1-金刚烷硫醇

1-金刚烷硫醇是一种有机硫化合物，化学式为C10H15SH。它可由1-溴金刚烷、硫脲、氢溴酸和冰乙酸回流反应，再经氢氧化钠水解、盐酸酸化得到；Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer. Organic & Biomolecular Chemistry, 2015. 或由1-金刚烷醇和劳森试剂反应制得。S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides. J. Org. Chem. 2023, 88, 17, 12311–12318. 它可以被高锰酸钾氧化为二(1-金刚烷基)二硫。Ground solid permanganate oxidative coupling of thiols into symmetrical/unsymmetrical disulfides: selective and improved process. Journal of Sulfur Chemistry, 2022. 43 (6). 

参考文献

Category:金刚烷基化合物
Category:硫醇