二叔丁基碳二亚胺

二叔丁基碳二亚胺是一种有机化合物，化学式为C9H18N2，它可以N,N'-二叔丁基硫脲为原料合成得到。Kim, Sunggak; Yi, Kyu Yang. 1,1'-Thiocarbonyldi-2,2'-pyridone. A new useful reagent for functional group conversions under essentially neutral conditions. Journal of Organic Chemistry, 1986. .

反应

二叔丁基碳二亚胺在三氟甲磺酸锌Li, Dongzhen; Guang, Jie; Zhang, Wen-Xiong; Wang, Yang; Xi, Zhenfeng. Zn(OTf)2-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species. Organic & Biomolecular Chemistry, 2010. .或三甲基铝Zhang, Wen-Xiong; Li, Dongzhen; Wang, Zitao; Xi, Zhenfeng. Alkyl Aluminum-Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines. Organometallics, 2009. .催化下，可以和苯胺反应，生成N,N'-二叔丁基-N''-苯基胍。它和草酰氯在二氯甲烷中反应，可以得到2,2-二氯-1,3-二叔丁基-4,5-咪唑烷二酮。Moerdyk, Jonathan P.; Bielawski, Christopher W. Reductive generation of stable, five-membered N,N'-diamidocarbenes. Chemical Communications, 2014. .

参考文献

Category:叔丁基化合物
Category:碳二亚胺