双环［2.2.2］辛烯

双环[2.2.2]辛烯是一种有机化合物，化学式为C8H12。它可以1,3-环己二烯为原料，经N-双环[2.2.2]辛亚基对甲苯磺酰肼中间体制得。它和溴化氢在乙酸中反应，可以得到2-溴双环[2.2.2]辛烷。Germain, J. E.; Blanchard, M. Isomerization of bicyclic olefins C8H12 on a silicophosphoric catalyst. Bulletin de la Societe Chimique de France, 1960: 473-481.它可以被氢气或肼还原为双环[2.2.2]辛烷。Brockway, Nolan M. Reactions of carbethoxycarbene with carbon-halogen bonds. Polar addition of deuterium bromide to bicyclo[2.2.2]-octene [Dissertation]. 1970. Univ. Oklahoma.

参考文献

Category:环烯烃
Category:双环化合物