六氰合铁(II)酸四甲基铵

六氰合铁(II)酸四甲基铵是一种无机化合物，化学式为[(CH3)4N]4[Fe(CN)6]。

制备
六氰合铁(II)酸四甲基铵可由六氰合铁(III)酸四甲基铵的还原反应制得，将过量的H2O2滴加至[(CH3)4N]3[Fe(CN)6]和[(CH3)4N]OH的混合溶液中，黄色逐渐变为无色。[(CH3)4N]4[Fe(CN)6]在加入乙醇后沉淀得到。D. E. Khoshtariya, Anna M. Kjaer, T. A. Marsagishvili, and Jens Ulstrup. Inhibition of near-infrared photoinduced electron transfer between free hexacyanoferrate(II) and hexacyanoferrate(III) by tetramethylammonium ions. J. Phys. Chem., 1992, 96 (11), pp 4154–4156. DOI: 10.1021/j100190a010

参考文献

拓展阅读
 Wilson, R. F.; James, J. The interaction of dihydrogen di(1,2,3-benzotriazolatium) hexacyanoferrate(II) with certain organic amines. II. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1963. 321: 175-179. DOI:10.1002/zaac.19633210308
Ferranti, Francesco; Indelli, Antonio. Conductance of aqueous solutions of cobaltcyanides, ferrocyanides, and molybdocyanides of potassium and of tetraalkylammonium ions. Journal of Solution Chemistry, 1974. 3 (8): 619-627. DOI:10.1007/BF00650405

category:四甲基铵盐
Category:亚铁氰酸盐