乙酸仲丁酯

乙酸仲丁酯是一种常用溶剂，用于漆和瓷漆。也用于生产非循环聚合物，乙烯树脂和硝化纤维。"Acetic acid", Ullman's encyclopedia of industrial chemistry (2003, 6th ed., Vol. 1, pp. 170–171). Weinheim, Germany: Wiley-VCH.它是一种可燃的，具有甜味的液体。Howard, H. H. (1993). sec-Butyl acetate. In Handbook of environmental fate and exposure data for organic chemists (Vol. 5, pp. 60-65). Chelsea, MI: Lewis.

乙酸仲丁酯有三种异构体：乙酸正丁酯，乙酸异丁酯和乙酸叔丁酯。

 历史 
生产乙酸仲丁酯的第一种方法是1946年发现的，用仲丁醇和醋酐反应制备。Altschul, R. (1946). "The Reversible Esterification of Carboxylic Acids with Isobutene and Trimethylethylene. Quantitative Studies and Synthetic Applications", Journal of the American Chemical Society, 68(12), 2605-2609.它最早由Rolf Altschul实验室中成功的制备，并发表于1946年。O'Neil, M. J. (Ed.) (2001). sec-Butyl Acetate. In The Merck index: An encyclopedia of chemicals, drugs, and biologicals (13th ed., pg. 1539). Whitehouse Stations, NJ: Merck.

 毒性
这种化合物的小鼠LD50为13 g/kg。Canadian Center for Occupational Health and Safety. (1996). 2-Butyl acetate. Retrieved February 20, 2009, from CHEMINFO database.
人体大量的接触乙酸仲丁酯会导致灼伤眼睛，口腔，喉咙，鼻子或皮肤。International Programme on Chemical Safety. (2003). sec-Butyl acetate. Retrieved February 20, 2009, from INCHEM database.
注射或吸入大量的乙酸仲丁酯会导致中枢神经系统的抑制，出现嗜睡和定向障碍的症状。

 参考文献

 外部链接 
 ChemExpr.com
 MSDS
 PubChem Compound

Category:酯类溶剂
Category:乙酸酯
Category:1940年代发现的物质
Category:仲丁酯