natgillin/translations-raw huggingface dataset:
The apparent desorption coefficient (Kdes) is, under the test conditions, the ratio between the content of the substance remaining in the soil phase and the mass concentration of the desorbed substance in the aqueous solution, when desorption equilibrium is reached:
Näennäinen desorptiokerroin (Kdes) on koeolosuhteissa maa-ainesfaasiin jääneen aineen pitoisuuden suhde desorboituneen aineen massakonsentraatioon vesiliuoksessa silloin, kun desorptiotasapainotila on saavutettu:
desorption coefficient (cm3 g-1);
desorptiokerroin (cm3 g-1)
total mass of the test substance desorbed from soil at desorption equilibrium (μg);
maa-aineksesta desorboituneen testiaineen kokonaismassa desorptiotasapainotilassa (μg)
total volume of the aqueous phase in contact with the soil during the desorption kinetics test (cm3).
maa-aineksen kanssa desorptiokinetiikkatestin aikana kosketuksiin joutuvan vesifaasin kokonaistilavuus (cm3).
Guidance for calculating the maq
Ohjeet maq
is given in Appendix 5 under the heading ‘Desorption’.
:n laskemiseksi annetaan lisäyksessä 5 kohdassa ”Desorptio”.
Remark
Huomautus:
If the adsorption test which was preceded, was performed with the parallel method the volume VT in the equation (12) is considered to be equal to V0.
Jos edeltävä adsorptiotesti suoritettiin rinnakkaismenetelmää käyttäen, niin yhtälössä (12) esiintyvä tilavuus VT oletetaan yhtä suureksi kuin Vo.
The Freundlich desorption isotherms equation relates the content of the test substance remaining adsorbed on the soil to the concentration of the test substance in solution at desorption equilibrium (equation 16).
Freundlichin desorptioisotermien yhtälö yhdistää maa-ainekseen adsorboituneeksi jääneen testiaineen pitoisuuden liuoksessa olevan testiaineen konsentraatioon desorptiotasapainotilassa (yhtälö 16).
For each test tube, the content of the substance remaining adsorbed on soil at desorption equilibrium is calculated as follows:
Kullekin koeputkelle lasketaan maa-ainekseen adsorboituneeksi jääneen aineen pitoisuus desorptiotasapainotilassa seuraavasti:
content of the test substance remaining adsorbed on the soil at desorption equilibrium (μg g-1);
maa-ainekseen adsorboituneeksi jääneen testiaineen pitoisuus desorptiotasapainotilassa (μg g-1)
mass of substance determined analytically in the aqueous phase at desorption equilibrium (μg);
vesifaasista desorptiotasapainotilassa analyyttisesti määritetyn aineen massa (μg)
mass of the test substance left over from the adsorption equilibrium due to incomplete volume replacement (μg);
epätäydellisestä tilavuustäydennyksestä johtuen adsorptiotasapainotilan ulkopuolelle jääneen testiaineen massa (μg)
volume of the solution taken from the tube for the measurement of the test substance, at desorption equilibrium (cm3);
koeputkesta testiaineen mittaamiseksi otetun liuoksen tilavuus, desorptiotasapainotilassa (cm3)
volume of the supernatant removed from the tube after the attainment of adsorption equilibrium and replaced by the same volume of a 0,01 M CaCl2 solution (cm3);
koeputkesta adsorptiotasapainotilan saavuttamisen jälkeen poistetun supernatantin tilavuus, joka korvataan samalla tilavuudella 0,01 M CaCl2-liuosta (cm3).
The Freundlich desorption equation is shown in (16):
Yhtälö (16) on Freundlichin desorptioyhtälö:
Freundlich desorption coefficient;
Freundlichin desorptiokerroin
n regression constant;
n regressiovakio
mass concentration of the substance in the aqueous phase at desorption equilibrium (μg cm-3).
vesifaasissa olevan aineen massakonsentraatio desorptiotasapainotilassa (μg cm-3).
The equations (16) and (17) can be plotted and the value of KF
Yhtälöt (16) ja (17) voidaan piirtää ja KF
and 1/n are calculated by regression analysis using the equation 17.
ja l/n -arvot lasketaan regressioanalyysin avulla yhtälöä 17 käyttäen.
if the Freundlich adsorption or desorption exponent 1/n is equal to 1, the Freundlich adsorption or desorption binding constant (KF
Jos Freundlichin adsorptio- tai desorptioeksponentti l/n on yhtä kuin 1, Freundlichin adsorption tai desorption sitoutumisvakio (KF
will be equal to the adsorption or desorption equilibrium constants (Kd and Kdes) respectively, and plots of Cs vs Caq will be linear.
on yhtä suuri kuin adsorptio- tai desorptiotasapainovakiot (vastaavasti Kd ja Kdes), jolloin CS vs Caq -käyrät ovat lineaariset.
If the exponents are not equal to 1, plots of Cs vs Caq will be non-linear and the adsorption and desorption constants will vary along the isotherms.
Jos eksponentit ovat erisuuria kuin 1, Cs vs Caq -käyrät eivät ole lineaarisia ja adsorptio- ja desorptiovakiot vaihtelevat isotermien eri kohdissa.
complete identification of the soil samples used including,
Käytettyjen maa-ainesnäytteiden täydelliset tunnistetiedot, johon sisältyy:
geographical reference of the site (latitude, longitude),
maantieteellinen sijainti (leveysasteet, pituusasteet),
date of sampling,
näytteenottopäivämäärä,
use pattern (e.g. agricultural soil, forest, etc.),
käyttömuoto (esimerkiksi maatalousmaa, metsä),
depth of sampling,
näytteenottosyvyys,
sand/silt/clay content;
hiekka-, liete- ja savipitoisuus,
pH values (in 0,01 M CaCl2),
pH-arvot (0,01 M CaCl2:ssa),
organic carbon content,
orgaanisen hiilen pitoisuus,
organic matter content,
orgaanisen aineksen pitoisuus,
nitrogen content,
typpipitoisuus,
C/N ratio,
C/N-suhde,
cation Exchange Capacity (mmol/kg),
kationinvaihtokyky (mmol/kg),
all information relating to the collection and storage of soil samples,
kaikki maa-ainesnäytteiden keräämiseen ja säilyttämiseen liittyvät tiedot,
where appropriate, all relevant information for the interpretation of the adsorption — desorption of the test substance,
soveltuvin osin kaikki testiaineen adsorptio-desorptiotulkinnan kannalta merkitykselliset tiedot,
reference of the methods used for the determination of each parameter,
kunkin muuttujan määrittämiseksi käytettyjen menetelmien kirjallisuusviitteet,
information on the test substance as appropriate,
testiainetta koskevat tiedot soveltuvin osin,
temperature of the experiments,
koelämpötilat,
centrifugation conditions,
sentrifugointiolosuhteet,
analytical procedure used to analyse the test substance,
analyysimenetelmä testiaineen analysoimiseksi,
justification for any use of solubilising agent for the preparation of the stock solution of the test substance,
perustelut kaikelle liuottavien aineiden käytölle testiaineen varastoliuosten valmistuksessa,
explanations of corrections made in the calculations, if relevant,
selvitykset laskelmissa tehdyistä korjauksista,
data according to the form sheet (Appendix 6) and graphical presentations,
tiedot taulukkomuodossa (liite 6) ja graafiset esitykset,
all information and observations helpful for the interpretation of the test results.
kaikki tiedot ja havainnot, jotka helpottavat testitulosten tulkintaa.
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