乙酰丙酮钕

乙酰丙酮钕是一种配位化合物，化学式为Nd(C5H7O2)3，或简写为Nd(acac)3，它的不稳定常数（logYn）分别为2.89、4.15和5.26（对应n=1, 2, 3）。它可由三烷氧基钕和乙酰丙酮反应制得，Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. .或通过金属钕在乙酰丙酮中电解得到。Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.它的二水合物和羰基铼配合物Re(CO)3X(4,4'-bipy)（X=Cl, Br）反应，可以得到Re(CO)3X(4,4'-bipy)Nd(acac)3。Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re+) and heteronuclear (Re+-Ln3+) tricarbonyl-halo complexes. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. .

参考文献

Category:钕化合物
Category:乙酰丙酮配合物