二氢化二茂钼

二氢化二茂钼是一种有机钼化合物，化学式为(η5-C5H5)2MoH2，或简写为Cp2MoH2。它是黄色对空气敏感的固体，可溶于一些有机溶剂。

它可由五氯化钼、环戊二烯基钠和硼氢化钠反应得到。它和氯仿反应，生成二氯化二茂钼。

它有“夹贝”式的结构，茂环不是平行的。K. Prout, T. S. Cameron, R. A. Forder, and in parts S. R. Critchley, B. Denton and G. V. Rees "The crystal and molecular structures of bent bis-π-cyclopentadienyl-metal complexes: (a) bis-π-cyclopentadienyldibromorhenium(V) tetrafluoroborate, (b) bis-π-cyclopentadienyldichloromolybdenum(IV), (c) bis-π-cyclopentadienylhydroxomethylaminomolybdenum(IV) hexafluorophosphate, (d) bis-π-cyclopentadienylethylchloromolybdenum(IV), (e) bis-π-cyclopentadienyldichloroniobium(IV), (f) bis-π-cyclopentadienyldichloromolybdenum(V) tetrafluoroborate, (g) μ-oxo-bis[bis-π-cyclopentadienylchloroniobium(IV)] tetrafluoroborate, (h) bis-π-cyclopentadienyldichlorozirconium" Acta Crystallogr. 1974, volume B30, pp. 2290–2304. 

参考文献

Category:氢化物
Category:茂金属
Category:有机钼化合物