溴化锫

溴化锫是锫的溴化物，化学式 BkBr3。

 结构 
溴化锫在低温下是PuBr3结构的，为正交晶系，晶格参数 a = 403 pm、b = 1271 pm 和c = 912 pm。在高温下，溴化锫呈AlCl3结构，为单斜晶系，晶格参数 a = 723 pm、b = 1253 pm、c = 683 pm 和β = 110.6°。John H. Burns, J. R. Peterson, J. N. Stevenson: Crystallographic Studies of some Transuranic Trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3, in: J. Inorg. Nucl. Chem., 1975, 37 (3), S. 743–749 ().J. P. Young, R. G. Haire, J. R. Peterson, D. D. Ensor, R. L. Fellows: Chemical Consequences of Radioactive Decay. 1. Study of 249Cf Ingrowth into Crystalline 249BkBr3: A New Crystalline Phase of CfBr3, in: Inorg. Chem., 1980, 19 (8), S. 2209–2212 ().D. Cohen, S. Fried, S. Siegel, B. Tani: The preparation and crystal structure of some berkelium compounds, in: Inorg. Nucl. Chem. Lett., 1968, 4 (5), S. 257–260 ().J. R. Peterson, D. E. Hobart: The Chemistry of Berkelium, in: Harry Julius Emeleus (Hrsg.): Advances in Inorganic Chemistry and Radiochemistry, Volume 28, Academic Press, 1984, ISBN 0-12023628-1, S. 29–64 (), hier: S. 52–53 (.

 参考资料

 扩展阅读
 David E. Hobart, Joseph R. Peterson: Berkelium , in: Lester R. Morss, Norman M. Edelstein, Jean Fuger (Hrsg.): The Chemistry of the Actinide and Transactinide Elements, Springer, Dordrecht 2006; ISBN 1-4020-3555-1, S. 1444–1498 ().

Category:锫化合物
Category:溴化物