From Wikipedia: 2001 Siberia Airlines Flight 1812Main article: Siberia Airlines Flight 1812On 4 October 2001, Tu-154 crashed over the Black Sea. The plane may have been hit by S-200 surface to air missile, fired from the Crimea peninsula during an exercise of Ukrainian military. All on board (66 passengers and 12 crew) were killed. Then President of Ukraine Leonid Kuchma and several high commanders of the military later expressed their condolences to the relatives of the victims.