氟化物亚硒酸盐

氟化物亚硒酸盐是一类，它同时含有氟离子（F-）和亚硒酸根（SeO32-）离子。

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名称化学式SeO3:F分子量晶系空间群晶胞参数（Å）晶胞体积密度光学性质参考文献氟化亚硒酸钪ScSeO3F1:1triclinicP <13−173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=23.830monoclinicP21/m >13a=4.0643 b =6.6109 c=6.32.35 β=93.298° Z=2氟化四亚硒酸三氧三钛三钠Na3Ti3O3(SeO3)4F4:1hexagonalP63a =12.8439 c =5.2339SHG 6 × KDP二氟化亚硒酸二锰Mn2SeO3F21:2274.83orthorhombicPnmaa = 7.50848 b = 10.350 and c = 5.47697 Z=4pink氟化亚硒酸铁FeSeO3F1:1201.81monoclinicP21/na=4.9559 b=5.2023 c=12.040 β=97.87 Z=4307.504.359yellow三氟化二亚硒酸二铁铵NH4Fe2F3(SeO3)22:3六氟化四亚硒酸四铁哌嗪鎓[C4N2H12]Fe4F6(SeO3)42:3933.40monoclinicC2/ca=15.168 b=7.3973 c=16.127 β=90.044 Z=51928.93.14brown六氟化四亚硒酸四铁二乙烯三铵[C4N3H14]Fe4F6(SeO3)42:3二氟化亚硒酸二钴Co2SeO3F21:2282.82orthorhombicPnmaa = 7.2655 b = 10.001 c = 5.3564 Z=4389.224.826粉色二氟化亚硒酸二镍Ni2(SeO3)F21:2282.3orthorhombicPnmaa=7.1727 b=9.9377 c=5.2364373.25黄色二氟化亚硒酸二铜Cu2(SeO3)F21:2292.05orthorhombicPnmaa = 7.066 b = 9.590 c = 5.563 Z=4377.05.146浅绿色二氟化亚硒酸二锌Zn2(SeO3)F21:2295.70orthorhombicPnmaa=7.276 b=10.042 c=5.256 Z=4384.05.114无色六氟化亚硒酸二镓三乙烯二铵C6H14N2Ga2F6SeO31:6494.59MonoclinicP21/ca=12.616 b=7.2700 c=13.605 β=104.746 Z=41206.82.722colourless三氟化亚硒酸镓乙二铵C2H10N2GaF3SeO31:3315.80monoclinicP21/ca=9.1107 b=8.0382 c=10.8302 β=90.045 Z=4793.12.2355无色一水合氟化亚硒酸草酸哌嗪鎓H2pipGaFSeO3[C2O4]H2O1:1409.87triclinicPa=6.377 b=9.2820 c=11.4112 α=66.53 β=77.44 γ=71.89585.472.325colourless(C4H15N3)2Ga4F2(SeO3)6(C2O4)·4H2O6:21467.11triclinicPa=8.9941 b=9.4963 c=11.2959 α=77.13 β=68.073 γ=83.776 Z=1872.172.793colourless亚硒酸氟化钒酰锶Sr(VO2F)(SeO3)316.52orthorhombicPbcaa=9.7816 b=8.0278 c=12.927 Z=81015.074.142yellow氟化亚硒酸钇YSeO3F1:1monoclinicP21/c <319a=6.5765 b=6.8971 c=7.1728 β=99.036 Z=4monoclincP 21/m >319600° a=6.5840 b=6.9809 c=4.3434 β =95.032 Z=23.922氟化四亚硒酸三氧三钛三银Ag3Ti3O3(SeO3)4F1042.15hexagonalP63a=12.8975 c=5.2180 Z=2751.704.604colourless SHG 2×KDP二氟化二亚硒酸锆二银Ag2ZrF2(SeO3)2598.88orthorhombicCmcaa=7.3640 b=31.451 c=6.27191452.65.477colopurless二氟化亚硒酸二镉Cd2(SeO3)F21:2389.76orthorhombicPnmaa=7.803 b=10.566 c=5.729 Z=4472.45.480无色三氟化亚硒酸乙二铵C2H10N2InF3SeO3360.90monoclinicP21/ca=9.3066 b=8.3012 c=11.2923 Z=4871.682.750colourless六氟化二亚硒酸三钪铯CsSc3F6[SeO3]22:6trigonalP3m1a  = 5.6534 c  = 10.6987 Z  = 1Cs(TiOF)3(SeO3)22:3635.53hexagonalP63mca=7.2420 c=11.8152 Z=2536.653.933Colourless SHG 5xKDP六氟化二亚硒酸三铁铯CsFe3(SeO3)2F62:6trigonalPm1a=5.459 c=10.537 Z=1271.9cyanBa(VO2F)(SeO3)366.24orthorhombicPbcaa=10.0539 b=8.3967 c=13.1741112.184.375yellow氟化亚硒酸镧LaSeO3F1:1monoclinicP21/ca = 18.198 b = 7.1575 c = 8.464 β = 96.89 Z = 12氟化亚硒酸铈CeSeO3F1:1六氟化二亚硒酸硒酸四镨Pr4(SeO3)2(SeO4)F62:6monoclinicC2/ca = 22.305 b = 7.1054 c = 8.356 β = 98.05° Z = 4浅绿色氟化四亚硒酸三镨Pr3F[SeO3]4浅绿色Pr5F[SiO4]2[SeO3]33:1triclinicPa  = 7.0114 b  = 9.8268 c  = 12.8679 α  = 70.552 β  = 76.904 γ  = 69.417° Z  = 25.511pale green氟化四亚硒酸三钕Nd3(SeO3)4FhexagonalP63mca=10.515  c=7.1211氟化四亚硒酸三钐Sm3(SeO3)4FhexagonalP63mca=10.474 c=7.0224氟化四亚硒酸三钆Gd3(SeO3)4F4:1hexagonalP63mca = 10.443 b = 6.9432 Z=2氟化四亚硒酸三镝Dy3(SeO3)4F4:11014.34hexagonalP63mca=10.360 c=6.8647 Z=2氟化亚硒酸钬HoSeO3F1:1monoclinicP21/ca=6.5784 b=6.8873 c=7.1825 β =99.213 Z=46.43Ho3F[SeO3]44:1hexagonalP63mca  = 10.3024 c  = 6.8037 Z  = 2氟化亚硒酸铒ErSeO3F1:1monoclinicP21/ca=6.5553 b=6.8741 c=7.1516 β =99.020 Z=46.54Er3F[SiO4][SeO3]22:1orthorhombicPnnaa  = 5.8692 b  = 15.2931 c  = 10.2967 Z  = 4pink氟化亚硒酸铥TmSeO3F1:1monoclinicP21/ca=6.5342 b=68607 c=7.1213 β =98,828 Z=46.63氟化亚硒酸镱YbSeO3F1:1monoclinicP21/ca=6.5146 b=6.8475 c=7.0924 β =98.637 Z=46.77氟化亚硒酸镥LuF[SeO3]1:1monoclinicP21/c−173°C: a=6.4839 b=6.8128 c=7.0581 β=98.657 Z=4308.236.916triclinicPa=6.4486 b=6.8441 c=4.2798 α=94.063 β=98.657 γ=91.895 Z=2187.045.698monoclinicP21/m173°C: a=6.4734 b=6.8702 c=4.2843 β=95.602 Z=2189.635.621氟化四亚硒酸三镥Lu3F(SeO3)44:11051.75trigonalP63a=9.883 c=7.066 Z=2597.75.844无色，SHG 2.5×KDP氟化亚硒酸钒酰铅PbVO2(SeO3)F1:1436.09orthorhombicPbcaa=9.812 b=8.147 c=13.026 Z=81041.35.563黄色氟化硝酸亚硒酸铅镉PbCdF(SeO3)(NO3)1:1orthorhombicPca21a=11.121 b=10.366 c=5.3950 Z=4621.95.634SHG 2.6×KDP 带隙 4.42 eV氟化亚硒酸铋BiFSeO31:1354.94orthorhombicPca21a=6.6774 b=6.8872 c=7.4702 Z=4343.546.862无色， SHG 13.5×KDP氟化亚硒酸焦亚硒酸三铋Bi3(SeO3)3(Se2O5)F3:1monoclinicF21SHG 3×KDP五氟化亚硒酸二铋钾KBi2SeO3F51:5679.02orthorhombicPbcma=4.553 b=17.80 c=8.80 Z=4712.96.326white band gap 4.08 eV五氟化亚硒酸二铋铷RbBi2SeO3F51:5725.39TriclinicPa=8.842 b=8.917 c=9.63 α=88.28 β=89.82 γ=89.76 Z=4758.96.349白色，band gap 4.18 eVRbBi(SeO3)F21:2459.41orthorhombicPnmaa=13.251 b=6.073 c=6.780 Z=4545.6Bi4TiO2F4(SeO3)44:41499.66monoclinicP21/ca=7.0237 b=6.6824 c=17.3240 β=106.637 Z=2779.076.393无色Bi4NbO3F3(SeO3)44:31541.67monoclinicP21/ca=7.0448 b=6.6814 c=17.4051 β=106.931 Z=2783.736.533colourlessBi4TeO4F2(TeO3)2(SeO3)22:21670.64monoclinicP21/ca=7.0304 b=6.6782 c=17.355 β=106.155 Z=2782.667.089colourlessBi2F2(MoO4)(SeO3)1:2742.86monoclinicP21/ca=7.1005 b=9.660 c=12.972 β=12.091 Z=4753.826.546无色Bi2ZrO2F2(SeO3)22:2833.10triclinicPa=5.8047 b=6.3469 c=6.7419 α=77.665 β=71.365 γ=72.795 Z=1222.876.207无色氟化二亚硒酸铋铅PbBi(SeO3)2F2:1orthorhombicPca21a=12.9672 b=4.5022 c=11.8221SHG 10.5×KDP; band gap 3.75 eV

 参考文献 

Category:亚硒酸盐
Category:氟化物
Category:混合阴离子化合物