六氢合锇(II)酸镁

六氢合锇(II)酸镁是一种活泼的配位氢化物，在空气中可自燃，化学式为Mg2[OsH6]，具有K2PtCl6结构。Huang, B., Bonhomme, F., Selvam, P., Yvon, K., & Fischer, P. (1991). New ternary and quaternary metal hydrides with K2PtCl6-type structures. Journal of the Less Common Metals, 171(2), 301–311. 它可由氢化镁（或镁）、锇和氢气在加热、加压下反应制得。Kritikos, M., & Nore´us, D. (1991). Synthesis and characterization of ternary alkaline-earth transition-metal hydrides containing octahedral [Ru(II)H6]4− and [Os(II)H6]4− complexes. Journal of Solid State Chemistry, 93(1), 256–262. 其氘代化合物Mg2[OsD6]被用于中子衍射表征结构，以确定氢的位置。Kritikos, M., Noréus, D., Bogdanović, B., & Wilczok, U. (1990). Mg2OsH6 — A new ternary hydride with the K2PtCl6-type structure. Journal of the Less Common Metals, 161(2), 337–340. 

参考文献

Category:配位氢化物
Category:锇化合物
Category:锇化合物