六氟磷酸铜

六氟磷酸铜是一种无机化合物，化学式为Cu(PF6)2，其中PF6−为非配位阴离子。

制备
六氟磷酸铜可由硝酸铜和六氟磷酸铵按1：2化学计量比反应得到。G Mukherjee，K Biradha. Coordination Polymers Containing M2L2 and M4L4 Metallacylces of Bis(pyridylcarboxamido)alkanes with an Odd Number of −(CH2)– Groups as Spacers: Guest Inclusion and Networks Recognition via α Sheet. Crystal Growth & Design, 2013, 13(9):4100–4109
Cu(NO3)2 + 2 NH4PF6 → Cu(PF6)2 + 2 NH4NO3

配合物
六氟磷酸铜可以形成配合物[Cu(L)2ONC(CN)2]PF6（L=邻二氮菲或2,2'-联吡啶）。Potocnak, I.; Vavra, M.; Jager, L.; et al. Ligand rigidity and the shape of the coordination polyhedra in five-coordinated copper(II) complexes with nitrosodicyanmethanide. Monograph Series of the International Conferences on Coordination Chemistry held periodically at Smolenice in Slovakia (2005)7, 306-312

参考文献

拓展阅读
AF Clifford，HC Beachell，WM Jack. The hydrogen fluoride solvent system—I A qualitative survey of acids. Journal of Inorganic & Nuclear Chemistry, 1957, 5(1):57-70

Category:二价铜化合物
category:六氟磷酸盐
Category:缺少物质图片的化学品条目