乙酸镥

乙酸镥是镥的乙酸盐，化学式为Lu(CH3COO)3。

制备
乙酸镥可由氧化镥和气态乙酸Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates. Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.或50%乙酸溶液Xina Graehlert, Graehlert Starke. Preparation, thermogravimetry, and IR spectra of rare earth acetates. Wissenschaftliche Zeitschrift der Technischen Universitaet Chemnitz, 1992. 34 (2): 219-229.反应得到。

性质
乙酸镥和氟化铵反应，生成氟化镥：
 Lu(CH3COO)3 + 3 NH4F → LuF3 + 3 CH3COONH4
氟硼酸盐（如[BMIM]BF4注释：原文为BMIM = 1-butyl-2-methylimidazolium，疑似写错，正确的是1-butyl-3-methylimidazolium）水解生成的也能与产生沉淀。Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocana, Manuel. Uniform, luminescent Eu:LuF3 nanoparticles. Journal of Nanoparticle Research, 2015. 17 (1): 1-10. DOI:10.1007/s11051-015-2874-z.

和磷酸反应，生成磷酸镥：Becerro, Ana I.; Ocana, Manuel. Quick synthesis, functionalization and properties of uniform, luminescent LuPO4-based nanoparticles. RSC Advances, 2015. 5 (44): 34517-34524. DOI:10.1039/C5RA05305F.

 Lu(CH3COO)3 + H3PO4 → LuPO4 + 3 CH3COOH

参考文献

category:鎦化合物
category:乙酸盐