苯并［a］咔唑

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苯并[a]咔唑是一种稠杂环有机物，化学式为C16H11N。有多种方法可以合成该化合物Wu, F., Huang, W., Yiliqi, Yang, J., & Gu, Y. (2018). Relay Catalysis of Bismuth Trichloride and Byproduct Hydrogen Bromide Enables the Synthesis of Carbazole and Benzo[α]carbazoles from Indoles and α-Bromoacetaldehyde Acetals. Advanced Synthesis & Catalysis. . Supporting Information.，例如，它可由N-(2-溴苯基)-1-萘胺和叔丁醇钾在液氨中光照反应制得；J. Org. Chem. 2009, 74, 12, 4490–4498. 2-(1-萘氨基)苯甲酸在乙酸钯、邻菲啰啉和碳酸银催化下于1,4-二氧六环中脱羧关环，也能得到该化合物。Pd-Catalyzed Decarboxylative Cross-Coupling of N-Aryl Anthranilic Acids to Access Carbazoles: Gram Scale Total Synthesis of Anti- Cancer Drug Ellipticine. Asian Journal of Organic Chemistry. 2023. .它和NBS反应，可以得到5-溴苯并[a]咔唑。Shin, Chang Hwan; Kim, Gong Gyeom; Heo, Jeong O; Chun, Min Seung; Kim, Dong Heon. Heterocyclic compounds as organic light-emitting device materials. 2015. KR2015027720.
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Category:咔唑