六氢合钌(II)酸镁

六氢合钌(II)酸镁是一种配位氢化物，化学式为Mg2[RuH6]，具有f.c.c.K2PtCl6结构。Huang, B., Bonhomme, F., Selvam, P., Yvon, K., & Fischer, P. (1991). New ternary and quaternary metal hydrides with K2PtCl6-type structures. Journal of the Less Common Metals, 171(2), 301–311. 它可由氢化镁（或镁）、钌和氢气在加热、加压下反应制得。Kritikos, M., & Nore´us, D. (1991). Synthesis and characterization of ternary alkaline-earth transition-metal hydrides containing octahedral [Ru(II)H6]4− and [Os(II)H6]4− complexes. Journal of Solid State Chemistry, 93(1), 256–262. 其氘代化合物Mg2[RuD6]也是已知的。

参考文献

拓展阅读
 Orgaz, E., & Gupta, M. (1993). Trends in the Electronic Structure of Intermetallic Hydrides: M2M'H6 (M = Mg, Ca, Sr, M’ = Fe, Ru, Os). Zeitschrift Für Physikalische Chemie, 181 (Part 1-2), 1–7. 
Category:配位氢化物
Category:钌化合物
Category:镁化合物