四硫酸根合二铑(II)酸钠

四硫酸根合二铑(II)酸钠是一种配位化合物，化学式为Na4[Rh2(SO4)4]，它以二水合物Na4[Rh2(SO4)4(H2O)2]和六水合物Na4[Rh2(SO4)4(H2O)2]·4H2O的形式存在。它在水溶液中和吡啶反应，得到[Rh2(SO4)2py6]·6H2O。Baranovskii, I. B.; Zhilyaev, A. N.; Dikareva, L. M. Sulfate and phosphate pyridine-containing binuclear rhodium(II) complexes with two bridging groups. Zhurnal Neorganicheskoi Khimii, 1985. 30 (7): 1785-1788. ISSN: 0044-457X.它可以由硫酸铈(IV)Baranovskii, I. B.; Zhilyaev, A. N.; Rotov, A. V. Binuclear rhodium(II,III) tetrasulfate complexes. Zhurnal Neorganicheskoi Khimii, 1985. 30 (12): 3205-3208. ISSN: 0044-457X.或经电化学法Ezerskaya, N. A.; Kiseleva, I. N.; Leonova, O. G. Oxidation-reduction transformations in solutions of binuclear rhodium sulfato complexes with an Rh-Rh bond. Zhurnal Neorganicheskoi Khimii, 1996. 41 (4): 593-597. ISSN: 0044-457X.氧化为混合价态的Rh(II,III)化合物。

参考文献

Category:铑配合物
Category:钠化合物
Category:硫酸盐
Category:含金属-金属键的化合物
Category:二价铑化合物