atomic Energy Research Estab. (Gt. Brit.), 1957.另一种制备方法是硝酸钚或氯化钚和碘酸钾及稀硝酸反应。Sklyarenko, I. S.; Chubukova, T. M. Thermogravimetry in analytical chemistry. IV. Thermogravimetric study of plutonium (IV) iodate. Zhurnal Analiticheskoi Khimii, 1963. 18 (4): 492-495. .它可以以四方晶系结晶，空间群P42/n。Travis H. Bray, Jie Ling, Eun Sang Choi, James S. Brooks, James V. Beitz, Richard E. Sykora, Richard G. Haire, David M. Stanbury, and Thomas E. Albrecht-Schmitt. Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel. Inorg. Chem. 2007, 46, 9, 3663–3668. 

参考文献

Category:钚化合物
Category:碘酸盐