六氰合钴(III)酸铊(I)

六氰合钴(III)酸铊(I)是一种配位化合物，化学式为Tl3[Co(CN)6]，它具有f.c.c.晶格，空间群Fm3m。Dragulescu, C.; Tribunescu, P. Structure of the simple and mixed cobalticyanides of silver and thallium. Rev. Chim. Minerale, 1965. 2 (1): 119-125.它可由六氰合钴(III)酸和碳酸亚铊反应得到，P. S. Braterman,   P. B. P. Phipps  and  R. J. P. Williams. 1147. Charge-transfer phenomena in some inorganic complexes. Part I. Electronic conduction in some complex cyanides. J. Chem. Soc., 1965, 6164-6169. 它也可由氰化钴和溶液反应，再对溶液加热得到：Sianokomplekse. South African Journal of Chemistry, 1966. 19 (2). 
 Co(CN)2 + 4 TlCN → Tl4Co(CN)6 
 2 Tl4Co(CN)6 + 2 H2O → 2 Tl3Co(CN)6 + 2 TlOH + H2↑
参考文献

Category:铊化合物
Category:钴氰酸盐