二高氯酸氧钒

二高氯酸氧钒也称高氯酸钒(IV)酰，是一种无机化合物，化学式为VO(ClO4)2。它可由V(OH)4和3.5 N高氯酸反应得到。Tishchenko, A. F.; Golub, A. M. Formation of vanadium(IV) perchlorate. Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya, 1974. 17 (5): 656-658. ISSN: 0579-2991.它的五水合物可溶于水，在水中解离为[VO(H2O)5]2+和ClO4−。Sathyanarayana, D. N.; Patel, C. C. A physicochemical study of vanadyl perchlorate pentahydrate. Indian Journal of Chemistry, 1965. 3 (11): 486-489. ISSN: 0019-5103.它可以和甲基苯基亚砜形成配合物VO(ClO4)2·4MPSO。Agarwal, R. K.; Singh, Pitam; Singh, Lakshman. Synthesis and characterization of oxovanadium(IV) complexes of methyl phenyl sulfoxide. Revue Roumaine de Chimie, 1993. 38 (7): 853-858. ISSN: 0035-3930.它可用于制备其它VO2+化合物。Agarwal, Ram K.; Singh, Lakshman; Sharma, Deepak K.; Singh, Ritu. Synthesis, spectral and thermal investigations of some oxovanadium(IV) complexes of hydrazones of isonicotinic acid hydrazide. Turkish Journal of Chemistry, 2005. 29 (3). 309-316. ISSN: 1300-0527.

参考文献

Category:四价钒化合物
Category:高氯酸盐