Context: Organic Reactions is a secondary reference which synthesizes the organic chemistry literature around particular chemical transformations. Each chapter of "Organic Reactions" is devoted to a particular organic chemical reaction, and chapters provide exhaustive coverage of literature work in the form of a tabular survey of known reactions. Mechanistic and experimental details, including the scope and limitations of each transformation, are also included., In organic chemistry , an aryl halide ( also known as haloarene or halogenoarene ) is an aromatic compound in which one or more hydrogen atoms directly bonded to an aromatic ring are replaced by a halide . The haloarene are distinguished from haloalkanes because they exhibit many differences in methods of preparation and properties . The most important members are the aryl chlorides , but the class of compounds is so broad that many derivatives enjoy niche applications ., Chemistry is a branch of physical science that studies the composition, structure, properties and change of matter. Chemistry includes topics such as the properties of individual atoms, how atoms form chemical bonds to create chemical compounds, the interactions of substances through intermolecular forces that give matter its general properties, and the interactions between substances through chemical reactions to form different substances., A drug is any substance (other than food that provides nutritional support) that, when inhaled, injected, smoked, consumed, absorbed via a patch on the skin, or dissolved under the tongue, causes a physiological change in the body., A polymer (Greek "poly-", "many" + "-mer", "parts") is a large molecule, or macromolecule, composed of many repeated subunits. Because of their broad range of properties, both synthetic and natural polymers play an essential and ubiquitous role in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass relative to small molecule compounds produces unique physical properties, including toughness, viscoelasticity, and a tendency to form glasses and semicrystalline structures rather than crystals., Organic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions, substitution reactions, pericyclic reactions, rearrangement reactions, photochemical reactions and redox reactions. In organic synthesis, organic reactions are used in the construction of new organic molecules. The production of many man-made chemicals such as drugs, plastics, food additives, fabrics depend on organic reactions., An organic compound is virtually any chemical compound that contains carbon, although a consensus definition remains elusive and likely arbitrary. Organic compounds are rare terrestrially, but of central importance because all known life is based on organic compounds. The most basic petrochemicals are considered the building blocks of organic chemistry., Chemical composition, also known as chemical makeup or simply, composition, is a concept in chemistry that has different, but similar, meanings if referred to a single pure substance or a mixture., Organic chemistry is a chemistry subdiscipline involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. Study of structure includes many physical and chemical methods to determine the chemical composition and the chemical constitution of organic compounds and materials. Study of properties includes both physical properties and chemical properties, and uses similar methods as well as methods to evaluate chemical reactivity, with the aim to understand the behavior of the organic matter in its pure form (when possible), but also in solutions, mixtures, and fabricated forms. The study of organic reactions includes probing their scope through use in preparation of target compounds (e.g., natural products, drugs, polymers, etc.) by chemical synthesis, as well as the focused study of the reactivities of individual organic molecules, both in the laboratory and via theoretical (in silico) study., A natural product is a chemical compound or substance produced by a living organismthat is, found in nature. In the broadest sense, natural products include any substance produced by life. Natural products can also be prepared by chemical synthesis (both semisynthesis and total synthesis) and have played a central role in the development of the field of organic chemistry by providing challenging synthetic targets. The term natural product has also been extended for commercial purposes to refer to cosmetics, dietary supplements, and foods produced from natural sources without added artificial ingredients., In silico (literally Latin for "in silicon", alluding to the mass use of silicon for semiconductor computer chips) is an expression used to mean "performed on computer or via computer simulation." The phrase was coined in 1989 as an allusion to the Latin phrases "in vivo", "in vitro", and "in situ", which are commonly used in biology (see also systems biology) and refer to experiments done in living organisms, outside of living organisms, and where they are found in nature, respectively., The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens. They are a subset of the general class of halocarbons, although the distinction is not often made. Haloalkanes are widely used commercially and, consequently, are known under many chemical and commercial names. They are used as flame retardants, fire extinguishants, refrigerants, propellants, solvents, and pharmaceuticals. Subsequent to the widespread use in commerce, many halocarbons have also been shown to be serious pollutants and toxins. For example, the chlorofluorocarbons have been shown to lead to ozone depletion. Methyl bromide is a controversial fumigant. Only haloalkanes which contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. Methyl iodide, a naturally occurring substance, however, does not have ozone-depleting properties and the United States Environmental Protection Agency has designated the compound a non-ozone layer depleter. For more information, see Halomethane. Haloalkane or alkyl halides are the compounds which have the general formula "RX" where R is an alkyl or substituted alkyl group and X is a halogen (F, Cl, Br, I)., A propellant or propellent is a chemical substance used in the production of energy or pressurized gas that is subsequently used to create movement of a fluid or to generate propulsion of a vehicle, projectile, or other object. Common propellants are energetic materials and consist of a fuel like gasoline, jet fuel, rocket fuel, and an oxidizer. Propellants are burned or otherwise decomposed to produce the propellant gas. Other propellants are simply liquids that can readily be vaporized., In chemistry, a mixture is a material system made up of two or more different substances which are mixed but are not combined chemically. A mixture refers to the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions, and colloids., Carbon (from "coal") is a chemical element with symbol C and atomic number 6. It is nonmetallic and tetravalentmaking four electrons available to form covalent chemical bonds. Three isotopes occur naturally, C and C being stable, while C is a radioactive isotope, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity., Subject: aryl halide, Relation: subclass_of, Options: (A) branch (B) c (C) carbon (D) chemical element (E) chemical reaction (F) chemical substance (G) chemical synthesis (H) chemistry (I) combination (J) composition (K) computer (L) computer simulation (M) concept (N) constitution (O) construction (P) dna (Q) drug (R) food (S) function (T) general (U) greek (V) latin (W) life (X) man (Y) material (Z) matter ([) mixture (\) natural (]) organic compound (^) organism (_) patch (`) polymer (a) preparation (b) product (c) production (d) range (e) redox (f) reference (g) role (h) science (i) silicon (j) simulation (k) single (l) skin (m) structure (n) study (o) substitution (p) support (q) system (r) via
Output: chemical substance