高铼酸钕

高铼酸钕是一种无机化合物，化学式为Nd(ReO4)3，存在无水物和四水合物Varfolomeev, M. B.; Plyushchev, V. E.; Rybakov, K. A. Monoclinic modification of neodymium perrhenate tetrahydrate. Zhurnal Neorganicheskoi Khimii, 1967. 12 (5): 1410-1411. ISSN: 0044-457X.Mashonkin, V. P.; Ilyukhin, V. V.; Varfolomeev, M. B. Structure of rhombic rare earth perrhenate tetrahydrates RE(ReO4)​3.4H2O (RE = praseodymium-dysprosium). Koordinatsionnaya Khimiya, 1977. 3 (7): 1014-1019. ISSN: 0132-344X.。它可由过量的氧化钕和240 g/L的高铼酸溶液反应得到。Plyushchev, V. E.; Amosov, V. M.; Varfolomeev, M. B. Synthesis and certain properties of lower crystallohydrates of yttrium, lanthanum, and lanthanoid perrhenates. Doklady Akademii Nauk SSSR, 1963. 150 (1): 105-108. ISSN: 0002-3264.在其溶液中可以观测到NdReO42+和Nd(ReO4)2+，稳定常数分别为16.5和23.6。Petrov, K. I.; Orlin, N. A.; Plyushchev, V. E. Neodymium perrhenate complexes studied by a spectrographic method. Zhurnal Neorganicheskoi Khimii, 1969. 14 (10): 2739-2742. ISSN: 0044-457X.

高铼酸钕和NdRe2在高温下反应，可以制得Nd4Re6O19。

参考文献

Category:钕化合物
Category:高铼酸盐