砷酸三(三甲基硅酯)

砷酸三(三甲基硅酯)是一种易水解的化合物，化学式为[(CH3)3SiO]3AsO。它可由砷酸银和三甲基氯硅烷在惰性有机溶剂中反应得到。Schmidt, Max; Schmidbaur, H. Tris(trimethylsilyl)orthoarsenate and orthophosphate. Angewandte Chemie (1959), 71, 553.它不如砷酸三(三乙基硅酯)稳定，容易缩合为多砷酸酯（如焦砷酸四(三甲基硅酯)）和六甲基二硅氧烷。Baier, Michael; Bissinger, Peter; Schmidbaur, Hubert. Arsenosiloxanes: formation and decomposition of trialkylsilyl arsenates and arsenites. Chemische Berichte (1992), 125(2), 373-376

参考文献

拓展阅读
 Silylated aminoarsenates with novel and conventional structures. 1993. 12 (9). .
 Germanosiloxanes. VI. Arsenic and selenic acid esters of trimethylsilanol and trimethylgermanol. Chemische Berichte, 1961. 94: 2451-2456. .

Category:三甲基硅氧基化合物
Category:砷酸酯