一磷化钛

一磷化钛（化学式：TiP）是一种无机化合物，通常为灰色粉末。它是有着高熔点的金属导体。H.G. Von Schnering, W. Hönle  Phosphides - Solid state chemistry  Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons 它对水或通常的酸稳定。它的性质和碱金属或碱土金属含P3−的磷化物（如Na3P）相比是不同的，那些磷化物不具备金属性，且会理科水解。一磷化钛被分类为“富金属磷化物”，有着多余的来自金属的离域价电子。

TiP可以通过TiCl4和PH3的反应制备。

钛的其它磷化物，如Ti3P、Hydrogen absorption in Ti3P  Halter U., Mrowietz M., Weiss A  Journal of the less-common metals  1986   118  343-348Ti2P、Structure of Ti2P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson  Acta Crystallogr. (2003). A59, 117-126  Ti7P4、New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979),  33,  401-402Ti5P3、Crystal Structure Refinement of Ti5P3   Carrillo C W., Lundström T  Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980  34  415-419和Ti4P3Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP2 and ZrP2,  Snell P.O, Acta Chem. Scand. 1968  22  1942-1952等，是已知的。

参考文献

Category:三价钛化合物
Category:磷化物