铋化物

铋化物是含Bi3−阴离子的化合物。碱金属的铋化物M3Bi都是已知的，例如铋化钠（Na3Bi）可以由钠和铋的单质在高温、高压下反应得到。S. A. Kulinich, M. E. Leonova, L. G. Sevast’yanova, et al. High-Pressure Synthesis of Sodium Bismuthide Na3Bi . Russian Journal of General Chemistry, 1999. 69（5）: 681-683

多元铋化物也有文献报道，例如有着PbClF结构的KCaBiH. Hirt, H. J. Deiseroth. Crystal structure of potassium calcium bismuthide, KCaBi . Zeitschrift für Kristallographie, 2003. 218(JG)、同时含有-1和-3价Bi的化合物Ba2Cd2.13Bi3OS.-Q. Xia and S. Bobev. Dibarium tricadmium bis­muthide(-I,-III) oxide, Ba2Cd3Bi3-δO . Acta Cryst. (2010). E66, i81 DOI: 10.1107/S1600536810046283等。
参考文献

拓展阅读
 Andrew L. Hector, Ivan P. Parkin. Transition Metal Pnictide Synthesis: Self Propagating Reactions Involving Sodium Arsenide, Antimonide and Bismuthide . Zeitschrift für Naturforschung B, 1994. 49(4)

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