镓宾

镓宾是一类电中性及一价镓的化合物，它们是稳定卡宾或末端的类似物。常见的配体有β-二亚胺、Pincer配体及过渡金属配体。

β-二亚胺镓宾的合成与反应如下：Zhong, Mingdong; Sinhababu, Soumen; Roesky, Herbert W. (2020). "The unique β-diketiminate ligand in aluminum( i ) and gallium( i ) chemistry". Dalton Transactions. 49 (5): 1351–1364. 
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镓宾可以与异氰酸酯发生[1+2]环加成反应，裂解C=O和C=N键。Dodonov, Vladimir A.; Chen, Weixing; Zhao, Yanxia; Skatova, Alexandra A.; Roesky, Peter W.; Wu, Biao; Yang, Xiao‐Juan; Fedushkin, Igor L. (2019-06-21). "Gallium "Shears" for C=N and C=O Bonds of Isocyanates". Chemistry – A European Journal. 25 (35): 8259–8267. 
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参考文献

Category:镓化合物