氯化二氨合铜(I)

氯化二氨合铜(I)是一种配位化合物，化学式为[Cu(NH3)2]Cl。它可由氯化亚铜和氨反应得到。它在真空中分解，生成CuCl·NH3。此外，CuCl·NH3也是已知的。Kol'tsov, S. I.; Kurashvili, S. E.; Dobruskin, V. Kh.; Smorodina, P. Formation of ammoniates by absorption of ammonia by copper(I) chloride films. Zhurnal Neorganicheskoi Khimii, 1985. 30 (10): 2700-2703. ISSN: 0044-457X.

氯化二氨合铜(I)的水溶液中含有[Cu(NH3)​2]​+、[Cu(NH3)​Cl2]​−和[Cu(NH3)​2Cl]，并可以迅速被空气中的氧氧化。Black, Jay; Spiccia, Leone; McPhail, D. C. Towards an understanding of copper(I) speciation and reactivity in the copper-ammonia-thiosulfate lixiviant system. Hydrometallurgy 2003, Proceedings of the International Symposium honoring Professor Ian M. Ritchie, 5th, Vancouver, BC, Canada, Aug. 24-27, 2003. ISBN 0-87339-554-9它的氨水溶液能够吸收一氧化碳，生成[Cu(NH3)3CO]Cl·H2O。van Krevelen, D. W.; Baans, C. M. E. Elimination of carbon monoxide from synthesis gases by absorption in cuprous salt solutions. Journal of Physical and Colloid Chemistry, 1950. 54: 370-390. ISSN: 0092-7023它也能和含末端炔氢的物质反应，生成炔化亚铜沉淀。李运康, 陈德芳. 末端炔烃与亚铜离子反应的实验研究 . 西安交通大学学报, 1994 (8).

参考文献

Category:铜化合物
Category:氯化物
Category:氨配合物