Comparison of the oxidation state of Fe in comet 81P/Wild 2 and chondritic-porous interplanetary dust particles
Comparison of the oxidation state of Fe in comet 81P/Wild 2 and chondritic-porous interplanetary dust particles R.C. Ogliore a, ⁎ , A.L. Butterworth a , S.C. Fakra b , Z. Gainsforth a , M.A. Marcus b , A.J. Westphal a a b Space Sciences Laboratory, University of California at Berkeley, Berkeley, CA 94720, USA Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA a r t i c l e i n f o a b s t r a c t The fragile structure of chondritic-porous interplanetary dust particles (CP-IDPs) and their minimal parent- body alteration have led researchers to believe these particles originate in comets rather than asteroids where aqueous and thermal alterations have occurred. The solar elemental abundances and atmospheric entry speed of CP-IDPs also suggest a cometary origin. With the return of the Stardust samples from Jupiter- family comet 81P/Wild 2, this hypothesis can be tested. We have measured the Fe oxidation state of 15 CP- IDPs and 194 Stardust fragments using a synchrotron-based x-ray microprobe. We analyzed ∼ 300 ng of Wild 2 material — three orders of magnitude more material than other analyses comparing Wild 2 and CP-IDPs. The Fe oxidation state of these two samples of material are N2σ different: the CP-IDPs are more oxidized than the Wild 2 grains. We conclude that comet Wild 2 contains material that formed at a lower oxygen fugacity than the parent-body, or parent bodies, of CP-IDPs. If all Jupiter-family comets are similar, they do not appear to be consistent with the origin of CP-IDPs. However, comets that formed from a different mix of nebular material and are more oxidized than Wild 2 could be the source of CP-IDPs.  comet 81P/Wild 2 interplanetary dust particles XANES Jupiter-family comets 1.  Chondritic-porous interplanetary dust particles (CP-IDPs), collect- ed in the stratosphere by high-altitude aircraft, are widely thought to originate in comets (Schramm et al., 1989; Bradley, 1994). The collisional history of asteroids makes it unlikely that these particles (fragile, porous aggregates of small grains) are asteroidal (Brownlee, 1985). The atmospheric entry speed of CP-IDPs, as deduced from thermal release proﬁles of solar wind He (Nier and Schlutter, 1992), is consistent with cometary, rather than asteroidal, orbits (Brownlee et al., 1995). Infrared and electron beam studies of IDPs show that those consisting of mostly anhydrous minerals are usually chondritic- porous, whereas IDPs rich in phyllosilicates are usually chondritic- smooth (Sandford and Walker, 1985; Bradley and Brownlee, 1986). The presence of GEMS (glass with embedded metal and sulﬁdes) in IDPs indicates a lack of thermal alteration (Bradley, 1994). CP-IDPs, therefore, show very little parent-body alteration and must originate from either anhydrous objects or hydrous objects that have been kept at very low temperature — again, consistent with cometary origin. Nevertheless, a cometary origin of CP-IDPs is not universally accepted (Flynn, 1992; Thomas et al., 1995). With the return of samples from comet 81P/Wild 2 by NASA's Stardust mission (Brownlee et al., 2006), it is now possible to compare CP-IDPs with material from this Jupiter- ⁎ Corresponding author. E-mail address: ogliore@ssl.berkeley.edu (R.C. Ogliore). family comet. We seek to prove or disprove, with a known level of conﬁdence, the hypothesis that CP-IDPs originate from parent bodies with the composition of comet Wild 2. The oxidation state of Fe is a clear mineralogic indicator of the oxidation state of meteorites (Rubin et al., 1988). Meteorite groups are in fact distinguished from each other by their differing Fe oxidation states, as Urey and Craig ﬁrst reported more than ﬁfty years ago (Urey and Craig, 1953). Parent-body processing can drastically change the Fe oxidation state of some of the meteorite groups, obscuring information about the original oxidation state the material acquired in the solar nebula (Rubin et al., 1988). Carbonates and Fe-bearing crystalline silicates, possible products of aqueous alteration on asteroids (Krot et al., 1995), are found alongside anhydrous minerals in the same Stardust track (Flynn, 2008), and therefore co-existed in one large aggregate in comet Wild 2. No phyllosilicates have been unambiguously identiﬁed in the Stardust samples (Zolensky et al., 2008). With these and other pieces of evidence, Wooden (2008) argues that instead of selective aqueous alteration on submicron scales in the comet itself, grains which formed in different regions of the solar nebula under varying reduction–oxidation conditions (e.g. Mg- and Fe-rich crystalline silicates) migrated, aggregated, and formed comet Wild 2. Likewise, the oxidation state of anhydrous CP-IDPs was unaffected by parent- body processing (Schramm et al., 1989; Zolensky and Thomas, 1995), so a comparison of the Fe oxidation state of comet Wild 2 with anhydrous CP-IDPs yields insight into the nebular environment in which they formed.

title: Elemental Compositions of Comet 81P/Wild 2 Samples Collected by Stardust
abstract: We measured the elemental compositions of material from 23 particles in aerogel and from residue in seven craters in aluminum foil that was collected during passage of the Stardust spacecraft through the coma of comet 81P/Wild 2. These particles are chemically heterogeneous at the largest size scale analyzed (∼180 ng). The mean elemental composition of this Wild 2 material is consistent with the CI meteorite composition, which is thought to represent the bulk composition of the solar system, for the elements Mg, Si, Mn, Fe, and Ni to 35%, and for Ca and Ti to 60%. The elements Cu, Zn, and Ga appear enriched in this Wild 2 material, which suggests that the CI meteorites may not represent the solar system composition for these moderately volatile minor elements.

title: Aerogel keystones: Extraction of complete hypervelocity impact events from aerogel collectors
abstract: In January 2006, the Stardust mission will return the first samples from a solid solar system body beyond the Moon and the first samples of contemporary interstellar dust ever collected. Although sophisticated laboratory instruments exist for the analysis of Stardust samples, techniques for the recovery of particles and particle residues from aerogel collectors remain primitive. Here, we describe our recent progress in developing techniques for extracting small volumes of aerogel, which we have called "keystones," which completely contain particle impacts but minimize the damage to the surrounding aerogel collector. These keystones can be fixed to custom-designed micromachined silicon fixtures (so called "microforklifts"). In this configuration, the samples are self-supporting, which can be advantageous in situations where interference from a supporting substrate is undesirable. The keystones may also be extracted and placed onto a substrate without a fixture. We have also demonstrated the capability of homologously crushing these unmounted keystones for analysis techniques that demand flat samples.

title: UNIQUE SIGNATURE OF DARK MATTER IN ANCIENT MICA
abstract: Mica can store (for >1 Gy) etchable tracks caused by atoms recoiling from WIMPs. Because a background from fission neutrons will eventually limit this technique, a unique signature for WIMPs in ancient mica is needed. Our motion around the center of the Galaxy causes WIMPs, unlike neutrons, to enter the mica from a preferred direction on the sky. Mica is a directional detector and despite the complex rotations that natural mica crystals make with respect to this WIMP ``wind,'' there is a substantial dependence of etch pit density on present day mica orientation.

title: Energy loss of relativistic heavy ions in matter
abstract: We have investigated the theory of energy loss of charged particles in matter due to ionization of the medium, integrating the work of other authors over several decades. We describe the most important corrections to standard energy-loss formulae. We compare our calculations to an improved measurement of the range of 1 A GeV U ions and to other codes and tabulations. We show that calculations based on the theory of ionization energy loss are at least as accurate as tabulations extrapolated from empirical data for the stopping of uranium ions in matter. We have made available the computer code resulting from our investigations.

title: Antarctic muon and neutrino detector array

title: Finding all flux vacua in an explicit example
abstract: A bstractWe explicitly construct all supersymmetric flux vacua of a particular Calabi-Yau compactification of type IIB string theory for a small number of flux carrying cycles and a given D3-brane tadpole. The analysis is performed in the large complex structure region by using the polynomial homotopy continuation method, which allows to find all stationary points of the polynomial equations that characterize the supersymmetric vacuum solutions. The number of vacua as a function of the D3 tadpole is in agreement with statistical studies in the literature. We calculate the available tuning of the cosmological constant from fluxes and extrapolate to scenarios with a larger number of flux carrying cycles. We also verify the range of scales for the moduli and gravitino masses recently found for a single explicit flux choice giving a Kähler uplifted de Sitter vacuum in the same construction.

title: Just enough inflation: power spectrum modifications at large scales
abstract: We show that models of `just enough' inflation, where the slow-roll evolution lasted only 50- 60 e-foldings, feature modifications of the CMB power spectrum at large angular scales. We perform a systematic analytic analysis in the limit of a sudden transition between any possible non-slow-roll background evolution and the final stage of slow-roll inflation. We find a high degree of universality since most common backgrounds like fast-roll evolution, matter or radiation-dominance give rise to a power loss at large angular scales and a peak together with an oscillatory behaviour at scales around the value of the Hubble parameter at the beginning of slow-roll inflation. Depending on the value of the equation of state parameter, different pre-inflationary epochs lead instead to an enhancement of power at low l, and so seem disfavoured by recent observational hints for a lack of CMB power at l 40. We also comment on the importance of initial conditions and the possibility to have multiple pre-inflationary stages.

title: Building an explicit de Sitter
abstract: A bstractWe construct an explicit example of a de Sitter vacuum in type IIB string theory that realizes the proposal of Kähler uplifting. As the large volume limit in this method depends on the rank of the largest condensing gauge group we carry out a scan of gauge group ranks over the Kreuzer-Skarke set of toric Calabi-Yau threefolds. We find large numbers of models with the largest gauge group factor easily exceeding a rank of one hundred. We construct a global model with Kähler uplifting on a two-parameter model on $ \mathbb{CP}_{11169}^4 $, by an explicit analysis from both the type IIB and F-theory point of view. The explicitness of the construction lies in the realization of a D7 brane configuration, gauge flux and RR and NS flux choices, such that all known consistency conditions are met and the geometric moduli are stabilized in a metastable de Sitter vacuum with spontaneous GUT scale supersymmetry breaking driven by an F-term of the Kähler moduli.

title: String Cosmology — Large-Field Inflation in String Theory

title: Tensor modes on the string theory landscape
abstract: A bstractWe attempt an estimate for the distribution of the tensor mode fraction r over the landscape of vacua in string theory. The dynamics of eternal inflation and quantum tunneling lead to a kind of democracy on the landscape, providing no bias towards large-field or small-field inflation regardless of the class of measure. The tensor mode fraction then follows the number frequency distributions of inflationary mechanisms of string theory over the landscape. We show that an estimate of the relative number frequencies for small-field vs large-field inflation, while unattainable on the whole landscape, may be within reach as a regional answer for warped Calabi-Yau flux compactifications of type IIB string theory.