3,3'-联吡啶

3,3'-联吡啶是一种有机化合物，化学式为C10H8N2，它是联吡啶的同分异构体之一。它可由3-溴吡啶和3-三丁基锡基吡啶在四(三苯基膦)钯催化下反应制得。Yamamoto, Y., Azuma, Y., & Mitoh, H. (1986). General Method for Synthesis of Bipyridines: Palladium Catalyzed Cross-coupling Reaction of Trimethylstannyl-pyridines with Bromopyridines. Synthesis, 1986(07), 564–565. 它和五氟化铌、叠氮基三甲基硅烷在乙腈中于反应，可以得到[Nb(N3)5]2(3,3'-bipy)；五氟化钽的反应与之类似。Coordination Adducts of Niobium(V) and Tantalum(V) Azide M(N3)5 (M=Nb, Ta) with Nitrogen Donor Ligands and their Self-Ionization. Angew Chem Int Ed. 2014. .

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Category:联吡啶