甲酸铜

甲酸铜是铜(II)的甲酸盐，化学式为Cu(HCOO)2。可以以无水物Motomichi Inoue, Masaji Kubo. Superexchange interaction in anhydrous copper(II) formate. Inorg. Chem., 1970, 9 (10), pp 2310–2314 DOI: 10.1021/ic50092a022、二水AM Heyns. The vibrational spectra of the copper(II) formates Part II. The internal formate and lattice modes of Cu(HCOO)2·2H2O. Journal of Molecular Structure, 1985, 127(1):9-20或四水合物Ryōiti Kiriyama, Hideko Ibamoto, Kanji Matsuo. The Crystal Structure of Cupric Formate Tetrahydrate, Cu(HCO2)2.4H2O. Acta Cryst, 1954, 7(6-7): 482-483的形式存在。也能和吡啶、尿素等形成加合物。H. Uekusa, S. Ohba, Y. Saito, et al. Structural comparison between dimeric copper(II) formate and acetate in pyridine and urea adducts. Acta Crystallographica Section C, 1989. 45(3): 377-380. DOI: 10.1107/S0108270188011904

制备
甲酸铜可由甲酸和碱式碳酸铜反应得到，产物的形貌、颜色等和反应条件有关。A. K. Galwey, D. Jamieson, M. E. Brown. Thermal decomposition of three crystalline modifications of anhydrous copper(II) formate. J. Phys. Chem., 1974, 78 (26), pp 2664–2670 DOI: 10.1021/j100619a006
化学性质
甲酸铜加热可以分解：
Cu(HCOO)2 → Cu + H2↑ + CO2↑
参考文献

拓展阅读
 甲酸铜的制备 （PPT）. 百度文库. [2017-2-22]

Category:二价铜化合物
Category:甲酸盐